Pentachloro-lambda5-phosphane

Cl5P

pentachloro-lambda5-phosphane

CAS10026-13-8
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
10026-13-8
EC Number
233-060-3
UN Number
1806
Index Number
015-008-00-X
PubChem CID
24819

Physical-chemical properties

Molecular Formula
Cl5P
Molar Mass
208.20 g/mol
IUPAC Name
pentachloro-lambda5-phosphane

Chemical Identifiers

InChI
InChI=1S/Cl5P/c1-6(2,3,4)5
InChI Key
UHZYTMXLRWXGPK-UHFFFAOYSA-N

Overview

Pentachloro-lambda5-phosphane (CAS 10026-13-8) is an inorganic phosphorus compound characterized by high reactivity and significant toxicological properties. This pentavalent phosphorus halide represents a critical intermediate in various industrial chemical processes, distinguished by its molecular formula Cl5P and molecular weight of 208.2 g/mol. The compound exhibits exceptional chemical reactivity due to the presence of five chlorine atoms bonded to a central phosphorus atom in its lambda5 oxidation state, making it a valuable yet hazardous reagent in specialized applications. Safety considerations are paramount when handling pentachloro-lambda5-phosphane, as evidenced by its comprehensive hazard classification including Acute Toxicity categories 2 and 4, Skin Corrosion 1B, and Specific Target Organ Toxicity Repeated Exposure category 2. The substance requires strict adherence to safety protocols, with appropriate personal protective equipment and engineered controls essential for safe manipulation. Its classification under ADR Class 8 as a corrosive material necessitates specialized transportation and storage requirements. The compound finds primary application in the synthesis of organophosphorus compounds, serving as a chlorinating agent in pharmaceutical intermediates production, and as a reagent in specialized chemical manufacturing processes. Its reactivity profile makes it particularly valuable in processes requiring selective chlorination or phosphorus incorporation. While structurally distinct from compounds like pentanedial, pentachloro-lambda5-phosphane shares similar handling requirements due to its reactive nature. Industrial users benefit from the compound's consistent quality and reliable supply chain management. OYSI ensures comprehensive technical support and regulatory compliance documentation for pentachloro-lambda5-phosphane distribution across European markets.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 4 *; STOT RE 2 *; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H302

Harmful if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1806
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NamePhosphorpentachlorid
Marine PollutantNo

Frequently Asked Questions

What is pentachloro-lambda5-phosphane?

Pentachloro-lambda5-phosphane is an inorganic phosphorus compound with the molecular formula Cl5P and CAS number 10026-13-8. It has a molecular weight of 208.2 g/mol and belongs to the family of phosphorus pentahalides. This chemical compound is classified as highly hazardous, exhibiting acute toxicity, skin corrosivity, and specific target organ toxicity properties. It requires careful handling due to its dangerous nature and corrosive characteristics.

What are the physicochemical properties of pentachloro-lambda5-phosphane?

Pentachloro-lambda5-phosphane is a phosphorus pentachloride compound that typically appears as a yellowish-white crystalline solid at room temperature. It has a pungent, irritating odor and readily hydrolyzes in the presence of moisture, releasing hydrogen chloride gas. The compound has a molecular weight of 208.2 g/mol and decomposes when exposed to water or humid conditions, making it highly reactive with aqueous environments.

What is pentachloro-lambda5-phosphane used for?

Pentachloro-lambda5-phosphane is primarily used as a chlorinating agent in organic synthesis and pharmaceutical manufacturing. It serves as a reagent for converting alcohols to alkyl chlorides and carboxylic acids to acid chlorides. The compound is also utilized in the production of organophosphorus compounds and as an intermediate in various chemical processes. Its applications are mainly restricted to industrial and laboratory settings due to its hazardous properties.

How to handle pentachloro-lambda5-phosphane safely?

Pentachloro-lambda5-phosphane requires strict safety measures during handling due to its corrosive and toxic nature. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, face shield, and protective clothing. Work must be conducted in a well-ventilated area or under a fume hood to prevent inhalation exposure. Avoid contact with skin, eyes, and clothing, and ensure emergency eyewash and safety shower facilities are readily accessible nearby.

How to store pentachloro-lambda5-phosphane correctly?

Pentachloro-lambda5-phosphane must be stored in a cool, dry place away from moisture and humidity to prevent decomposition. The container should be tightly sealed and kept in a well-ventilated area, separated from incompatible materials such as water, alcohols, and bases. Storage areas should be equipped with appropriate spill containment measures and maintained at stable temperatures. Regular inspection of containers for signs of corrosion or leakage is essential.

What to do in case of contact with pentachloro-lambda5-phosphane?

Immediate action is required for any contact with pentachloro-lambda5-phosphane due to its corrosive properties. For skin contact, immediately flush the affected area with copious amounts of water for at least 15 minutes while removing contaminated clothing. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing is difficult. Always seek medical assistance promptly.

How to dispose of pentachloro-lambda5-phosphane appropriately?

Pentachloro-lambda5-phosphane must be disposed of as hazardous chemical waste according to local and European regulations. The compound cannot be discharged into sewers or waterways due to its corrosive and toxic nature. Disposal should be conducted through licensed hazardous waste management companies that can handle corrosive materials. Small quantities may be neutralized by qualified professionals before disposal, but this should never be attempted without proper expertise and equipment.

How to transport pentachloro-lambda5-phosphane?

Pentachloro-lambda5-phosphane is classified under ADR Class 8 (corrosive substances) with Packing Group II, indicating high danger level for transport. It requires specialized packaging meeting UN specifications and proper hazard labeling including corrosive substance markings. Transportation must comply with ADR regulations for dangerous goods, including driver certification and vehicle equipment requirements. Proper documentation and emergency response information must accompany all shipments.

Is pentachloro-lambda5-phosphane subject to specific regulations?

Pentachloro-lambda5-phosphane is subject to various European chemical regulations including REACH registration requirements and CLP classification obligations. The compound is classified with multiple hazard classes (Acute Tox. 2, Acute Tox. 4, STOT RE 2, Skin Corr. 1B) requiring specific labeling and safety data sheets. While not currently listed as an SVHC substance, it may be subject to additional restrictions depending on intended use and local regulations.

Where to buy pentachloro-lambda5-phosphane in Europe?

Pentachloro-lambda5-phosphane is available through OYSI, a specialized European distributor of technical chemicals and laboratory reagents. As an established chemical supplier, OYSI can provide this regulated substance to qualified industrial and research customers with appropriate handling capabilities. Due to the hazardous nature of this compound, purchases typically require verification of proper storage facilities, safety protocols, and legitimate industrial or research applications before order processing.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.