Copper;sulfate;pentahydrate

CuH10O9S

copper;sulfate;pentahydrate

CAS7758-99-8
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7758-99-8
UN Number
3288
Index Number
029-023-00-4
PubChem CID
24463

Physical-chemical properties

Molecular Formula
CuH10O9S
Molar Mass
249.69 g/mol
IUPAC Name
copper;sulfate;pentahydrate

Chemical Identifiers

InChI
InChI=1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
InChI Key
JZCCFEFSEZPSOG-UHFFFAOYSA-L

Overview

Copper sulfate pentahydrate (CAS 7758-99-8) is an inorganic copper salt characterized by its distinctive blue crystalline structure and high water solubility. This essential industrial chemical, also known as blue vitriol or cupric sulfate pentahydrate, represents one of the most widely utilized copper compounds in commercial applications. With its molecular formula CuH10O9S and molecular weight of 249.69 g/mol, copper sulfate pentahydrate forms bright blue crystals that readily dissolve in water, making it highly versatile for various industrial processes. The pentahydrate form contains five molecules of water of crystallization, which contributes to its stability and handling characteristics under normal conditions. From a safety perspective, copper sulfate pentahydrate requires careful handling due to its classification as Acute Tox. 4 and Eye Dam. 1, necessitating appropriate protective equipment during use. Its significant environmental impact is reflected in its Aquatic Acute 1 and Aquatic Chronic 1 classifications, requiring strict containment measures to prevent environmental release. The substance carries GHS07, GHS05, and GHS09 pictograms with a "Danger" signal word, and falls under ADR class 6.1 for transportation purposes. Industrial applications include agricultural fungicides, electroplating processes, and metal treatment operations. In agricultural settings, it serves as an effective antimicrobial agent, while in manufacturing, it functions as a catalyst and copper source for various chemical processes. Unlike specialized compounds such as methyl(triphenyl)phosphanium chloride used in organic synthesis, copper sulfate pentahydrate offers broad-spectrum utility across multiple industries. OYSI maintains reliable inventory of technical-grade copper sulfate pentahydrate to support diverse European industrial requirements.

Safety & Classification

Danger
Classification:

Acute Tox. 4; Eye Dam. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3288
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameKupfer(II)-sulfat-Pentahydrat
Marine PollutantNo

Frequently Asked Questions

What is copper sulfate pentahydrate?

Copper sulfate pentahydrate is an inorganic crystalline compound with the chemical formula CuSO4·5H2O (CAS: 7758-99-8). This blue crystalline salt contains five molecules of water of crystallization per copper sulfate unit, giving it a molecular weight of 249.69 g/mol. It is one of the most common copper compounds used in industry and is classified as a hazardous substance requiring careful handling due to its toxicity and environmental impact.

What are the physicochemical properties of copper sulfate pentahydrate?

Copper sulfate pentahydrate appears as bright blue crystals or crystalline powder at room temperature. It is highly soluble in water, producing a characteristic blue solution, and has no distinct odor. The compound is stable under normal conditions but loses water of crystallization when heated, transforming into the anhydrous white form. It has a density of approximately 2.286 g/cm³ and decomposes at temperatures above 200°C.

What is copper sulfate pentahydrate used for?

Copper sulfate pentahydrate serves multiple industrial and agricultural purposes. It is primarily used as a fungicide in agriculture, for electroplating and metal finishing processes, and as a catalyst in various chemical reactions. Additionally, it finds applications in water treatment as an algaecide, in the production of other copper compounds, textile dyeing, leather processing, and as a laboratory reagent for analytical chemistry and educational purposes.

How to handle copper sulfate pentahydrate safely?

Copper sulfate pentahydrate requires careful handling using appropriate personal protective equipment including safety goggles, gloves, and protective clothing to prevent skin and eye contact. Work in well-ventilated areas to avoid inhalation of dust particles. Avoid eating, drinking, or smoking during handling. Wash hands thoroughly after use and ensure emergency eyewash stations are accessible. The substance is classified as Acute Tox. 4 and Eye Dam. 1, requiring strict adherence to safety protocols.

How to store copper sulfate pentahydrate correctly?

Copper sulfate pentahydrate should be stored in a cool, dry, well-ventilated area away from incompatible materials such as strong bases, aluminum, and magnesium. Keep containers tightly closed and protect from moisture to prevent caking. Store away from food, beverages, and animal feed. Ensure storage areas are equipped with appropriate spill containment measures and maintain temperatures below 30°C to preserve product stability and prevent decomposition.

What to do in case of contact with copper sulfate pentahydrate?

Copper sulfate pentahydrate contact requires immediate action. For eye contact, rinse immediately with plenty of water for at least 15 minutes and seek medical attention due to its Eye Dam. 1 classification. For skin contact, wash thoroughly with soap and water. If inhaled, move to fresh air immediately. If ingested, rinse mouth and seek medical attention without inducing vomiting. Always consult a physician in case of exposure and provide the safety data sheet.

How to dispose of copper sulfate pentahydrate properly?

Copper sulfate pentahydrate disposal must comply with local environmental regulations due to its Aquatic Acute 1 and Aquatic Chronic 1 classifications. Never dispose of it down drains or into water systems. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities may require neutralization before disposal. Contaminated packaging should also be treated as hazardous waste. Always consult local authorities for specific disposal requirements in your region.

How to transport copper sulfate pentahydrate?

Copper sulfate pentahydrate is classified under ADR Class 6.1 (toxic substances), Packing Group III for transportation. It requires appropriate hazardous material packaging, labeling with GHS07, GHS05, and GHS09 pictogrammes, and documentation including transport documents. Vehicles must display proper placards and drivers need hazardous materials training. Ensure packages are secure, undamaged, and protected from moisture during transit while following all applicable dangerous goods regulations.

Is copper sulfate pentahydrate subject to specific regulations?

Copper sulfate pentahydrate is subject to multiple regulatory frameworks including REACH registration requirements in Europe and CLP classification as Acute Tox. 4, Eye Dam. 1, Aquatic Acute 1, and Aquatic Chronic 1. It requires safety data sheets, proper labeling with 'Danger' signal word, and compliance with occupational exposure limits. While not currently listed as SVHC, its environmental toxicity makes it subject to strict usage and disposal regulations across European jurisdictions.

Where to buy copper sulfate pentahydrate in Europe?

Copper sulfate pentahydrate is available through OYSI, a European distributor of technical chemicals offering reliable supply across the continent. As specialized chemical distributors, OYSI ensures product quality, regulatory compliance, and proper documentation including safety data sheets. They serve various industries requiring this compound for industrial, agricultural, and laboratory applications while maintaining strict quality standards and providing technical support for safe handling and usage.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.