Nickel(2+) carbonate

CNiO3

nickel(2+) carbonate

CAS3333-67-3
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
3333-67-3
EC Number
222-068-2
UN Number
3077
Index Number
028-010-00-0
PubChem CID
18746

Physical-chemical properties

Molecular Formula
CNiO3
Molar Mass
118.70 g/mol
IUPAC Name
nickel(2+) carbonate

Chemical Identifiers

InChI
InChI=1S/CH2O3.Ni/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
InChI Key
ZULUUIKRFGGGTL-UHFFFAOYSA-L

Overview

Nickel(2+) carbonate (CAS 3333-67-3) is an inorganic nickel salt with distinctive green crystalline properties and significant industrial applications. This chemical compound, also known by its IUPAC designation nickel(2+) carbonate, represents a critical intermediate in nickel chemistry and industrial processing. With the molecular formula CNiO3 and a molecular weight of 118.702 g/mol, this substance appears as a light green crystalline powder that serves multiple roles across various industrial sectors. The compound belongs to the family of nickel salts, sharing chemical relationships with other important nickel compounds such as nickel(2+) dihydroxide and nickel(2+) sulfate, which are frequently used in similar industrial applications. These related substances often appear together in nickel processing operations and electrochemical applications. Safety considerations are paramount when handling nickel(2+) carbonate, as it carries significant hazard classifications including carcinogenicity (Carc. 1A), mutagenicity (Muta. 2), and reproductive toxicity (Repr. 1B). The compound displays the "Danger" signal word and requires appropriate GHS08, GHS07, and GHS09 pictograms for proper identification. Its ADR Class 9 designation indicates it falls under miscellaneous dangerous substances for transportation purposes. Primary industrial applications include electroplating operations, where it serves as a nickel source for coating processes, catalyst preparation in chemical manufacturing, and ceramic colorant production for specialized industrial ceramics. The compound's consistent chemical properties make it particularly valuable in controlled industrial processes requiring reliable nickel content. OYSI maintains strategic inventory of nickel(2+) carbonate to support European industrial customers requiring this specialized chemical compound for their technical applications.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 1; Skin Irrit. 2; Resp. Sens...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickelcarbonat
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) carbonate?

Nickel(2+) carbonate is an inorganic chemical compound with the molecular formula CNiO3 and CAS number 3333-67-3. This nickel salt has a molecular weight of 118.702 g/mol and appears as a green crystalline solid. It is classified as a hazardous substance with multiple health risks including carcinogenic, mutagenic, and reproductive toxicity properties. The compound is widely used in industrial applications, particularly in electroplating and catalyst manufacturing processes.

What are the physicochemical properties of nickel(2+) carbonate?

Nickel(2+) carbonate is a green crystalline solid that is practically insoluble in water but soluble in acids and ammonia solutions. The compound is odorless and has a density higher than water. It decomposes upon heating to release carbon dioxide and form nickel oxide. The substance is stable under normal conditions but should be protected from moisture and acids to prevent decomposition reactions.

What is nickel(2+) carbonate used for?

Nickel(2+) carbonate is primarily used in electroplating operations to provide nickel coatings on metal surfaces. It serves as a precursor for manufacturing nickel catalysts used in hydrogenation reactions and other chemical processes. The compound is also utilized in the production of nickel oxide, ceramic glazes, and pigments. Additionally, it finds application in battery manufacturing and as a component in specialized chemical synthesis reactions.

How to handle nickel(2+) carbonate safely?

Nickel(2+) carbonate requires strict safety measures due to its carcinogenic and sensitizing properties. Personnel must wear appropriate respiratory protection, chemical-resistant gloves, and protective clothing to prevent skin contact and inhalation. Work should be conducted in well-ventilated areas or under fume hoods. Avoid generating dust and implement proper hygiene practices including thorough hand washing after handling. Emergency eyewash and shower facilities should be readily available.

How to store nickel(2+) carbonate correctly?

Nickel(2+) carbonate should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from incompatible materials such as strong acids and oxidizing agents. Storage areas must be secure and accessible only to trained personnel due to the substance's hazardous classification. Containers should be clearly labeled with appropriate hazard warnings and kept away from heat sources and moisture to prevent decomposition.

What to do in case of contact with nickel(2+) carbonate?

Skin contact with nickel(2+) carbonate requires immediate removal of contaminated clothing and thorough washing with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. For eye contact, flush with clean water for at least 15 minutes while holding eyelids open. In case of ingestion, do not induce vomiting and seek immediate medical care. Always consult a physician in case of exposure.

How to dispose of nickel(2+) carbonate appropriately?

Nickel(2+) carbonate must be disposed of as hazardous waste according to local and national regulations. The substance cannot be disposed of in regular waste streams due to its toxic and carcinogenic properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Recovery and recycling may be possible through specialized metal recovery processes. Always consult current waste disposal regulations and maintain proper documentation for waste disposal activities.

How to transport nickel(2+) carbonate?

Nickel(2+) carbonate is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transport purposes. The substance must be packaged in approved containers with proper hazard labels and documentation. Transport vehicles require appropriate placarding and drivers must have hazardous materials training. Shipping papers must include the correct technical name, UN number, and hazard class. Compliance with international transport regulations is mandatory for safe shipment.

Is nickel(2+) carbonate subject to specific regulations?

Nickel(2+) carbonate is subject to extensive regulations under REACH and CLP classifications due to its hazardous properties including carcinogenicity (Category 1A) and reproductive toxicity (Category 1B). The substance requires safety data sheets, hazard labeling with GHS pictograms (GHS07, GHS08, GHS09), and the signal word 'Danger'. Occupational exposure limits apply, and specific worker protection measures are mandated. Import, use, and handling must comply with national chemical safety regulations.

Where to buy nickel(2+) carbonate in Europe?

Nickel(2+) carbonate is available through OYSI, a specialized European distributor of technical chemicals. As an established chemical supplier, OYSI provides high-quality nickel(2+) carbonate with proper documentation including safety data sheets and certificates of analysis. The company serves industrial customers across Europe with reliable supply chains and technical support. Contact OYSI directly for availability, specifications, packaging options, and regulatory compliance documentation for your specific applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.