Sodium;fluoride;hydrofluoride
F2HNa
sodium;fluoride;hydrofluoride
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Identification
- CAS Number
- 1333-83-1
- EC Number
- 215-608-3
- UN Number
- 2439
- Index Number
- 009-007-00-3
- PubChem CID
- 219061
Physical-chemical properties
- Molecular Formula
- F2HNa
- Molar Mass
- 61.99 g/mol
- IUPAC Name
- sodium;fluoride;hydrofluoride
Chemical Identifiers
- InChI
- InChI=1S/2FH.Na/h2*1H;/q;;+1/p-1
- InChI Key
- BFXAWOHHDUIALU-UHFFFAOYSA-M
Overview
Sodium fluoride hydrofluoride (CAS 1333-83-1) is an inorganic fluoride salt with highly corrosive and toxic properties. This chemical compound, also known by its molecular formula F2HNa with a molecular weight of 61.9946 g/mol, represents a significant industrial fluoride source used across various technical applications. The substance appears as a white crystalline solid that readily dissolves in water, forming highly acidic solutions due to the presence of both fluoride and hydrofluoride ions. Its unique chemical structure combines the properties of both sodium fluoride and hydrogen fluoride, making it particularly effective in applications requiring controlled fluoride release. The compound poses serious safety risks, classified under acute toxicity category 3 and skin corrosion category 1B according to GHS standards. The presence of GHS06 and GHS05 pictograms indicates both acute toxicity and corrosive hazards, requiring careful handling procedures and appropriate personal protective equipment. As an ADR class 8 substance, it is regulated as a corrosive material during transport, necessitating specialized packaging and documentation. Primary industrial applications include metal surface treatment processes, where its fluoride content provides effective cleaning and etching capabilities, glass manufacturing as a fluxing agent, and specialized chemical synthesis reactions. The compound shares similar applications with related substances such as potassium fluoride hydrofluoride, though each offers distinct reactivity profiles suited to specific industrial requirements. Storage requires non-metallic containers in dry, well-ventilated areas away from incompatible materials, particularly bases and metals that may react violently with fluoride compounds. OYSI maintains reliable supply chains for sodium fluoride hydrofluoride to meet diverse European industrial requirements.
Safety & Classification
Acute Tox. 3 *; Skin Corr. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 2439 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Natriumhydrogendifluorid, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is sodium fluoride hydrofluoride?
Sodium fluoride hydrofluoride is an inorganic chemical compound with the formula F2HNa and CAS number 1333-83-1. This substance has a molecular weight of 61.9946 g/mol and belongs to the family of fluoride compounds. It is classified as a corrosive and acutely toxic material, requiring careful handling and specialized safety measures. The compound is commonly used in industrial applications where fluoride chemistry is required.
What are the physicochemical properties of sodium fluoride hydrofluoride?
Sodium fluoride hydrofluoride is a white crystalline solid at room temperature with high solubility in water. The compound is hygroscopic, meaning it readily absorbs moisture from the atmosphere. It has a molecular formula of F2HNa and exhibits strong ionic character due to the presence of sodium and fluoride ions. The substance is stable under normal conditions but can release hydrogen fluoride when exposed to acids or elevated temperatures.
What is sodium fluoride hydrofluoride used for?
Sodium fluoride hydrofluoride is primarily used in industrial metal surface treatment processes, including etching and cleaning of aluminum and steel surfaces. It serves as a fluorinating agent in chemical synthesis and is employed in glass etching applications. The compound is also utilized in specialized cleaning formulations for removing oxide layers from metals and in certain electroplating processes where controlled fluoride release is required.
How to handle sodium fluoride hydrofluoride safely?
Sodium fluoride hydrofluoride requires strict safety protocols due to its Acute Tox. 3 and Skin Corr. 1B classifications. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, face shield, and acid-resistant clothing. Work must be conducted in well-ventilated areas or under fume extraction systems. Avoid skin and eye contact completely, and ensure emergency eyewash and shower stations are readily accessible during handling operations.
How to store sodium fluoride hydrofluoride correctly?
Sodium fluoride hydrofluoride must be stored in tightly sealed, corrosion-resistant containers in a cool, dry, and well-ventilated area. Keep away from acids, alkalis, and metals to prevent dangerous reactions. Storage areas should be equipped with appropriate spill containment measures and restricted to authorized personnel only. Maintain storage temperatures below 25°C and protect from moisture to prevent degradation and hydrogen fluoride release.
What to do in case of contact with sodium fluoride hydrofluoride?
Immediate action is critical due to the substance's corrosive nature. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for at least 20 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek immediate medical attention in all cases of exposure, as fluoride compounds can cause delayed serious effects.
How to dispose of sodium fluoride hydrofluoride properly?
Sodium fluoride hydrofluoride disposal must comply with local and European waste regulations as a hazardous chemical waste. The substance cannot be disposed of through normal waste streams and requires treatment by licensed hazardous waste disposal facilities. Neutralization should only be performed by qualified professionals using appropriate calcium-based neutralizing agents. Container disposal must follow hazardous packaging waste protocols, ensuring complete decontamination before disposal.
How to transport sodium fluoride hydrofluoride?
Sodium fluoride hydrofluoride is classified as ADR Class 8 (corrosive substances), Packing Group II, indicating medium danger level during transport. Packaging must meet UN specifications for corrosive materials, using appropriate inner packaging and cushioning materials. Transport vehicles require proper placarding and documentation. Drivers must hold ADR certification for Class 8 materials, and emergency response information must accompany shipments throughout European transport networks.
Is sodium fluoride hydrofluoride subject to particular regulations?
Sodium fluoride hydrofluoride is subject to comprehensive European chemical regulations under REACH and CLP frameworks. The substance requires safety data sheets and proper classification labeling with GHS06 and GHS05 pictograms and 'Danger' signal word. While not currently listed as an SVHC (Substance of Very High Concern), it falls under fluoride compound restrictions in various EU member states and requires authorization for certain industrial applications.
Where to buy sodium fluoride hydrofluoride in Europe?
Sodium fluoride hydrofluoride is available through OYSI, a specialized European distributor of technical chemical products. OYSI provides compliant packaging, documentation, and delivery services across European markets for industrial customers. As a regulated hazardous chemical, purchases typically require verification of legitimate industrial use and appropriate handling capabilities. Contact OYSI directly for availability, technical specifications, and regulatory compliance support for your specific application requirements.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.