Sodium;fluoride;hydrofluoride

F2HNa

sodium;fluoride;hydrofluoride

CAS1333-83-1
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
1333-83-1
EC Number
215-608-3
UN Number
2439
Index Number
009-007-00-3
PubChem CID
219061

Physical-chemical properties

Molecular Formula
F2HNa
Molar Mass
61.99 g/mol
IUPAC Name
sodium;fluoride;hydrofluoride

Chemical Identifiers

InChI
InChI=1S/2FH.Na/h2*1H;/q;;+1/p-1
InChI Key
BFXAWOHHDUIALU-UHFFFAOYSA-M

Overview

Sodium fluoride hydrofluoride (CAS 1333-83-1) is an inorganic fluoride compound with highly corrosive and toxic properties. This chemical substance, also known by its molecular formula F2HNa, represents a specialized fluoride derivative with a molecular weight of 61.9946 g/mol. As a white crystalline solid, sodium fluoride hydrofluoride exhibits exceptional reactivity and requires careful handling due to its significant safety hazards. The compound falls under multiple danger classifications, including Acute Toxicity Category 3 and Skin Corrosion Category 1B, necessitating stringent safety protocols during storage, handling, and transportation. The substance's corrosive nature is particularly pronounced, capable of causing severe chemical burns upon contact with skin or mucous membranes. Its acute toxicity profile demands immediate medical attention in case of exposure, making proper personal protective equipment and ventilation systems essential for safe industrial use. Similar to related compounds like potassium fluoride hydrofluoride, this material requires specialized containment and handling procedures due to its aggressive chemical behavior. In industrial applications, sodium fluoride hydrofluoride serves primarily in specialized chemical synthesis processes, metal surface treatment operations, and as an intermediate in fluorine chemistry applications. The compound's unique properties make it valuable in certain etching processes and as a fluorinating agent in organic chemistry reactions. Its classification under ADR Class 8 (corrosive substances) reflects the need for specialized transportation and storage requirements. OYSI maintains availability of sodium fluoride hydrofluoride for qualified industrial customers, ensuring proper documentation and safety compliance throughout the supply chain.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H301

Toxic if swallowed.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2439
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameNatriumhydrogendifluorid, fest
Marine PollutantNo

Frequently Asked Questions

What is sodium fluoride hydrofluoride?

Sodium fluoride hydrofluoride is an inorganic chemical compound with the molecular formula F2HNa and CAS number 1333-83-1. This substance has a molecular weight of 61.9946 g/mol and is classified as a corrosive material with acute toxicity properties. It is commonly known as sodium hydrogen difluoride or sodium bifluoride and appears as a white crystalline solid that is highly soluble in water.

What are the physicochemical properties of sodium fluoride hydrofluoride?

Sodium fluoride hydrofluoride is a white crystalline solid at room temperature with high water solubility. The compound is hygroscopic, meaning it readily absorbs moisture from air. It has a molecular weight of 61.9946 g/mol and typically appears as odorless crystals or powder. The substance is highly corrosive and releases hydrogen fluoride when in contact with acids or moisture.

What is sodium fluoride hydrofluoride used for?

Sodium fluoride hydrofluoride is primarily used in industrial applications including metal surface treatment, glass etching, and as a cleaning agent for removing rust and mineral deposits. It serves as an intermediate in fluorine chemistry and is utilized in the production of other fluoride compounds. The substance is also employed in specialized cleaning formulations and certain electroplating processes.

How to handle sodium fluoride hydrofluoride safely?

Sodium fluoride hydrofluoride must be handled with extreme caution due to its Acute Tox. 3 and Skin Corr. 1B classifications. Essential PPE includes chemical-resistant gloves, safety goggles, face protection, and protective clothing. Work in well-ventilated areas or under fume extraction systems. Avoid contact with skin, eyes, and respiratory tract. Always have calcium gluconate gel available for emergency treatment of potential fluoride burns.

How to store sodium fluoride hydrofluoride correctly?

Sodium fluoride hydrofluoride should be stored in tightly sealed, corrosion-resistant containers in a cool, dry, well-ventilated area away from incompatible materials. Keep away from acids, metals, and organic materials to prevent dangerous reactions. Store separately from food, feed, and drinking water. Ensure storage areas are equipped with appropriate spill containment and emergency response materials including calcium compounds for neutralization.

What to do in case of contact with sodium fluoride hydrofluoride?

Immediate action is required in case of contact with sodium fluoride hydrofluoride. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes, then apply calcium gluconate gel. For eye contact, irrigate immediately with water for 15 minutes. If inhaled, move to fresh air. Seek immediate medical attention in all cases, emphasizing fluoride exposure to medical personnel.

How to dispose of sodium fluoride hydrofluoride appropriately?

Sodium fluoride hydrofluoride disposal must comply with local and national hazardous waste regulations due to its corrosive and toxic properties. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal companies. Neutralization with calcium compounds may be required before disposal. Always consult local environmental authorities and follow proper waste classification procedures according to applicable legislation.

How to transport sodium fluoride hydrofluoride?

Sodium fluoride hydrofluoride is classified under ADR Class 8 (corrosive substances) with Packing Group II, indicating medium danger level. Transportation requires appropriate UN-specification packaging, proper labeling with GHS05 and GHS06 pictograms, and accompanying transport documents. Vehicles must be equipped with appropriate emergency equipment and drivers need proper training for handling corrosive materials during transport.

Is sodium fluoride hydrofluoride subject to specific regulations?

Sodium fluoride hydrofluoride is subject to multiple regulatory frameworks including REACH registration requirements, CLP classification as Acute Tox. 3 and Skin Corr. 1B, and ADR transport regulations. The substance is not currently listed as an SVHC under REACH. Users must comply with occupational safety regulations, environmental protection laws, and proper classification and labeling requirements under the GHS system.

Where to buy sodium fluoride hydrofluoride in Europe?

Sodium fluoride hydrofluoride is available through OYSI, a trusted European distributor of technical chemicals. OYSI provides this specialized chemical compound to industrial customers across Europe with proper documentation, safety data sheets, and regulatory compliance support. As an experienced chemical distributor, OYSI ensures quality products and professional service for customers requiring this corrosive fluoride compound for their industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.