Nickel(2+) sulfate

NiO4S

nickel(2+) sulfate

CAS7786-81-4
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7786-81-4
EC Number
232-104-9
UN Number
3288
Index Number
028-009-00-5
PubChem CID
24586

Physical-chemical properties

Molecular Formula
NiO4S
Molar Mass
154.76 g/mol
IUPAC Name
nickel(2+) sulfate

Chemical Identifiers

InChI
InChI=1S/Ni.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2
InChI Key
LGQLOGILCSXPEA-UHFFFAOYSA-L

Overview

Nickel(2+) sulfate (CAS 7786-81-4) is an inorganic salt compound with strong oxidizing properties and high water solubility. This crystalline sulfate salt represents one of the most commercially significant nickel compounds in industrial applications. As a member of the transition metal sulfate family, nickel(2+) sulfate exhibits distinctive green coloration in its hexahydrate form and demonstrates excellent solubility in water, making it highly versatile for various chemical processes. The compound's molecular formula NiO4S corresponds to a molar mass of 154.76 g/mol, though it commonly exists as hydrated forms in commercial applications. Safety considerations are paramount when handling nickel(2+) sulfate, as it carries multiple hazard classifications including carcinogenicity (Category 1A), reproductive toxicity (Category 1B), and respiratory sensitization. The compound requires careful handling protocols due to its potential for causing skin irritation and its classification under ADR Class 6.1 for toxic substances. Professional handling equipment and adequate ventilation systems are essential for safe industrial use. Primary industrial applications include electroplating operations where nickel(2+) sulfate serves as a key component in nickel plating baths, providing uniform metallic coatings with excellent corrosion resistance. The compound also finds extensive use in battery manufacturing, particularly in nickel-cadmium and nickel-metal hydride battery production. Additionally, it functions as a catalyst precursor in various chemical synthesis processes. Related compounds such as nickel(2+) dihydroxide and nickel(2+) carbonate serve similar industrial functions but offer different solubility characteristics and processing advantages depending on specific application requirements. OYSI maintains reliable supply chains for nickel(2+) sulfate to support European industrial operations requiring consistent quality and timely delivery.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; Acute Tox. 4 *; Acute Tox. 4 *; STOT RE 1; Skin Irrit. 2; Resp. Sens...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3288
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameNickelsulfat
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) sulfate?

Nickel(2+) sulfate is an inorganic chemical compound with the formula NiO4S and CAS number 7786-81-4. This salt contains nickel in its +2 oxidation state combined with sulfate ions, resulting in a molecular weight of 154.76 g/mol. It is classified as a highly hazardous substance with carcinogenic, mutagenic, and reproductive toxicity properties, requiring careful handling and strict safety protocols in industrial applications.

What are the physicochemical properties of nickel(2+) sulfate?

Nickel(2+) sulfate typically appears as green crystalline crystals or powder at room temperature. The compound is highly soluble in water, forming characteristic green solutions due to the presence of nickel ions. It is odorless and has a molecular weight of 154.76 g/mol. The substance is stable under normal conditions but can decompose at high temperatures, releasing toxic sulfur oxides and nickel compounds.

What is nickel(2+) sulfate used for?

Nickel(2+) sulfate serves primarily in electroplating processes for nickel coating of metals, providing corrosion resistance and decorative finishes. It is extensively used in the production of nickel-cadmium batteries and as a catalyst in various chemical reactions. Additionally, it finds applications in ceramic glazes, textile dyeing, and as a precursor for other nickel compounds in chemical manufacturing industries.

How to handle nickel(2+) sulfate safely?

Nickel(2+) sulfate requires strict safety protocols including respiratory protection, chemical-resistant gloves, and protective clothing to prevent skin contact and inhalation. Work should be conducted in well-ventilated areas or under fume hoods due to its carcinogenic and respiratory sensitizing properties. Eye protection is mandatory, and personnel should be trained on emergency procedures. Regular health monitoring is recommended for workers with occupational exposure.

How to store nickel(2+) sulfate correctly?

Nickel(2+) sulfate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Keep containers away from heat sources and direct sunlight to prevent decomposition. Storage areas must be equipped with appropriate spill containment measures and restricted access due to the substance's hazardous classification. Separate from reducing agents, acids, and organic materials to prevent dangerous reactions.

What to do in case of contact with nickel(2+) sulfate?

Skin contact with nickel(2+) sulfate requires immediate removal of contaminated clothing and thorough washing with soap and water for at least 15 minutes. In case of eye contact, rinse immediately with plenty of water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately and seek medical care. For ingestion, do not induce vomiting and seek immediate medical attention while providing safety data sheet information.

How to dispose of nickel(2+) sulfate appropriately?

Nickel(2+) sulfate disposal must comply with local and national hazardous waste regulations due to its toxic and carcinogenic properties. The substance cannot be disposed of in regular waste streams and requires treatment by licensed hazardous waste disposal facilities. Recovery and recycling of nickel content is often preferred for environmental and economic reasons. Consult local environmental authorities for specific disposal requirements and approved waste management facilities.

How to transport nickel(2+) sulfate?

Nickel(2+) sulfate is classified under ADR as Class 6.1 (toxic substances), Packing Group III, requiring appropriate hazardous goods packaging and documentation for transport. Packages must be properly labeled with GHS pictograms (GHS08, GHS07, GHS09) and carry the 'Danger' signal word. Transport vehicles must comply with ADR regulations, and drivers require hazardous materials training. Proper shipping papers and emergency response information must accompany shipments.

Is nickel(2+) sulfate subject to specific regulations?

Nickel(2+) sulfate is subject to extensive European regulations under REACH and CLP due to its classification as Carcinogenic 1A, Mutagenic 2, and Reproductive toxicant 1B. It requires safety data sheets, exposure scenario documentation, and strict workplace exposure limits. The substance faces restrictions in consumer products and requires authorization for certain uses. Companies must comply with notification requirements and implement risk management measures throughout the supply chain.

Where to buy nickel(2+) sulfate in Europe?

Nickel(2+) sulfate is available through OYSI, a European distributor specializing in technical chemical products with comprehensive regulatory compliance. OYSI provides proper documentation, safety data sheets, and technical support for industrial customers across Europe. Due to the substance's hazardous classification, purchases are typically restricted to qualified industrial users with appropriate handling capabilities and regulatory compliance. Contact OYSI directly for availability, specifications, and regulatory guidance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.