Cesium hydroxide
CsHO
cesium hydroxide
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Identification
- CAS Number
- 21351-79-1
- EC Number
- 244-344-1
- UN Number
- 2682
- PubChem CID
- 62750
Physical-chemical properties
- Molecular Formula
- CsHO
- Molar Mass
- 149.91 g/mol
- IUPAC Name
- cesium hydroxide
Chemical Identifiers
- InChI
- InChI=1S/Cs.H2O/h;1H2/q+1;/p-1
- InChI Key
- HUCVOHYBFXVBRW-UHFFFAOYSA-M
Overview
Cesium hydroxide (CAS 21351-79-1) is an alkali metal hydroxide with exceptionally high basicity and reactivity properties. This inorganic compound represents one of the strongest bases available in industrial chemistry, making it a valuable reagent for specialized chemical processes requiring extreme alkaline conditions. As a member of the alkali metal hydroxide family, cesium hydroxide exhibits remarkable chemical properties due to cesium's position at the bottom of Group 1 in the periodic table. The compound appears as white crystalline solids that are highly hygroscopic, readily absorbing moisture from the atmosphere to form concentrated alkaline solutions. Its molecular structure consists of cesium cations (Cs+) and hydroxide anions (OH-), creating an ionic compound with a molecular weight of 149.913 g/mol. The substance demonstrates exceptional solubility in water, producing strongly basic solutions with pH values significantly higher than those achieved by more common bases like sodium or potassium hydroxide. This enhanced basicity makes cesium hydroxide particularly effective in applications requiring powerful nucleophilic conditions or extreme pH environments. Despite its classification under ADR Class 8 as a corrosive material, proper handling protocols enable safe industrial use. Primary industrial applications include organic synthesis as a strong base catalyst, particularly in reactions where conventional bases prove insufficient. The compound serves as an essential reagent in specialized chemical manufacturing processes, including the production of cesium salts and certain pharmaceutical intermediates. Unlike more reactive compounds such as trichlorostibane or 4-methoxybenzoyl chloride, cesium hydroxide offers controlled basicity with predictable reaction outcomes. OYSI maintains reliable supplies of high-purity cesium hydroxide to support diverse European industrial applications requiring this specialized alkaline reagent.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 2682 |
| ADR Class | 8 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Caesiumhydroxid, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is cesium hydroxide?
Cesium hydroxide is an inorganic chemical compound with the molecular formula CsHO and CAS number 21351-79-1. It is an alkali metal hydroxide formed by the combination of cesium and hydroxide ions, with a molecular weight of 149.913 g/mol. This compound is highly hygroscopic and represents one of the strongest bases known in chemistry, making it valuable for specialized industrial applications requiring extreme alkalinity.
What are the physicochemical properties of cesium hydroxide?
Cesium hydroxide appears as white crystalline solid at room temperature and is extremely hygroscopic, readily absorbing moisture from air. It is highly soluble in water, producing a strongly alkaline solution with significant heat generation. The compound is also soluble in alcohols and has a high melting point typical of ionic compounds. Due to its hygroscopic nature, it must be handled in dry conditions to prevent atmospheric moisture absorption.
What is cesium hydroxide used for?
Cesium hydroxide serves as a specialized catalyst in organic synthesis reactions, particularly in polymerization processes and as a strong base for chemical transformations. It is used in the production of specialty chemicals, pharmaceutical intermediates, and in research applications requiring extremely basic conditions. The compound also finds application in the electronics industry and in specialized analytical chemistry procedures where its unique properties are advantageous.
How to handle cesium hydroxide safely?
Cesium hydroxide requires careful handling due to its highly caustic nature and hygroscopic properties. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, and protective clothing to prevent skin and eye contact. Work should be conducted in well-ventilated areas or under fume hoods. Avoid contact with moisture and ensure dry handling conditions. Keep away from incompatible materials and have appropriate neutralizing agents readily available.
How to store cesium hydroxide correctly?
Cesium hydroxide must be stored in tightly sealed, moisture-proof containers in a dry, cool environment away from humidity sources. The storage area should be well-ventilated and separated from acids, organic materials, and metals that could react with the compound. Use appropriate secondary containment to prevent environmental release. Regular inspection of container integrity is essential due to the compound's hygroscopic nature and potential for container deterioration.
What to do in case of contact with cesium hydroxide?
Immediate action is required for any contact with cesium hydroxide due to its highly caustic properties. For skin contact, immediately flush with copious amounts of water for at least 15 minutes and remove contaminated clothing. In case of eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek emergency medical care. Always consult medical professionals promptly.
How to dispose of cesium hydroxide properly?
Cesium hydroxide disposal must comply with local and national hazardous waste regulations as it is classified as corrosive waste. The compound should never be disposed of through regular waste streams or sewerage systems. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may be carefully neutralized with appropriate acids under controlled conditions by qualified personnel, but this should only be done following proper safety protocols and regulatory approval.
How to transport cesium hydroxide?
Cesium hydroxide is classified under ADR Class 8 (corrosive substances) with Packing Group II, indicating moderate danger level for transport. It must be packaged in UN-approved containers suitable for corrosive materials and properly labeled with appropriate hazard markings. Transport documentation must include proper shipping names and hazard classifications. Vehicles must carry appropriate emergency equipment and drivers require ADR certification for handling corrosive substances during transport.
Is cesium hydroxide subject to specific regulations?
Cesium hydroxide is regulated under various chemical safety frameworks including REACH registration requirements in Europe and CLP classification for hazard communication. While not currently listed as a Substance of Very High Concern (SVHC), it must comply with standard chemical safety regulations for corrosive substances. Users must maintain safety data sheets, conduct appropriate risk assessments, and implement necessary control measures as required by occupational health and safety legislation.
Where to buy cesium hydroxide in Europe?
Cesium hydroxide is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers across Europe. As a professional chemical distributor, OYSI provides quality cesium hydroxide with appropriate documentation including certificates of analysis and safety data sheets. Contact OYSI directly for specific product specifications, packaging options, and availability to meet your technical requirements for this specialized chemical compound.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.