Nickel(2+);oxalate

C2NiO4

nickel(2+);oxalate

CAS547-67-1
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
547-67-1
EC Number
208-933-7
UN Number
3077
Index Number
028-039-00-9
PubChem CID
68354

Physical-chemical properties

Molecular Formula
C2NiO4
Molar Mass
146.71 g/mol
IUPAC Name
nickel(2+);oxalate

Chemical Identifiers

InChI
InChI=1S/C2H2O4.Ni/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
InChI Key
DOLZKNFSRCEOFV-UHFFFAOYSA-L

Overview

Nickel(2+) oxalate (CAS 547-67-1) is an inorganic nickel salt compound with carcinogenic properties and significant environmental hazard potential. This crystalline coordination compound consists of nickel ions in the +2 oxidation state combined with oxalate anions, forming a stable complex with the molecular formula C2NiO4. As a member of the transition metal oxalate family, nickel(2+) oxalate shares structural similarities with other nickel compounds such as sulfanylidenenickel and selanylidenenickel, though it exhibits distinct chemical behavior due to the oxalate ligand coordination. The compound presents serious health and safety considerations, classified as a Category 1A carcinogen with the potential for specific target organ toxicity following repeated exposure. Its classification as a skin sensitizer requires careful handling protocols, while its acute and chronic aquatic toxicity designations reflect significant environmental concerns. The GHS08, GHS07, and GHS09 pictograms emphasize the multiple hazard categories associated with this material, necessitating comprehensive risk management strategies in industrial applications. Nickel(2+) oxalate finds primary application in specialized catalytic processes, particularly in organic synthesis reactions where controlled nickel release is required. The compound also serves as a precursor material in the preparation of nickel-based catalysts and advanced materials manufacturing. Additionally, it functions as an intermediate in certain electroplating and surface treatment processes where precise nickel deposition control is essential. Due to its ADR Class 9 classification as a miscellaneous dangerous substance, transportation and storage require adherence to specific regulatory requirements. OYSI maintains availability of nickel(2+) oxalate for qualified industrial customers with appropriate handling capabilities and regulatory compliance frameworks.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickeloxalat
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+);oxalate?

Nickel(2+);oxalate is an inorganic chemical compound with the molecular formula C2NiO4 and CAS number 547-67-1. This substance consists of nickel ions in the +2 oxidation state combined with oxalate anions, forming a crystalline salt with a molecular weight of 146.71 g/mol. It is classified as a Category 1A carcinogen and requires careful handling due to its significant health hazards including skin sensitization and specific target organ toxicity.

What are the physicochemical properties of nickel(2+);oxalate?

Nickel(2+);oxalate typically appears as a light green crystalline solid at room temperature. The compound has limited solubility in water and most organic solvents, which is characteristic of metal oxalate salts. It is odorless and stable under normal conditions. The molecular structure consists of nickel cations coordinated with oxalate ligands, giving it distinctive chemical properties typical of transition metal coordination compounds.

What is nickel(2+);oxalate used for?

Nickel(2+);oxalate is primarily used as a precursor in the preparation of nickel catalysts and other nickel-containing materials. It serves as an intermediate in metallurgical processes and can be used in electroplating applications. The compound is also utilized in research and development for synthesizing specialized nickel compounds. Due to its carcinogenic properties, its use is restricted to professional and industrial applications with appropriate safety controls.

How to handle nickel(2+);oxalate safely?

Nickel(2+);oxalate requires strict safety measures due to its carcinogenic and sensitizing properties. Always wear appropriate personal protective equipment including nitrile gloves, safety goggles, and respiratory protection. Work in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin contact and use proper handling techniques to minimize dust generation. Regular health monitoring is recommended for workers with occupational exposure to this substance.

How to store nickel(2+);oxalate correctly?

Nickel(2+);oxalate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Keep containers away from sources of ignition and moisture. Store in designated areas with restricted access due to its carcinogenic classification. Ensure proper labeling with GHS pictograms (GHS08, GHS07, GHS09) and maintain an inventory record. Avoid storage near acids or strong oxidizing agents that could cause decomposition.

What to do in case of contact with nickel(2+);oxalate?

Skin contact with nickel(2+);oxalate requires immediate removal of contaminated clothing and thorough washing of affected areas with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. In case of eye contact, rinse thoroughly with clean water for at least 15 minutes and remove contact lenses if present. Always seek immediate medical attention for any exposure, informing healthcare providers of the carcinogenic nature of the substance.

How to dispose of nickel(2+);oxalate appropriately?

Nickel(2+);oxalate must be disposed of as hazardous waste through licensed waste management companies due to its carcinogenic properties and environmental toxicity. Never discharge into drains, soil, or waterways as it is classified as aquatic toxic. Collect waste in appropriate containers and label clearly. Follow local and national regulations for hazardous waste disposal, including proper documentation and manifests. Consider recovery or recycling options where available for nickel-containing compounds.

How to transport nickel(2+);oxalate?

Nickel(2+);oxalate is classified as ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. It must be packaged in UN-approved containers with proper labeling and documentation. Transport vehicles must carry appropriate emergency response information and placards. Drivers require ADR training for Class 9 materials. Ensure proper segregation from incompatible materials during transport and follow all applicable dangerous goods regulations for road, rail, or sea transport.

Is nickel(2+);oxalate subject to specific regulations?

Nickel(2+);oxalate is subject to comprehensive chemical regulations including REACH registration requirements and CLP classification as a Category 1A carcinogen. It requires safety data sheets and appropriate hazard communication. Occupational exposure limits apply in workplace settings, and specific authorization may be required for certain uses. The substance is regulated under dangerous goods transport legislation and environmental protection laws due to its aquatic toxicity classification.

Where to buy nickel(2+);oxalate in Europe?

Nickel(2+);oxalate is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical supplier, OYSI can provide this regulated substance to qualified industrial customers with appropriate safety protocols and documentation. Due to its carcinogenic classification, purchase requires proper authorization and compliance with chemical regulations. Contact OYSI directly to discuss specific requirements, quantities, and regulatory compliance for your application needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.