Ethyl 2-methylprop-2-enoate

C6H10O2

ethyl 2-methylprop-2-enoate

CAS97-63-2
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
97-63-2
EC Number
202-597-5
UN Number
2277
Index Number
607-071-00-2
PubChem CID
7343

Physical-chemical properties

Molecular Formula
C6H10O2
Molar Mass
114.14 g/mol
IUPAC Name
ethyl 2-methylprop-2-enoate

Chemical Identifiers

InChI
InChI=1S/C6H10O2/c1-4-8-6(7)5(2)3/h2,4H2,1,3H3
InChI Key
SUPCQIBBMFXVTL-UHFFFAOYSA-N

Overview

Ethyl 2-methylprop-2-enoate (CAS 97-63-2) is an acrylic ester monomer with high reactivity and polymerization capability. This important industrial chemical, also known by its EC number 202-597-5, represents a key building block in polymer chemistry and specialty chemical manufacturing. With its molecular formula C6H10O2 and molecular weight of 114.14 g/mol, ethyl 2-methylprop-2-enoate exhibits the characteristic properties of acrylic esters, making it valuable for numerous synthetic applications. The compound belongs to the same chemical family as other reactive monomers like styrene, sharing similar polymerization characteristics but offering distinct performance advantages in specific applications. Its chemical structure features a vinyl group that readily undergoes addition polymerization, enabling the formation of high-performance polymer materials with tailored properties. From a safety perspective, ethyl 2-methylprop-2-enoate requires careful handling due to its classification as a flammable liquid (Flam. Liq. 2) and its potential to cause skin and eye irritation. The substance carries GHS02 and GHS07 pictograms with a "Danger" signal word, indicating its flammable nature and health hazards. It is classified under ADR Class 3 for transportation purposes, requiring appropriate safety measures during shipping and storage. Primary industrial applications include the production of acrylic polymers and copolymers for coatings, adhesives, and specialty plastics. The compound serves as a reactive diluent in radiation-curing systems and finds use in the manufacture of impact modifiers for various polymer formulations. Its controlled polymerization properties make it particularly suitable for producing materials with specific mechanical and thermal characteristics. OYSI maintains reliable supply chains for ethyl 2-methylprop-2-enoate, ensuring consistent availability for European industrial customers requiring this specialized acrylic monomer.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2277
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameEthylmethacrylat, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is ethyl 2-methylprop-2-enoate?

Ethyl 2-methylprop-2-enoate is an organic chemical compound with the molecular formula C6H10O2 and CAS number 97-63-2. This substance belongs to the family of acrylate esters and has a molecular weight of 114.14 g/mol. It is classified as a flammable liquid with potential health hazards including skin and eye irritation, skin sensitization, and specific target organ toxicity. The compound requires careful handling due to its hazardous properties.

What are the physicochemical properties of ethyl 2-methylprop-2-enoate?

Ethyl 2-methylprop-2-enoate is a liquid at room temperature with characteristic ester-like odor. As an acrylate ester with molecular formula C6H10O2, it exhibits typical properties of organic esters including moderate volatility and limited water solubility. The compound has a molecular weight of 114.14 g/mol and demonstrates flammable characteristics, requiring appropriate fire safety precautions during handling and storage.

What is ethyl 2-methylprop-2-enoate used for?

Ethyl 2-methylprop-2-enoate serves as a monomer in polymer synthesis and is commonly used in the production of acrylic resins, coatings, and adhesives. Its applications include manufacturing of paints, varnishes, and various polymer materials where its reactive double bond enables polymerization reactions. The compound is also utilized in specialty chemical synthesis and as an intermediate in the production of other chemical compounds.

How to handle ethyl 2-methylprop-2-enoate safely?

Ethyl 2-methylprop-2-enoate requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas or under fume extraction to avoid inhalation. Keep away from heat sources, sparks, and open flames due to its flammable nature. Avoid prolonged skin contact as the substance can cause sensitization and irritation.

How to store ethyl 2-methylprop-2-enoate correctly?

Ethyl 2-methylprop-2-enoate must be stored in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Use appropriate containers that are tightly sealed to prevent vapor release and contamination. Store separately from strong oxidizers, acids, and bases to prevent incompatible reactions. Maintain storage temperature below recommended limits and ensure proper labeling with hazard information.

What to do in case of contact with ethyl 2-methylprop-2-enoate?

In case of skin contact with ethyl 2-methylprop-2-enoate, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of ethyl 2-methylprop-2-enoate appropriately?

Ethyl 2-methylprop-2-enoate must be disposed of according to local and national waste regulations as hazardous chemical waste. Do not discharge into drains, soil, or waterways due to environmental concerns. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities may require neutralization or controlled incineration at authorized facilities. Always consult current waste disposal regulations in your jurisdiction.

How to transport ethyl 2-methylprop-2-enoate?

Ethyl 2-methylprop-2-enoate is classified under ADR as Class 3 (flammable liquids), Packing Group II, requiring compliance with dangerous goods transportation regulations. Use appropriate packaging that meets UN specification requirements and ensure proper labeling with hazard diamonds and transport documentation. Vehicles must carry appropriate emergency equipment and drivers need ADR certification for transporting this flammable liquid.

Is ethyl 2-methylprop-2-enoate subject to specific regulations?

Ethyl 2-methylprop-2-enoate is subject to European REACH regulation requiring registration for manufacture or import above one tonne per year. The substance must be classified and labeled according to CLP regulation with appropriate hazard pictograms (GHS02, GHS07) and danger signal word. It is not currently listed as a Substance of Very High Concern (SVHC), but users must comply with safety data sheet requirements and occupational exposure limits.

Where to buy ethyl 2-methylprop-2-enoate in Europe?

Ethyl 2-methylprop-2-enoate is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. OYSI provides this chemical compound with proper documentation, safety data sheets, and regulatory compliance for professional applications. Contact OYSI directly for availability, packaging options, and delivery to your location within Europe for your specific industrial or research requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.