Chloro(dimethyl)silane

C2H7ClSi

chloro(dimethyl)silane

CAS1066-35-9

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Identification

CAS Number
1066-35-9
EC Number
213-912-0
UN Number
2924
PubChem CID
66108

Physical-chemical properties

Molecular Formula
C2H7ClSi
Molar Mass
94.61 g/mol
IUPAC Name
chloro(dimethyl)silane

Chemical Identifiers

InChI
InChI=1S/C2H7ClSi/c1-4(2)3/h4H,1-2H3
InChI Key
YGHUUVGIRWMJGE-UHFFFAOYSA-N

Overview

Chloro(dimethyl)silane (CAS 1066-35-9) is an organosilicon compound with reactive chloro and methyl substituents on silicon. This colorless liquid represents a fundamental building block in organosilicon chemistry, serving as an essential intermediate for various silicone-based materials and chemical syntheses. With its molecular formula C2H7ClSi and molecular weight of 94.61 g/mol, chloro(dimethyl)silane exhibits the characteristic reactivity of chlorosilanes, making it valuable for numerous industrial applications requiring silicon-carbon bond formation. The compound's structure features a silicon atom bonded to two methyl groups and one chlorine atom, along with a hydrogen atom. This configuration provides both hydrolytic reactivity through the Si-Cl bond and thermal stability from the Si-C bonds. The presence of the chlorine substituent makes it readily reactive with alcohols, amines, and water, enabling its use in condensation reactions and surface modifications. Safety considerations for chloro(dimethyl)silane include its classification under ADR Class 3 as a flammable liquid. Proper handling requires appropriate ventilation and fire prevention measures due to its flammable nature. Storage should occur in dry conditions to prevent hydrolysis reactions. Primary industrial applications include silicone polymer synthesis, where it serves as a chain-stopping agent or crosslinking component. The compound is also utilized in surface treatment formulations and as a precursor for specialized organosilicon materials. Unlike simpler compounds such as 2-ethylbutyl acetate used in coatings, chloro(dimethyl)silane offers unique silicon chemistry capabilities for advanced material development. OYSI maintains reliable supplies of chloro(dimethyl)silane to support diverse industrial requirements across European markets.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2924
ADR Class3
Packing GroupI
Tunnel CodeC/E
Proper Shipping NameChlordimethylsilan
Marine PollutantNo

Frequently Asked Questions

What is chloro(dimethyl)silane?

Chloro(dimethyl)silane is an organosilicon compound with the molecular formula C2H7ClSi and CAS number 1066-35-9. This chemical has a molecular weight of 94.61 g/mol and belongs to the family of chlorosilanes. It consists of a silicon atom bonded to two methyl groups and one chlorine atom, making it a monofunctional silane derivative used primarily in industrial synthesis applications.

What are the physicochemical properties of chloro(dimethyl)silane?

Chloro(dimethyl)silane is a colorless liquid with a characteristic pungent odor typical of chlorosilanes. It is highly reactive with water, undergoing hydrolysis to form siloxanes and hydrogen chloride. The compound has a relatively low molecular weight of 94.61 g/mol and exhibits typical organosilicon compound properties including volatility and sensitivity to moisture. It is soluble in organic solvents but reacts vigorously with protic solvents.

What is chloro(dimethyl)silane used for?

Chloro(dimethyl)silane is primarily used as a chemical intermediate in the synthesis of silicone polymers and siloxanes. It serves as a building block for producing dimethylsiloxane units in silicone chemistry. The compound is utilized in surface modification applications, as a coupling agent, and in the manufacture of specialty silicone materials. It is also employed in research and development for creating custom organosilicon compounds with specific properties.

How to handle chloro(dimethyl)silane safely?

Chloro(dimethyl)silane requires careful handling due to its reactive nature and flammability (ADR Class 3, Group I). Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation of vapors. Keep away from heat sources, sparks, and open flames. Use only non-sparking tools and ensure proper grounding of equipment to prevent static discharge.

How to store chloro(dimethyl)silane correctly?

Chloro(dimethyl)silane must be stored in tightly sealed containers in a cool, dry place away from moisture and incompatible materials. Keep containers in a well-ventilated area away from heat sources and ignition sources due to its flammable nature. Store separately from water, alcohols, and strong bases which can cause violent reactions. Use appropriate secondary containment and ensure storage areas comply with local fire safety regulations for flammable liquids.

What to do in case of contact with chloro(dimethyl)silane?

Chloro(dimethyl)silane contact requires immediate action to prevent injury. For skin contact, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention.

How to dispose of chloro(dimethyl)silane properly?

Chloro(dimethyl)silane disposal must follow local and national hazardous waste regulations. The substance cannot be disposed of down drains or in regular waste due to its reactive and flammable nature. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be carefully hydrolyzed under controlled conditions by qualified personnel, but this should only be done following appropriate safety protocols and environmental regulations.

How to transport chloro(dimethyl)silane?

Chloro(dimethyl)silane is classified under ADR Class 3 (flammable liquids), Group I, indicating high hazard during transport. It must be packaged in appropriate UN-specification containers and labeled according to dangerous goods regulations. Transport requires proper documentation, emergency response information, and compliance with routing restrictions. Only qualified carriers with dangerous goods authorization should handle transportation, and vehicles must carry appropriate firefighting equipment.

Is chloro(dimethyl)silane subject to specific regulations?

Chloro(dimethyl)silane is subject to various chemical regulations including REACH registration requirements for manufacture, import, or use within the European Union. It must comply with CLP regulation for classification, labeling, and packaging. The substance is not currently listed as a Substance of Very High Concern (SVHC). Users must follow occupational safety regulations and may need to comply with additional local chemical safety requirements depending on application and quantities used.

Where to buy chloro(dimethyl)silane in Europe?

Chloro(dimethyl)silane is available through specialized chemical distributors in Europe, including OYSI, a European distributor of technical chemicals. When sourcing this compound, ensure the supplier provides proper documentation including safety data sheets, certificates of analysis, and compliance with REACH regulations. Work with established distributors who understand the handling requirements and can provide technical support for your specific application needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.