Nickel(2+) carbonate

CNiO3

nickel(2+) carbonate

CAS3333-67-3
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
3333-67-3
EC Number
222-068-2
UN Number
3077
Index Number
028-010-00-0
PubChem CID
18746

Physical-chemical properties

Molecular Formula
CNiO3
Molar Mass
118.70 g/mol
IUPAC Name
nickel(2+) carbonate

Chemical Identifiers

InChI
InChI=1S/CH2O3.Ni/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
InChI Key
ZULUUIKRFGGGTL-UHFFFAOYSA-L

Overview

Nickel(2+) carbonate (CAS 3333-67-3) is an inorganic salt compound with significant industrial applications and notable health hazard properties. This chemical substance, also known by its IUPAC designation nickel(2+) carbonate, represents a critical intermediate compound in nickel chemistry with the molecular formula CNiO3 and a molecular weight of 118.702 g/mol. As a member of the transition metal carbonate family, it shares chemical similarities with related nickel compounds such as nickel(2+) dihydroxide and nickel(2+) sulfate, which are frequently encountered in similar industrial processes. The compound presents significant safety considerations that require careful handling protocols. Classified under multiple hazard categories including carcinogenicity (Carc. 1A), mutagenicity (Muta. 2), and reproductive toxicity (Repr. 1B), nickel carbonate demands stringent workplace safety measures. The substance also exhibits acute toxicity properties, respiratory sensitization potential, and skin irritation characteristics, necessitating appropriate personal protective equipment and ventilation systems. Its classification under ADR Class 9 indicates specific transport requirements for safe logistics handling. In industrial applications, nickel(2+) carbonate serves primarily as a precursor in nickel catalyst preparation, particularly for hydrogenation processes in the chemical industry. It also functions as an intermediate in electroplating operations and in the production of specialized nickel-based materials for electronics manufacturing. The ceramics industry utilizes this compound for creating nickel-containing glazes and pigments. OYSI maintains reliable supply chains for nickel(2+) carbonate, ensuring consistent availability for European industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 1; Skin Irrit. 2; Resp. Sens...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickelcarbonat
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) carbonate?

Nickel(2+) carbonate is an inorganic chemical compound with the molecular formula CNiO3 and CAS number 3333-67-3. This nickel salt has a molecular weight of 118.702 g/mol and appears as a green crystalline solid. It is classified as a highly hazardous substance with carcinogenic, mutagenic, and reproductive toxicity properties, requiring strict handling protocols and safety measures in industrial applications.

What are the physicochemical properties of nickel(2+) carbonate?

Nickel(2+) carbonate is a green crystalline solid at room temperature with limited water solubility. The compound is stable under normal conditions but decomposes when heated, releasing carbon dioxide. It exhibits typical carbonate chemical behavior, reacting with acids to produce carbon dioxide gas. Its density and melting point vary depending on the specific hydrate form, with the compound often existing as hydrated crystals in commercial preparations.

What is nickel(2+) carbonate used for?

Nickel(2+) carbonate is primarily used in electroplating applications, ceramic glazes, and as a precursor for other nickel compounds. It serves as a catalyst in various chemical processes and is utilized in the production of nickel-based pigments for ceramics and glass industries. The compound also finds applications in battery manufacturing and as an intermediate in the synthesis of specialized nickel catalysts for industrial chemical reactions.

How to handle nickel(2+) carbonate safely?

Safe handling of nickel(2+) carbonate requires appropriate personal protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction systems due to its respiratory sensitizing properties. Avoid generating dust and prevent skin contact. Regular health monitoring is recommended for workers exposed to this carcinogenic substance, and strict adherence to occupational exposure limits is essential.

How to store nickel(2+) carbonate correctly?

Proper storage of nickel(2+) carbonate requires a dry, cool, well-ventilated area away from incompatible materials such as strong acids and reducing agents. Containers should be tightly sealed to prevent moisture absorption and dust generation. Storage areas must be clearly labeled with appropriate hazard warnings and equipped with spill containment measures. Access should be restricted to trained personnel only, with emergency response equipment readily available.

What to do in case of contact with nickel(2+) carbonate?

In case of skin contact with nickel(2+) carbonate, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. For eye contact, flush with clean water for at least 15 minutes and remove contact lenses if present. Seek immediate medical attention in all cases of exposure, informing healthcare providers of the specific chemical involved.

How to dispose of nickel(2+) carbonate appropriately?

Disposal of nickel(2+) carbonate must comply with local and national hazardous waste regulations due to its classification as a carcinogenic substance. The material should be collected by licensed hazardous waste contractors for treatment at authorized facilities. Never dispose of this compound in regular waste streams or sewage systems. Contaminated packaging and materials must also be treated as hazardous waste and disposed of through appropriate channels with proper documentation.

How to transport nickel(2+) carbonate?

Transportation of nickel(2+) carbonate is regulated under ADR Class 9 (Miscellaneous Dangerous Goods), Packing Group III. Proper shipping documentation, labeling with appropriate hazard pictogramms (GHS08, GHS07, GHS09), and packaging in UN-approved containers are mandatory. Vehicles must carry appropriate emergency response information and drivers require hazardous materials training. The danger signal word 'DANGER' must be clearly displayed on all transport documentation and packaging.

Is nickel(2+) carbonate subject to specific regulations?

Yes, nickel(2+) carbonate is subject to extensive regulations under REACH and CLP due to its classification as Carcinogenic 1A, Mutagenic 2, and Reproductive toxicant 1B. Companies must comply with registration requirements, safety data sheet provisions, and exposure scenario documentation. Occupational exposure limits apply, and the substance requires authorization for certain uses. Import and use may be restricted in various applications, particularly those involving consumer exposure or environmental release.

Where to buy nickel(2+) carbonate in Europe?

Nickel(2+) carbonate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across the continent. OYSI provides compliant packaging, proper documentation, and technical support for this regulated substance. Due to its hazardous classification, purchases are typically restricted to qualified industrial users with appropriate handling facilities and safety protocols. Contact OYSI directly for availability, specifications, and regulatory compliance support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.