Trichloromethylbenzene

C7H5Cl3

trichloromethylbenzene

CAS98-07-7
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

Consulting for Trichloromethylbenzene

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
98-07-7
EC Number
202-634-5
UN Number
2226
Index Number
602-038-00-9
PubChem CID
7367

Physical-chemical properties

Molecular Formula
C7H5Cl3
Molar Mass
195.50 g/mol
IUPAC Name
trichloromethylbenzene

Chemical Identifiers

InChI
InChI=1S/C7H5Cl3/c8-7(9,10)6-4-2-1-3-5-6/h1-5H
InChI Key
XEMRAKSQROQPBR-UHFFFAOYSA-N

Overview

Trichloromethylbenzene (CAS 98-07-7) is an aromatic organochlorine compound with significant industrial applications and notable safety considerations due to its carcinogenic properties. This chemical substance, also known by its systematic IUPAC name, represents an important intermediate in various industrial processes. With the molecular formula C7H5Cl3 and a molecular weight of 195.5 g/mol, trichloromethylbenzene consists of a benzene ring substituted with a trichloromethyl group. The compound is classified under EC number 202-634-5 and falls under ADR class 8, indicating its corrosive nature during transportation. The safety profile of trichloromethylbenzene requires careful attention, as it is classified as a Category 1B carcinogen under the GHS system. The substance also presents acute toxicity risks (categories 3 and 4), causes skin irritation (category 2), serious eye damage (category 1), and specific target organ toxicity following single exposure (category 3). These hazard classifications are reflected in the mandatory "Danger" signal word and the corresponding GHS pictograms GHS08 (health hazard), GHS06 (toxicity), and GHS05 (corrosion). In industrial applications, trichloromethylbenzene serves primarily as a chemical intermediate in organic synthesis, particularly in the production of pharmaceuticals and agrochemicals. It is also utilized in specialized polymer manufacturing processes and as a reagent in various chemical transformations. Unlike simpler organochlorine compounds such as pentachloro-lambda5-phosphane, trichloromethylbenzene's aromatic structure provides unique reactivity patterns that make it valuable for specific synthetic pathways. OYSI maintains reliable supplies of trichloromethylbenzene for qualified industrial customers throughout Europe, ensuring compliance with all applicable safety and transportation regulations.

Safety & Classification

Danger
Classification:

Carc. 1B; Acute Tox. 3 *; Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Dam. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

H331

Toxic if inhaled.

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H318

Causes serious eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2226
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameBenzotrichlorid
Marine PollutantNo

Frequently Asked Questions

What is trichloromethylbenzene?

Trichloromethylbenzene is an organic chemical compound with the molecular formula C7H5Cl3 and CAS number 98-07-7. This aromatic compound consists of a benzene ring substituted with a trichloromethyl group (-CCl3). With a molecular weight of 195.5 g/mol, it is classified as a hazardous substance due to its carcinogenic properties (Category 1B) and various toxicological effects. The compound presents significant safety concerns requiring careful handling and appropriate safety measures in industrial applications.

What are the physicochemical properties of trichloromethylbenzene?

Trichloromethylbenzene is typically a liquid at room temperature with characteristic aromatic properties. As an aromatic chlorinated compound, it exhibits low water solubility due to its hydrophobic nature, while being soluble in organic solvents. The presence of three chlorine atoms significantly increases its density compared to toluene. The compound has a distinctive chemical odor typical of chlorinated aromatics. Its physical state and properties make it suitable for various industrial applications where organic solvents are required.

What is trichloromethylbenzene used for?

Trichloromethylbenzene serves as an important intermediate in organic synthesis and chemical manufacturing processes. It is primarily used in the production of pharmaceuticals, agrochemicals, and specialty chemicals. The compound acts as a building block for various aromatic compounds and can be used in the synthesis of dyes and pigments. Due to its reactive trichloromethyl group, it participates in numerous chemical transformations, making it valuable in fine chemical synthesis and research applications within the pharmaceutical and chemical industries.

How to handle trichloromethylbenzene safely?

Trichloromethylbenzene requires strict safety protocols due to its carcinogenic and toxic properties. Personnel must wear appropriate PPE including chemical-resistant gloves, safety goggles, and respiratory protection when exposure is possible. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Avoid skin and eye contact completely. Use non-sparking tools and ensure proper grounding to prevent static discharge. Emergency shower and eyewash stations must be readily accessible. Only trained personnel should handle this substance.

How to store trichloromethylbenzene correctly?

Trichloromethylbenzene must be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Use appropriate chemical-resistant containers with tight-fitting lids to prevent vapor escape. Storage areas should be equipped with secondary containment and appropriate fire suppression systems. Keep away from strong bases, oxidizing agents, and reactive metals. Ensure proper labeling and segregation from other chemicals. Storage facilities must comply with local regulations for carcinogenic substances and maintain appropriate temperature control to prevent degradation.

What to do in case of contact with trichloromethylbenzene?

Immediate action is critical following contact with trichloromethylbenzene. For skin contact, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move victim to fresh air and provide respiratory support if needed. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician and provide the safety data sheet to medical personnel.

How to dispose of trichloromethylbenzene appropriately?

Trichloromethylbenzene disposal must comply with local and international hazardous waste regulations due to its carcinogenic classification. The substance cannot be disposed of through regular waste streams and requires specialized hazardous waste treatment facilities. Incineration at high temperatures with appropriate emission controls is typically the preferred disposal method. Small quantities should be collected in appropriate containers and transferred to licensed waste management companies. Empty containers must also be treated as hazardous waste. Always consult local environmental authorities for specific disposal requirements.

How to transport trichloromethylbenzene?

Trichloromethylbenzene is classified as ADR Class 8 (corrosive substances), Packing Group II, requiring specific transport protocols. Packaging must meet UN specification standards and be properly labeled with appropriate hazard placards and markings. Transport vehicles must be equipped with appropriate emergency equipment and drivers must hold ADR certification. Documentation including transport documents and emergency response information must accompany shipments. Segregation requirements must be observed, keeping the substance away from incompatible materials during transport. International shipping may require additional permits and documentation.

Is trichloromethylbenzene subject to specific regulations?

Trichloromethylbenzene is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification obligations. As a Category 1B carcinogen, it faces strict workplace exposure limits and may require authorization for certain uses. The substance must be properly classified, labeled, and accompanied by safety data sheets. Occupational health regulations mandate specific protective measures and medical surveillance for workers. Export/import may require permits depending on destination countries. Companies must maintain detailed records and comply with reporting obligations under chemical safety legislation.

Where to buy trichloromethylbenzene in Europe?

Trichloromethylbenzene is available through specialized chemical distributors in Europe, including OYSI, which supplies high-quality chemicals to industrial customers across the European market. Due to its hazardous classification, purchase typically requires proper business credentials and intended use documentation. Suppliers must provide comprehensive safety data sheets and ensure compliance with REACH and CLP regulations. Professional buyers should verify supplier certifications and quality standards. OYSI offers reliable supply chains and technical support for industrial customers requiring this specialized chemical compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.