Selanylidenenickel

NiSe

selanylidenenickel

CAS1314-05-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1314-05-2
EC Number
215-216-2
UN Number
3077
Index Number
028-049-00-3
PubChem CID
62394

Physical-chemical properties

Molecular Formula
NiSe
Molar Mass
137.66 g/mol
IUPAC Name
selanylidenenickel

Chemical Identifiers

InChI
InChI=1S/Ni.Se
InChI Key
QHASIAZYSXZCGO-UHFFFAOYSA-N

Overview

Selanylidenenickel (CAS 1314-05-2) is an inorganic nickel selenide compound with semiconductor properties and high toxicity classification. Selanylidenenickel represents a significant compound in the transition metal chalcogenide family, combining nickel and selenium in a 1:1 stoichiometric ratio. This crystalline material exhibits unique electronic and optical properties that make it valuable in specialized industrial applications, despite its considerable health and environmental hazards. The compound's molecular structure creates a semiconductor with distinctive characteristics that differentiate it from related materials such as sulfanylidenenickel, where sulfur replaces selenium in the crystal lattice. The substance carries severe safety classifications, including Category 1A carcinogenicity and Category 1 specific target organ toxicity following repeated exposure. These hazard classifications necessitate stringent handling protocols and specialized safety equipment during storage, transport, and processing. The compound also presents significant environmental risks, classified as both acutely and chronically toxic to aquatic life, requiring careful waste management and containment procedures. Industrial applications of selanylidenenickel primarily focus on semiconductor technology and specialized alloy production. The material serves as a precursor in the synthesis of advanced semiconductor devices and thin-film applications where its unique electronic properties are essential. Additionally, it finds use in specialized catalyst formulations and in the production of certain types of photovoltaic cells where selenium-based compounds offer specific performance advantages. OYSI maintains availability of selanylidenenickel for qualified industrial customers, ensuring proper regulatory compliance and safe handling documentation for all shipments throughout Europe.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickel(II)-selenid
Marine PollutantNo

Frequently Asked Questions

What is selanylidenenickel?

Selanylidenenickel is an inorganic compound with the molecular formula NiSe and CAS number 1314-05-2. It represents a binary compound of nickel and selenium with a molecular weight of 137.66 g/mol. This material is classified as a highly hazardous substance with carcinogenic properties (Category 1A) and poses significant risks to human health and the environment. It requires specialized handling procedures and is subject to strict regulatory controls due to its dangerous nature.

What are the physicochemical properties of selanylidenenickel?

Selanylidenenickel appears as a solid crystalline material at room temperature. As a nickel selenide compound, it typically exhibits metallic luster and semiconductor properties. The compound has limited solubility in water but may react with acids. Its physicochemical behavior is influenced by the presence of both nickel and selenium atoms in its structure, contributing to its specific electronic and thermal properties that make it suitable for specialized industrial applications.

What is selanylidenenickel used for?

Selanylidenenickel is primarily used in specialized industrial applications including semiconductor manufacturing, electronic components, and advanced materials research. Its unique electronic properties make it valuable in the production of photovoltaic devices and thermoelectric materials. Due to its hazardous classification, its use is restricted to professional industrial settings with appropriate safety controls and environmental protection measures. Applications require specialized expertise and compliance with strict safety protocols.

How to handle selanylidenenickel safely?

Selanylidenenickel requires extensive personal protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing due to its carcinogenic and sensitizing properties. Work must be conducted in well-ventilated areas or under controlled atmosphere conditions. Personnel must be trained in hazardous material handling and emergency procedures. Skin contact must be avoided at all costs due to sensitization risks, and inhalation protection is mandatory to prevent systemic toxicity effects.

How to store selanylidenenickel correctly?

Selanylidenenickel must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas should be equipped with appropriate containment systems and restricted access due to the carcinogenic nature of the material. The compound should be kept away from acids, oxidizing agents, and moisture. Secondary containment is recommended, and storage facilities must comply with local regulations for carcinogenic substances and environmental protection requirements.

What to do in case of contact with selanylidenenickel?

Immediate medical attention is required for any contact with selanylidenenickel. In case of skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical care. For eye contact, rinse with clean water for at least 15 minutes. Due to its carcinogenic properties, all exposure incidents must be documented and reported to occupational health services for proper medical follow-up.

How to dispose of selanylidenenickel appropriately?

Selanylidenenickel disposal must be handled by licensed hazardous waste management companies due to its carcinogenic classification and environmental toxicity. The material cannot be disposed of through regular waste streams and requires specialized treatment methods. Disposal must comply with local and EU regulations for carcinogenic substances and aquatic pollutants. All disposal activities must be properly documented, and waste containers must be clearly labeled with appropriate hazard information before collection by authorized waste management services.

How to transport selanylidenenickel?

Selanylidenenickel is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. Transport requires appropriate packaging, labeling with GHS pictograms (GHS08, GHS07, GHS09), and accompanying documentation including safety data sheets. Shipments must comply with dangerous goods transport regulations and be handled by carriers qualified for hazardous materials. Special precautions are needed to prevent package damage and environmental release during transit.

Is selanylidenenickel subject to specific regulations?

Selanylidenenickel is subject to extensive European regulations under REACH and CLP due to its carcinogenic Category 1A classification. The substance requires safety data sheets, hazard communication, and may be subject to authorization procedures. Its classification as STOT RE 1 and aquatic toxicity categories impose additional restrictions on use and handling. Companies using this material must comply with occupational health regulations, environmental protection requirements, and may need specialized permits depending on the application and quantities involved.

Where to buy selanylidenenickel in Europe?

Selanylidenenickel is available through specialized chemical distributors in Europe, including OYSI, which supplies high-quality chemical products to industrial customers. Due to its hazardous classification, procurement requires proper documentation, safety protocols, and compliance with regulatory requirements. OYSI provides technical support and ensures proper packaging, labeling, and documentation for safe delivery. Customers must demonstrate appropriate handling capabilities and regulatory compliance before purchase approval for this controlled substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.