N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine

C6H18N4

CAS112-24-3
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
112-24-3
EC Number
203-950-6
UN Number
2259
Index Number
612-059-00-5
PubChem CID
5565

Physical-chemical properties

Molecular Formula
C6H18N4
Molar Mass
146.23 g/mol
IUPAC Name
N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine

Chemical Identifiers

InChI
InChI=1S/C6H18N4/c7-1-3-9-5-6-10-4-2-8/h9-10H,1-8H2
InChI Key
VILCJCGEZXAXTO-UHFFFAOYSA-N

Overview

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine (CAS 112-24-3) is a polyamine compound with strong alkaline properties and multiple reactive amine groups. This linear tetramine, commonly known in industrial applications for its exceptional chelating and crosslinking capabilities, represents a significant chemical intermediate in various manufacturing processes. With its molecular formula C6H18N4 and molecular weight of 146.23 g/mol, this compound features four primary and secondary amine groups that provide remarkable versatility in chemical reactions and industrial applications. The substance exhibits strong basic properties due to its multiple amine functionalities, making it highly reactive with acids, aldehydes, and other electrophilic compounds. Its classification under GHS includes Acute Toxicity Category 4, Skin Corrosion 1B, and Skin Sensitization Category 1, requiring careful handling with appropriate personal protective equipment. The compound carries a "Danger" signal word and displays GHS07 and GHS05 pictograms, indicating its corrosive nature and potential health hazards. Transportation falls under ADR Class 8, reflecting its corrosive properties. Key industrial applications include its use as a curing agent for epoxy resins, where it provides excellent crosslinking properties, as a chelating agent in metal treatment processes, and as an intermediate in the synthesis of specialized polymers and surfactants. Unlike simpler amines such as phenylmethanamine, this tetramine offers multiple reaction sites, enabling complex molecular architectures in polymer chemistry. The compound's aquatic chronic toxicity classification (Category 3) necessitates proper environmental handling protocols during industrial use. OYSI supplies this technical-grade polyamine to European industrial customers, supporting applications across adhesive, coating, and specialty chemical manufacturing sectors.

Safety & Classification

Danger
Classification:

Acute Tox. 4 *; Skin Corr. 1B; Skin Sens. 1; Aquatic Chronic 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H312

Harmful in contact with skin.

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H412

Harmful to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2259
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameTriethylentetramin
Marine PollutantNo

Frequently Asked Questions

What is N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine is a linear polyamine compound with the molecular formula C6H18N4 and CAS number 112-24-3. This organic chemical features four amine groups connected by ethylene bridges, giving it strong basic properties and high reactivity. With a molecular weight of 146.23 g/mol, it belongs to the family of polyethylene polyamines and is classified as a corrosive substance requiring careful handling due to its hazardous nature.

What are the physicochemical properties of N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine is typically a viscous liquid at room temperature with a characteristic amine odor. The compound is highly hygroscopic and readily absorbs moisture from air. It exhibits excellent water solubility due to its multiple amine groups, which also make it strongly alkaline in aqueous solution. The substance has a relatively high boiling point and low vapor pressure, typical of polyamine compounds with hydrogen bonding capabilities.

What is N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine used for?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine serves as a crucial building block in various industrial applications. It is primarily used as a curing agent for epoxy resins, providing excellent adhesion and chemical resistance properties. The compound also functions as an intermediate in the synthesis of chelating agents, corrosion inhibitors, and fuel additives. Additionally, it finds application in the production of specialty polymers, textile auxiliaries, and as a catalyst in certain chemical reactions.

How to handle N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine safely?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine requires strict safety precautions due to its corrosive nature and skin sensitization potential. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume extraction systems. Avoid direct skin contact and inhalation of vapors. Use appropriate spill containment materials and ensure emergency shower facilities are readily accessible. Regular safety training for handling personnel is mandatory.

How to store N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine correctly?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine must be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from heat sources and direct sunlight. The storage area should be equipped with appropriate containment systems to prevent environmental release. Keep away from acids, oxidizing agents, and incompatible materials. Containers should be made of suitable materials resistant to corrosion. Regular inspection of storage containers is essential to detect any signs of degradation or leakage.

What to do in case of contact with N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine?

Immediate action is required in case of contact with N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine due to its corrosive properties. For skin contact, immediately remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing is difficult. Seek medical attention immediately for all exposure incidents.

How to dispose of N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine properly?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine disposal must comply with local, national, and international waste regulations due to its hazardous classification. The substance should never be discharged directly into the environment or sewage systems. Disposal should be conducted through licensed waste treatment facilities capable of handling corrosive and toxic materials. Small quantities may require neutralization before disposal, while larger amounts typically require incineration at specialized high-temperature facilities. Always consult local authorities for specific disposal requirements.

How to transport N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine is classified as ADR Class 8 (corrosive substances), Packing Group II, requiring specialized transport procedures. Packages must be properly labeled with appropriate hazard symbols and documentation. Transport vehicles must be equipped with emergency response equipment and drivers must hold valid dangerous goods certifications. The substance requires robust, leak-proof packaging designed for corrosive materials. All transport operations must comply with international dangerous goods regulations including proper segregation from incompatible materials.

Is N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine subject to specific regulations?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine is subject to comprehensive European chemical regulations including REACH registration and CLP classification requirements. The substance is classified under multiple hazard categories requiring proper labeling, safety data sheets, and risk management measures. While not currently listed as a SVHC (Substance of Very High Concern), it requires compliance with occupational exposure limits and environmental protection measures. Manufacturers and importers must fulfill registration obligations and downstream users must implement appropriate risk management measures.

Where to buy N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine in Europe?

N'-[2-(2-aminoethylamino)ethyl]ethane-1,2-diamine is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. As an established chemical distributor, OYSI ensures product quality, appropriate packaging, and adherence to transportation regulations. Contact OYSI directly for specific availability, technical specifications, and delivery options to meet your industrial requirements while maintaining full regulatory compliance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.