Selanylidenenickel

NiSe

selanylidenenickel

CAS1314-05-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for Selanylidenenickel

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
1314-05-2
EC Number
215-216-2
UN Number
3077
Index Number
028-049-00-3
PubChem CID
62394

Physical-chemical properties

Molecular Formula
NiSe
Molar Mass
137.66 g/mol
IUPAC Name
selanylidenenickel

Chemical Identifiers

InChI
InChI=1S/Ni.Se
InChI Key
QHASIAZYSXZCGO-UHFFFAOYSA-N

Overview

Selanylidenenickel (CAS 1314-05-2) is an inorganic nickel selenide compound with semiconductor properties and notable toxicological concerns. This binary chalcogenide represents an important material in advanced materials science and electronic applications. Selanylidenenickel forms part of the transition metal selenide family, sharing structural similarities with related compounds such as sulfanylidenenickel, though exhibiting distinct electronic and optical properties due to selenium's larger atomic radius and different electronegativity. The compound crystallizes in a hexagonal structure and demonstrates semiconductor behavior with a narrow bandgap, making it valuable for specialized electronic and optoelectronic applications. The safety profile of selanylidenenickel requires careful consideration due to its classification as a Category 1A carcinogen and specific target organ toxicant. The compound poses significant health risks including skin sensitization and potential respiratory tract damage following repeated exposure. Environmental concerns are equally important, as the substance exhibits acute and chronic aquatic toxicity. Proper handling protocols must include appropriate personal protective equipment, controlled atmosphere processing, and specialized waste management procedures to minimize exposure risks. Industrial applications primarily focus on advanced materials manufacturing, particularly in the production of specialized semiconductors and photovoltaic devices. The compound serves as a precursor in thin-film deposition processes and finds use in certain catalytic applications where its unique electronic properties provide specific advantages. Research applications include studies in quantum dot synthesis and advanced battery electrode materials. OYSI maintains professional-grade selanylidenenickel supplies for qualified industrial customers, ensuring full regulatory compliance and comprehensive safety documentation for all shipments.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickel(II)-selenid
Marine PollutantNo

Frequently Asked Questions

What is selanylidenenickel?

Selanylidenenickel is an inorganic compound with the chemical formula NiSe, consisting of nickel and selenium atoms in a 1:1 ratio. This binary compound has a molecular weight of 137.66 g/mol and is classified under CAS number 1314-05-2. It belongs to the family of transition metal selenides and exhibits semiconductor properties. The compound is considered highly hazardous, classified as a Category 1A carcinogen with additional concerns for skin sensitization and environmental toxicity.

What are the physicochemical properties of selanylidenenickel?

Selanylidenenickel typically appears as a dark crystalline solid with metallic luster at room temperature. The compound has a molecular weight of 137.66 g/mol and exhibits semiconductor properties characteristic of transition metal selenides. It is generally insoluble in water but may react with strong acids. The material demonstrates stability under normal conditions but requires careful handling due to its toxic nature. Its crystal structure and electrical properties make it suitable for specialized electronic applications.

What is selanylidenenickel used for?

Selanylidenenickel is primarily used in specialized electronic and semiconductor applications due to its unique electrical properties. It serves as a component in certain photovoltaic cells, electronic devices, and research applications involving transition metal selenides. The compound may also be utilized in catalysis research and materials science studies. Given its hazardous classification, its use is typically restricted to professional and industrial settings with appropriate safety controls and expertise in handling toxic materials.

How to handle selanylidenenickel safely?

Selanylidenenickel requires extreme caution due to its carcinogenic and sensitizing properties. Essential personal protective equipment includes respiratory protection with appropriate filters, chemical-resistant gloves, safety goggles, and protective clothing covering all exposed skin. Work must be conducted in well-ventilated areas, preferably under fume hoods or controlled atmospheres. Avoid generating dust or vapors, and never eat, drink, or smoke in work areas. Regular health monitoring and training in hazardous material handling are essential for all personnel.

How to store selanylidenenickel correctly?

Selanylidenenickel must be stored in tightly sealed, chemically compatible containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas should be restricted to authorized personnel only, with appropriate warning signage and secondary containment measures. Keep away from sources of heat, sparks, and direct sunlight. The storage facility should have emergency response equipment readily available and comply with local regulations for carcinogenic substances. Regular inventory checks and container integrity inspections are recommended.

What to do in case of contact with selanylidenenickel?

Immediate decontamination is crucial following any contact with selanylidenenickel. For skin contact, remove contaminated clothing and wash affected areas thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention. For eye contact, flush with clean water for 15 minutes and remove contact lenses if present. In all cases of exposure, seek immediate medical attention and inform healthcare providers about the carcinogenic nature of the substance and potential for sensitization.

How to dispose of selanylidenenickel properly?

Selanylidenenickel disposal must comply with local and international hazardous waste regulations due to its carcinogenic and environmentally toxic properties. The material cannot be disposed of through regular waste streams and requires specialized hazardous waste treatment facilities. Contact licensed hazardous waste disposal companies with experience in heavy metal and carcinogenic compounds. Maintain detailed disposal records and certificates of destruction. Never attempt to neutralize, dilute, or dispose of the material without proper authorization and expertise.

How to transport selanylidenenickel?

Selanylidenenickel is classified as ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. Packages must be properly labeled with appropriate hazard markings and documentation must include proper shipping names and hazard classifications. Vehicles transporting this material require appropriate ADR certification and drivers must have hazardous materials training. Emergency response information must accompany shipments, and transport should follow designated routes with appropriate emergency response capabilities available along the route.

Is selanylidenenickel subject to specific regulations?

Selanylidenenickel is subject to extensive European regulations including REACH registration requirements and CLP classification as a Category 1A carcinogen. While not currently listed as a Substance of Very High Concern (SVHC), its carcinogenic classification subjects it to strict occupational exposure limits and workplace controls. Users must comply with industrial emissions directives, waste framework regulations, and may require specific permits for use. Regular monitoring, risk assessments, and worker health surveillance programs are typically mandatory under occupational safety regulations.

Where to buy selanylidenenickel in Europe?

Selanylidenenickel is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous materials. As a professional chemical distributor, OYSI provides proper documentation, safety data sheets, and regulatory compliance support for this highly regulated substance. Given the material's carcinogenic classification and strict handling requirements, purchase is typically restricted to qualified industrial users with appropriate safety infrastructure and regulatory permits. Contact OYSI directly to discuss specific requirements, quantities, and compliance documentation needed for your application.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.