Nickel(2+) dihydroxide

H2NiO2

nickel(2+) dihydroxide

CAS12054-48-7
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
12054-48-7
EC Number
235-008-5
UN Number
3077
Index Number
028-008-00-X
PubChem CID
61534

Physical-chemical properties

Molecular Formula
H2NiO2
Molar Mass
92.71 g/mol
IUPAC Name
nickel(2+) dihydroxide

Chemical Identifiers

InChI
InChI=1S/Ni.2H2O/h;2*1H2/q+2;;/p-2
InChI Key
BFDHFSHZJLFAMC-UHFFFAOYSA-L

Overview

Nickel(2+) dihydroxide (CAS 12054-48-7) is an inorganic hydroxide compound with strong oxidizing properties and significant health hazards. This green crystalline compound, also known by its IUPAC name nickel(2+) dihydroxide, represents an important nickel-based chemical intermediate in various industrial applications. With the molecular formula H2NiO2 and a molecular weight of 92.708 g/mol, this substance exhibits the characteristic properties of transition metal hydroxides while presenting serious safety considerations that require careful handling protocols. The compound is classified under multiple hazard categories, including carcinogenic (Category 1A), mutagenic (Category 2), and reproductive toxicity (Category 1B) properties. Its danger classification extends to acute toxicity, specific target organ toxicity after repeated exposure, skin irritation, and respiratory sensitization. The presence of GHS08, GHS07, and GHS09 pictograms on safety documentation reflects these serious health and environmental concerns. As an ADR Class 9 substance, special transportation requirements apply for commercial distribution. In industrial applications, nickel(2+) dihydroxide serves primarily as a precursor in battery manufacturing, particularly for nickel-metal hydride and nickel-cadmium battery systems. The compound also functions as a catalyst in various chemical processes and finds use in electroplating operations. These applications often involve related nickel compounds such as nickel(2+) carbonate and nickel(2+) sulfate, which share similar industrial utility but differ in their specific chemical properties and handling requirements. Given its hazardous nature, proper personal protective equipment, adequate ventilation systems, and strict adherence to safety protocols are essential when working with this material. OYSI provides technical-grade nickel(2+) dihydroxide with comprehensive safety documentation to qualified industrial customers across Europe.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 1; Skin Irrit. 2; Resp. Sens...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickeldihydroxid
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) dihydroxide?

Nickel(2+) dihydroxide is an inorganic chemical compound with the formula H2NiO2 and CAS number 12054-48-7. This nickel salt has a molecular weight of 92.708 g/mol and appears as a green crystalline solid. It is classified as a highly hazardous substance with carcinogenic, mutagenic, and reproductive toxicity properties, requiring careful handling and specialized safety measures in industrial applications.

What are the physicochemical properties of nickel(2+) dihydroxide?

Nickel(2+) dihydroxide is a green crystalline solid that is poorly soluble in water but dissolves in acids and ammonia solutions. The compound is stable under normal conditions but decomposes upon heating to form nickel oxide. It has a density of approximately 4.1 g/cm³ and exhibits basic properties due to its hydroxide groups, making it reactive with acids to form nickel salts.

What is nickel(2+) dihydroxide used for?

Nickel(2+) dihydroxide is primarily used in the production of nickel-cadmium batteries as a cathode material. It serves as a precursor for manufacturing other nickel compounds and catalysts in chemical processes. The compound is also utilized in electroplating applications, ceramic production, and as a component in specialized coatings. Its applications are strictly regulated due to its hazardous classification.

How to handle nickel(2+) dihydroxide safely?

Nickel(2+) dihydroxide requires strict safety measures including respiratory protection, chemical-resistant gloves, and protective clothing due to its carcinogenic and sensitizing properties. Work must be conducted in well-ventilated areas or under fume extraction systems. Avoid skin contact and inhalation of dust particles. Use appropriate containment measures to prevent environmental release and ensure all personnel are trained in hazardous material handling procedures.

How to store nickel(2+) dihydroxide correctly?

Nickel(2+) dihydroxide must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials such as strong acids and oxidizing agents. Storage areas should be equipped with appropriate containment systems and restricted access due to the compound's hazardous classification. Containers should be properly labeled and stored according to local regulations for carcinogenic substances.

What to do in case of contact with nickel(2+) dihydroxide?

Nickel(2+) dihydroxide contact requires immediate action: for skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. Seek immediate medical attention for all exposures due to the compound's carcinogenic and toxic properties.

How to dispose of nickel(2+) dihydroxide appropriately?

Nickel(2+) dihydroxide disposal must comply with local and national hazardous waste regulations due to its classification as a carcinogenic and environmentally hazardous substance. The material cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment facilities. Contact licensed waste disposal companies and follow all regulatory requirements for documentation, packaging, and transportation of this hazardous material.

How to transport nickel(2+) dihydroxide?

Nickel(2+) dihydroxide is classified as ADR Class 9 (miscellaneous dangerous goods), Packing Group III for transportation purposes. It requires appropriate packaging, labeling with GHS pictogrammes (GHS08, GHS07, GHS09), and proper shipping documentation. Transport must comply with ADR regulations for dangerous goods, including driver training requirements and vehicle specifications for Class 9 materials.

Is nickel(2+) dihydroxide subject to specific regulations?

Nickel(2+) dihydroxide is subject to strict regulations under REACH and CLP legislation in Europe due to its classification as Carcinogenic 1A, Mutagenic 2, and Reproductive toxicant 1B. It requires safety data sheets, hazard labeling with 'Danger' signal word, and compliance with occupational exposure limits. Users must implement risk management measures and may require authorization for certain uses under REACH.

Where to buy nickel(2+) dihydroxide in Europe?

Nickel(2+) dihydroxide is available through specialized chemical distributors in Europe, including OYSI, which supplies industrial chemicals to European markets. Due to its hazardous classification, purchase requires proper documentation, safety compliance verification, and adherence to regulatory requirements. Buyers must demonstrate appropriate handling capabilities and legitimate industrial use before procurement of this restricted chemical substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.