Nickel(2+) dihydroxide

H2NiO2

nickel(2+) dihydroxide

CAS12054-48-7
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
12054-48-7
EC Number
235-008-5
UN Number
3077
Index Number
028-008-00-X
PubChem CID
61534

Physical-chemical properties

Molecular Formula
H2NiO2
Molar Mass
92.71 g/mol
IUPAC Name
nickel(2+) dihydroxide

Chemical Identifiers

InChI
InChI=1S/Ni.2H2O/h;2*1H2/q+2;;/p-2
InChI Key
BFDHFSHZJLFAMC-UHFFFAOYSA-L

Overview

Nickel(2+) dihydroxide (CAS 12054-48-7) is an inorganic nickel compound with alkaline properties and significant industrial applications in electrochemical processes. This green crystalline powder represents one of the most important nickel hydroxide compounds used in modern industrial applications. As a divalent nickel compound with the molecular formula H2NiO2 and EC number 235-008-5, nickel(2+) dihydroxide exhibits unique electrochemical properties that make it valuable in various technical processes. The compound belongs to the same chemical family as other nickel salts such as nickel(2+) carbonate and nickel(2+) sulfate, sharing similar coordination chemistry but offering distinct solubility and reactivity characteristics. The substance presents significant safety considerations due to its classification as a Category 1A carcinogen, mutagen, and reproductive toxicant. It carries the signal word "Danger" and displays GHS pictograms GHS08, GHS07, and GHS09, indicating serious health hazards including respiratory sensitization, skin irritation, and environmental concerns. As a Class 9 ADR substance, it requires appropriate handling protocols and specialized storage conditions to ensure worker safety and environmental protection. Primary industrial applications include battery manufacturing, particularly in nickel-metal hydride (NiMH) batteries where it serves as a key cathode material, electroplating processes for corrosion-resistant coatings, and catalyst preparation in various chemical synthesis reactions. The compound's electrochemical stability and hydroxide ion availability make it essential in these specialized applications. OYSI maintains reliable supply chains for nickel(2+) dihydroxide, ensuring consistent quality and regulatory compliance for European industrial customers requiring this critical nickel compound.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 1; Skin Irrit. 2; Resp. Sens...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickeldihydroxid
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) dihydroxide?

Nickel(2+) dihydroxide is an inorganic compound with the chemical formula H2NiO2 and CAS number 12054-48-7. This nickel salt has a molecular weight of 92.708 g/mol and appears as a green crystalline solid. It is classified as a highly hazardous substance with carcinogenic, mutagenic, and reproductive toxicity properties. The compound requires careful handling due to its significant health risks and environmental concerns.

What are the physicochemical properties of nickel(2+) dihydroxide?

Nickel(2+) dihydroxide is a green crystalline solid that is poorly soluble in water but soluble in acids and ammonia solutions. The compound is stable under normal conditions but decomposes upon heating to form nickel oxide. It has a density of approximately 4.15 g/cm³ and exhibits basic properties due to the hydroxide groups in its structure.

What is nickel(2+) dihydroxide used for?

Nickel(2+) dihydroxide is primarily used in the production of nickel-cadmium batteries as an active cathode material. It serves as a precursor for manufacturing other nickel compounds and catalysts in chemical processes. The compound is also utilized in electroplating applications and as a component in certain specialized coatings and ceramic formulations in industrial settings.

How to handle nickel(2+) dihydroxide safely?

Nickel(2+) dihydroxide requires strict safety measures including respiratory protection, chemical-resistant gloves, and protective clothing due to its carcinogenic and sensitizing properties. Work should be conducted in well-ventilated areas or under fume extraction. Avoid skin contact and inhalation of dust particles. Emergency eyewash stations and safety showers must be readily accessible when handling this dangerous substance.

How to store nickel(2+) dihydroxide correctly?

Nickel(2+) dihydroxide should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Keep containers away from heat sources and direct sunlight. Store separately from acids, oxidizing agents, and food products. Ensure proper labeling with hazard warnings and maintain an inventory of quantities due to its hazardous classification.

What to do in case of contact with nickel(2+) dihydroxide?

In case of skin contact with nickel(2+) dihydroxide, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention. For eye contact, rinse with plenty of water for at least 15 minutes and remove contact lenses if present. Seek immediate medical attention in all cases of exposure.

How to dispose of nickel(2+) dihydroxide appropriately?

Nickel(2+) dihydroxide must be disposed of as hazardous waste according to local and national regulations. The compound cannot be disposed of in regular waste streams due to its toxic and carcinogenic properties. Contact authorized waste disposal companies for proper collection and treatment. Small quantities should be neutralized and treated by qualified professionals before final disposal in approved hazardous waste facilities.

How to transport nickel(2+) dihydroxide?

Nickel(2+) dihydroxide is classified as ADR Class 9 (miscellaneous dangerous goods), Packing Group III for transportation purposes. It requires appropriate hazardous goods packaging, labeling, and documentation during transport. Vehicles must carry proper safety equipment and emergency response information. Only trained personnel should handle the transportation, following all relevant dangerous goods regulations for road, rail, or sea transport.

Is nickel(2+) dihydroxide subject to special regulations?

Nickel(2+) dihydroxide is subject to strict regulations under REACH and CLP due to its classification as carcinogenic (1A), mutagenic (2), and reprotoxic (1B). It requires safety data sheets, exposure scenarios, and risk assessments. The compound may be subject to authorization requirements and workplace exposure limits. Users must comply with occupational health regulations and environmental protection measures when handling this substance.

Where to buy nickel(2+) dihydroxide in Europe?

Nickel(2+) dihydroxide is available through OYSI, a European distributor of technical chemicals specializing in hazardous substances. As an authorized supplier, OYSI provides proper documentation, safety data sheets, and regulatory compliance support. Due to the compound's hazardous nature, purchases require proper authorization and adherence to safety regulations. Contact OYSI directly for availability, technical specifications, and delivery arrangements across Europe.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.