Pentanedial

C5H8O2

pentanedial

CAS111-30-8
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
111-30-8
EC Number
203-856-5
UN Number
3265
Index Number
605-022-00-X
PubChem CID
3485

Physical-chemical properties

Molecular Formula
C5H8O2
Molar Mass
100.12 g/mol
IUPAC Name
pentanedial

Chemical Identifiers

InChI
InChI=1S/C5H8O2/c6-4-2-1-3-5-7/h4-5H,1-3H2
InChI Key
SXRSQZLOMIGNAQ-UHFFFAOYSA-N

Overview

Pentanedial (CAS 111-30-8) is a linear dialdehyde compound with high reactivity and significant industrial crosslinking applications. This five-carbon dialdehyde, also known by its IUPAC name pentanedial, represents an important bifunctional organic compound in industrial chemistry. With the molecular formula C5H8O2 and a molecular weight of 100.12 g/mol, pentanedial features two terminal aldehyde groups that confer exceptional reactivity and versatility in chemical synthesis and materials science applications. The compound exhibits significant safety considerations due to its corrosive nature and multiple hazard classifications. Pentanedial is classified as acutely toxic (categories 2 and 3), a skin corrosive substance (category 1B), and presents respiratory and skin sensitization risks. The presence of GHS pictograms including skull and crossbones (GHS06), corrosion (GHS05), health hazard (GHS08), and environmental hazard (GHS09) reflects its comprehensive danger profile requiring careful handling protocols and appropriate personal protective equipment. In industrial applications, pentanedial serves primarily as a crosslinking agent in polymer chemistry, where its dual aldehyde functionality enables the formation of stable covalent bonds between polymer chains. The compound finds significant use in textile treatment processes for improving fabric properties and in the formulation of specialty adhesives and coatings. Unlike structurally different compounds such as 2-isocyanatoethylbenzene, which contains an isocyanate functional group, pentanedial's dialdehyde structure provides unique reactivity patterns particularly valuable in controlled polymerization reactions. The compound's ADR classification as Class 8 (corrosive substances) necessitates specialized transportation and storage requirements, ensuring proper containment and handling throughout the supply chain. OYSI maintains reliable supplies of high-quality pentanedial to support diverse industrial applications across European markets.

Safety & Classification

Danger
Classification:

Acute Tox. 2; Acute Tox. 3; STOT SE 3; Skin Corr. 1B; Resp. Sens. 1; Skin Sens. 1A; Aquatic Acute...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H314

Causes severe skin burns and eye damage.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H411

Toxic to aquatic life with long lasting effects.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3265
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameGlutardialdehyd, wässerige Lösung, Konz. <= 25 %
Marine PollutantNo

Frequently Asked Questions

What is pentanedial?

Pentanedial is a linear aliphatic dialdehyde with the molecular formula C5H8O2 and CAS number 111-30-8. It consists of a five-carbon chain with aldehyde groups at both ends, giving it the systematic name glutaraldehyde. With a molecular weight of 100.12 g/mol, this compound is classified as highly hazardous with multiple safety concerns including acute toxicity, skin corrosion, and respiratory sensitization properties.

What are the physicochemical properties of pentanedial?

Pentanedial is typically a colorless to pale yellow liquid with a pungent, acrid odor at room temperature. It is highly soluble in water and polar organic solvents due to its aldehyde functional groups. The compound has a tendency to polymerize in aqueous solutions, forming cyclic hemiacetals and other oligomeric structures. Its reactive nature makes it unstable in certain conditions, requiring careful handling and storage.

What is pentanedial used for?

Pentanedial is primarily used as a disinfectant and sterilizing agent in healthcare settings due to its potent antimicrobial properties. It serves as a cross-linking agent in protein and enzyme immobilization, leather tanning processes, and as a fixative in electron microscopy. Industrial applications include use as a biocide in water treatment systems and as an intermediate in pharmaceutical and chemical synthesis processes.

How to handle pentanedial safely?

Pentanedial requires extensive personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection due to its corrosive and sensitizing properties. Work must be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Given its Acute Tox. 2 classification and respiratory sensitization potential, minimize skin contact and vapor exposure. Use appropriate spill containment materials and ensure emergency eyewash stations are readily accessible.

How to store pentanedial correctly?

Pentanedial must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat sources and incompatible materials. Keep containers in secondary containment due to its corrosive nature (Skin Corr. 1B classification). Avoid storage near bases, strong oxidizers, and reactive metals. Maintain storage temperatures below 25°C to prevent decomposition and polymerization. Ensure storage areas have appropriate spill control measures and restricted access.

What to do in case of contact with pentanedial?

Immediate action is critical due to pentanedial's corrosive properties. For skin contact, remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention due to respiratory sensitization risks. For eye contact, rinse thoroughly with water for at least 15 minutes and remove contact lenses if present. Seek immediate medical attention for all exposure routes.

How to dispose of pentanedial appropriately?

Pentanedial waste must be disposed of as hazardous chemical waste through licensed waste management companies in compliance with local and EU regulations. The substance cannot be discharged to sewers or waterways due to its aquatic toxicity classification. Neutralization may be possible under controlled conditions by trained personnel, but typically requires professional hazardous waste disposal. Empty containers should also be treated as hazardous waste due to residual contamination risks.

How to transport pentanedial?

Pentanedial is classified as ADR Class 8 (corrosive substances), Packing Group II, requiring specialized packaging and documentation for transport. Shipments must use UN-approved packaging with appropriate hazard labels including corrosive placards. Transport vehicles need proper segregation from incompatible materials and emergency response information. Professional carriers experienced in hazardous chemical transport should handle shipments, ensuring compliance with international dangerous goods regulations.

Is pentanedial subject to specific regulations?

Pentanedial is regulated under multiple EU frameworks including CLP regulation due to its hazard classification and REACH regulation for chemical safety. Its respiratory sensitization properties (Resp. Sens. 1) may trigger workplace exposure limits and occupational health surveillance requirements. While not currently listed as SVHC, its hazardous properties require strict compliance with industrial emissions directives and worker protection regulations across EU member states.

Where to buy pentanedial in Europe?

Pentanedial is available through OYSI, a European distributor specializing in technical chemical products. OYSI provides reliable supply chains across Europe with proper hazardous material handling and regulatory compliance documentation. Given the substance's hazardous classification requiring specialized transport and handling, professional suppliers like OYSI ensure appropriate packaging, safety data sheets, and regulatory compliance for industrial and research applications throughout European markets.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.