Pentachloro-lambda5-phosphane

Cl5P

pentachloro-lambda5-phosphane

CAS10026-13-8
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
10026-13-8
EC Number
233-060-3
UN Number
1806
Index Number
015-008-00-X
PubChem CID
24819

Physical-chemical properties

Molecular Formula
Cl5P
Molar Mass
208.20 g/mol
IUPAC Name
pentachloro-lambda5-phosphane

Chemical Identifiers

InChI
InChI=1S/Cl5P/c1-6(2,3,4)5
InChI Key
UHZYTMXLRWXGPK-UHFFFAOYSA-N

Overview

Pentachloro-lambda5-phosphane (CAS 10026-13-8) is a highly reactive phosphorus pentachloride compound with strong chlorinating and dehydrating properties. This inorganic compound, with molecular formula Cl5P and EC number 233-060-3, represents one of the most important phosphorus halides in industrial chemistry. With a molecular weight of 208.2 g/mol, pentachloro-lambda5-phosphane appears as a yellowish-white crystalline solid that readily sublimes at room temperature, producing dense, corrosive vapors. The compound demonstrates exceptional reactivity with water, alcohols, and other nucleophilic substances, making it a powerful reagent for various chemical transformations. The substance carries significant safety considerations, classified under multiple hazard categories including Acute Toxicity 2 and 4, Skin Corrosion 1B, and Specific Target Organ Toxicity (Repeated Exposure) 2. These classifications necessitate the "Danger" signal word and require appropriate GHS pictograms (GHS06, GHS08, GHS05) on packaging. Transportation falls under ADR Class 8, reflecting its corrosive nature and potential hazards during handling and storage. Industrial applications of pentachloro-lambda5-phosphane include its use as a chlorinating agent in organic synthesis, particularly in pharmaceutical intermediate production, as a catalyst in polymerization reactions, and as a dehydrating agent in various chemical processes. Unlike simpler compounds such as pentanedial, this phosphorus compound offers unique reactivity patterns that make it invaluable for specific synthetic pathways requiring precise chlorination or dehydration steps. OYSI maintains reliable supply chains for pentachloro-lambda5-phosphane, ensuring consistent availability for European industrial customers requiring this specialized chemical reagent.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 4 *; STOT RE 2 *; Skin Corr. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H302

Harmful if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1806
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NamePhosphorpentachlorid
Marine PollutantNo

Frequently Asked Questions

What is pentachloro-lambda5-phosphane?

Pentachloro-lambda5-phosphane is an inorganic phosphorus compound with the chemical formula Cl5P and CAS number 10026-13-8. This chemical substance has a molecular weight of 208.2 g/mol and belongs to the pentavalent phosphorus halides family. It is classified as a highly hazardous material due to its acute toxicity and corrosive properties, requiring careful handling and specialized safety measures in industrial applications.

What are the physicochemical properties of pentachloro-lambda5-phosphane?

Pentachloro-lambda5-phosphane is a phosphorus pentachloride compound that typically appears as a yellowish crystalline solid at room temperature. It has a pungent, irritating odor and readily hydrolyzes in contact with moisture, forming hydrogen chloride and phosphoric acid. The compound has limited solubility in water due to its reactive nature, but dissolves in certain organic solvents. Its high reactivity makes it sensitive to atmospheric humidity.

What is pentachloro-lambda5-phosphane used for?

Pentachloro-lambda5-phosphane serves primarily as a chlorinating agent in organic synthesis and chemical manufacturing processes. It is utilized in the production of organophosphorus compounds, pharmaceuticals intermediates, and specialty chemicals. The compound also finds applications in the synthesis of phosphorus-containing polymers and as a catalyst in certain chemical reactions. Its strong chlorinating properties make it valuable in industrial organic chemistry applications.

How to handle pentachloro-lambda5-phosphane safely?

Pentachloro-lambda5-phosphane requires strict safety protocols including wearing full protective equipment: chemical-resistant gloves, safety goggles, and respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods due to its corrosive and toxic nature. Avoid contact with skin, eyes, and inhalation of vapors. Emergency shower and eyewash stations should be readily accessible. Only trained personnel should handle this substance following established safety procedures.

How to store pentachloro-lambda5-phosphane correctly?

Pentachloro-lambda5-phosphane must be stored in tightly sealed, dry containers away from moisture and humidity. Storage areas should be cool, well-ventilated, and separated from incompatible materials such as water, alcohols, and organic compounds. The substance should be kept in original packaging with proper labeling and stored in designated chemical storage areas with appropriate secondary containment. Regular inspection for container integrity is essential.

What to do in case of contact with pentachloro-lambda5-phosphane?

Immediate action is required for any contact with pentachloro-lambda5-phosphane. For skin contact, remove contaminated clothing and flush affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water for 15-20 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek immediate medical attention in all cases. Do not induce vomiting if ingested.

How to dispose of pentachloro-lambda5-phosphane appropriately?

Pentachloro-lambda5-phosphane disposal must comply with local and European waste regulations as hazardous chemical waste. The substance cannot be disposed of through regular waste streams and requires specialized hazardous waste treatment facilities. Contact licensed waste management companies for proper collection and disposal. Small quantities may be neutralized under controlled conditions by trained professionals, but this should only be done following specific protocols and local regulations.

How to transport pentachloro-lambda5-phosphane?

Pentachloro-lambda5-phosphane is classified under ADR Class 8 (Corrosive substances), Packing Group II, indicating high transport hazards. Transportation requires specialized packaging meeting UN specifications, proper hazard labeling, and documentation including safety data sheets. Only authorized carriers trained in hazardous materials transport should handle shipments. Vehicles must be equipped with appropriate safety equipment and emergency response materials during transport.

Is pentachloro-lambda5-phosphane subject to specific regulations?

Pentachloro-lambda5-phosphane is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification standards. The substance is not currently listed as an SVHC (Substance of Very High Concern). Companies must comply with workplace safety regulations, proper labeling requirements showing GHS06, GHS08, and GHS05 pictograms, and maintain safety data sheets. Industrial users must implement risk management measures according to regulatory guidelines.

Where to buy pentachloro-lambda5-phosphane in Europe?

Pentachloro-lambda5-phosphane is available through specialized chemical distributors across Europe, including OYSI, a professional European distributor of technical chemicals. Due to its hazardous classification, purchases typically require verification of legitimate industrial use and proper handling capabilities. OYSI can provide technical support, safety documentation, and regulatory compliance assistance for European customers requiring this specialized chemical compound for industrial applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.