Potassium permanganate

KMnO4

potassium permanganate

CAS7722-64-7
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7722-64-7
EC Number
231-760-3
UN Number
1490
Index Number
025-002-00-9
PubChem CID
516875

Physical-chemical properties

Molecular Formula
KMnO4
Molar Mass
158.03 g/mol
IUPAC Name
potassium permanganate

Chemical Identifiers

InChI
InChI=1S/K.Mn.4O/q+1;;;;;-1
InChI Key
VZJVWSHVAAUDKD-UHFFFAOYSA-N

Overview

Potassium permanganate (CAS 7722-64-7) is an inorganic oxidizing salt with strong oxidizing properties and distinctive purple crystalline appearance. This versatile chemical compound, with the molecular formula KMnO4 and a molecular weight of 158.034 g/mol, serves as one of the most widely recognized oxidizing agents in industrial applications. The compound presents as dark purple or bronze-colored crystals that dissolve readily in water to produce characteristic purple solutions. Its powerful oxidizing capabilities make it invaluable across numerous sectors, from water treatment to chemical synthesis. From a safety perspective, potassium permanganate requires careful handling due to its classification as an oxidizing solid (Ox. Sol. 2) and its potential reproductive toxicity (Repr. 2). The substance carries the danger signal word and displays multiple GHS pictograms including GHS03, GHS08, GHS07, and GHS09, reflecting its oxidizing nature, health hazards, and environmental concerns. Its ADR classification as class 5.1 emphasizes the need for proper storage and transportation protocols to prevent unwanted reactions with combustible materials. In industrial applications, potassium permanganate finds extensive use in water treatment processes for iron and manganese removal, as well as for disinfection purposes. The chemical industry utilizes it as a key oxidizing agent in organic synthesis reactions, while the textile sector employs it for bleaching and dyeing processes. Unlike related oxidizing compounds such as chromium(2+);dioxido(dioxo)chromium or barium(2+);dichlorate;hydrate, potassium permanganate offers the advantage of producing less toxic byproducts in many applications. OYSI maintains reliable supplies of technical-grade potassium permanganate to support diverse industrial requirements across European markets.

Safety & Classification

Danger
Classification:

Ox. Sol. 2; Repr. 2; Acute Tox. 4 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H272

May intensify fire; oxidiser.

H302

Harmful if swallowed.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1490
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameKaliumpermanganat
Marine PollutantNo

Frequently Asked Questions

What is potassium permanganate?

Potassium permanganate is an inorganic chemical compound with the formula KMnO4 and CAS number 7722-64-7. It is a powerful oxidizing agent with a molecular weight of 158.034 g/mol. This crystalline substance appears as dark purple crystals and is widely used in various industrial applications due to its strong oxidizing properties. It is classified as a hazardous substance with oxidizing, reproductive toxicity, and aquatic toxicity properties under GHS classification.

What are the physicochemical properties of potassium permanganate?

Potassium permanganate appears as dark purple or bronze-colored crystals with a metallic luster. It is highly soluble in water, producing a characteristic intense purple solution. The compound is odorless and has a molecular weight of 158.034 g/mol. It readily decomposes when heated, releasing oxygen gas. The substance is hygroscopic and can stain skin and clothing upon contact due to its strong oxidizing nature.

What is potassium permanganate used for?

Potassium permanganate serves multiple industrial and professional purposes as a strong oxidizing agent. It is commonly used in water treatment for disinfection and removal of iron and manganese, in chemical synthesis as an oxidizing reagent, and in analytical chemistry for titrations. Other applications include use in textile processing, leather tanning, wood preservation, and as a component in certain cleaning formulations for industrial equipment.

How to handle potassium permanganate safely?

Potassium permanganate requires careful handling due to its oxidizing and toxic properties. Personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing must be worn. Work in well-ventilated areas to avoid dust inhalation. Avoid contact with combustible materials, reducing agents, and organic substances. Use non-sparking tools and ensure proper grounding to prevent static electricity buildup during handling operations.

How to store potassium permanganate correctly?

Potassium permanganate must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and separate from incompatible materials including organic substances, reducing agents, acids, and flammable materials. Storage areas should be equipped with appropriate fire suppression systems. Containers should be made of compatible materials and properly labeled according to GHS requirements.

What to do in case of contact with potassium permanganate?

Potassium permanganate contact requires immediate first aid measures. For skin contact, immediately flush with plenty of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse thoroughly with water for at least 15 minutes. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician after any significant exposure to this substance.

How to dispose of potassium permanganate appropriately?

Potassium permanganate disposal must comply with local and European waste regulations as it is classified as hazardous waste. Small quantities can be neutralized by careful reaction with reducing agents under controlled conditions, but this should only be performed by trained personnel. Large quantities require disposal through licensed hazardous waste contractors. Never dispose of in regular waste streams or pour down drains due to its environmental toxicity classification.

How to transport potassium permanganate?

Potassium permanganate is classified under ADR as Class 5.1 (Oxidizing Substances), Packing Group II, requiring specific transport regulations. It must be packaged in UN-approved containers with proper labeling including GHS pictogrammes GHS03, GHS07, GHS08, and GHS09. Transport vehicles must carry appropriate emergency equipment and documentation. Only trained personnel should handle transportation, and specific routing restrictions may apply in certain areas.

Is potassium permanganate subject to particular regulations?

Potassium permanganate is subject to extensive European regulations including REACH registration requirements and CLP classification as Oxidizing Solid 2, Reproductive Toxicity 2, Acute Toxicity 4, and Aquatic toxicity categories. Although not listed as a SVHC substance, it requires safety data sheets, proper labeling with danger signal words, and compliance with occupational exposure limits. Some applications may require additional permits or notifications to authorities.

Where to buy potassium permanganate in Europe?

Potassium permanganate is available through OYSI, a specialized European distributor of technical chemicals. OYSI supplies this oxidizing agent to industrial customers across Europe, ensuring full regulatory compliance and proper documentation including safety data sheets. As a professional chemical distributor, OYSI provides technical support and guidance for safe handling and application of potassium permanganate in various industrial processes and water treatment applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.