Cesium

Cs

cesium

CAS7440-46-2

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Identification

CAS Number
7440-46-2
EC Number
231-155-4
UN Number
1407
PubChem CID
5354618

Physical-chemical properties

Molecular Formula
Cs
Molar Mass
132.91 g/mol
IUPAC Name
cesium

Chemical Identifiers

InChI
InChI=1S/Cs
InChI Key
TVFDJXOCXUVLDH-UHFFFAOYSA-N

Overview

Cesium (CAS 7440-46-2) is a highly reactive alkali metal with exceptional chemical reactivity and the lowest ionization energy of all stable elements. Cesium represents one of the most fascinating and reactive elements in the periodic table, belonging to the alkali metal family alongside sodium and potassium. This soft, silvery-gold metallic element exhibits remarkable properties that make it invaluable for specialized industrial and scientific applications. With its atomic number 55 and molecular weight of 132.905452 g/mol, cesium stands as the heaviest naturally occurring alkali metal, displaying unique characteristics that distinguish it from its lighter counterparts. The element's extraordinary reactivity stems from its single valence electron, which is easily removed due to cesium's exceptionally low ionization energy. This property makes cesium spontaneously ignite in air and react violently with water, producing cesium hydroxide and hydrogen gas. Unlike mercury, which remains liquid at room temperature, cesium has a relatively low melting point of 28.5°C, meaning it can exist as a liquid just above room temperature. Cesium finds critical applications in atomic clocks, where its precise atomic transitions define the international standard for time measurement. The aerospace industry utilizes cesium in ion propulsion systems for spacecraft, while the electronics sector employs it in photomultiplier tubes and infrared detectors. Additionally, cesium compounds serve as catalysts in organic synthesis reactions. Due to its classification under ADR Class 4.3 as a substance that emits flammable gases when in contact with water, cesium requires specialized handling protocols and storage conditions. Proper safety measures, including inert atmosphere packaging and trained personnel, are essential when working with this highly reactive metal. OYSI provides high-quality cesium products to meet the demanding requirements of research institutions and specialized industrial applications across Europe.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1407
ADR Class4.3
Packing GroupI
Tunnel CodeB/E
Proper Shipping NameCaesium, nicht pyrophor
Marine PollutantNo

Frequently Asked Questions

What is cesium?

Cesium is an alkali metal element with the chemical symbol Cs and atomic number 55. It is the most electropositive and reactive of all metals, appearing as a soft, silvery-gold colored metal at room temperature. With a molecular weight of 132.905452 g/mol, cesium has the lowest melting point of all alkali metals and exhibits unique properties including high reactivity with water and air, making it valuable for specialized industrial applications.

What are the physicochemical properties of cesium?

Cesium is a soft, silvery-gold metal that melts at 28.5°C, making it liquid at slightly elevated temperatures. It has a density of 1.93 g/cm³ and readily oxidizes in air, forming a golden oxide layer. Cesium is highly soluble in water, alcohol, and acids, reacting vigorously and sometimes explosively with water to produce cesium hydroxide and hydrogen gas. It has no characteristic odor but must be stored under inert conditions due to its extreme reactivity.

What is cesium used for?

Cesium is primarily used in atomic clocks for precise timekeeping, serving as the international standard for time measurement. It finds applications in photoelectric cells, scintillation detectors, and ion propulsion systems for spacecraft. In the petroleum industry, cesium compounds are used in drilling fluids for deep wells. Research applications include quantum physics experiments, and cesium isotopes are utilized in medical imaging and cancer treatment protocols in specialized healthcare facilities.

How to handle cesium safely?

Cesium must be handled with extreme caution due to its high reactivity with moisture and air. Always wear protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in an inert atmosphere or dry glove box when possible. Avoid contact with water, acids, or oxidizing agents as violent reactions can occur. Ensure adequate ventilation and have appropriate fire suppression equipment nearby. Personnel should be trained in emergency procedures before handling this reactive metal.

How to store cesium correctly?

Cesium must be stored under mineral oil or in sealed ampoules under inert gas (argon or nitrogen) to prevent oxidation and reaction with moisture. Use airtight containers made of compatible materials, avoiding contact with water, acids, halogens, and organic compounds. Store in a cool, dry area away from heat sources and incompatible materials. Maintain storage temperature below 28°C to keep it in solid form, and ensure containers are properly labeled with handling warnings.

What to do in case of contact with cesium?

Cesium contact requires immediate emergency response due to its caustic properties and reactivity. For skin contact, immediately brush off any solid metal particles without using water, then flush with large amounts of water for at least 15 minutes. For eye contact, rinse immediately with water for 15 minutes and seek medical attention. If ingested, do not induce vomiting and seek immediate medical care. In case of fire, use dry sand or specialized metal fire suppressants, never water.

How to dispose of cesium appropriately?

Cesium disposal must comply with local hazardous waste regulations and should only be performed by qualified professionals. Small quantities can be carefully reacted with alcohols under controlled conditions to form less reactive compounds. Never dispose of cesium in regular waste streams or pour down drains. Contact specialized hazardous waste disposal companies experienced in alkali metal handling. All disposal activities must follow environmental protection guidelines and may require special permits depending on local regulations.

How to transport cesium?

Cesium is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group I, indicating high danger level. It must be transported in approved packaging systems designed for water-reactive substances, completely sealed and protected from moisture. Vehicles must carry appropriate emergency equipment and documentation. Drivers require specialized training for dangerous goods transport, and specific routing restrictions may apply depending on local transportation regulations.

Is cesium subject to specific regulations?

Cesium is regulated under REACH as a chemical substance requiring registration for commercial use in the European Union. While not classified as a Substance of Very High Concern (SVHC), it falls under dangerous goods regulations for transport and storage. Industrial users must comply with workplace safety directives and may need special permits. Import/export may require licenses depending on end-use applications, particularly for research or military purposes, and all handling must meet local environmental protection standards.

Where to buy cesium in Europe?

Cesium is available through OYSI, a specialized European distributor of technical chemicals with expertise in reactive metals and hazardous materials. As a professional chemical supplier, OYSI can provide cesium in appropriate packaging with full documentation including safety data sheets and transport certificates. We ensure compliance with European regulations and offer technical support for safe handling and storage. Contact OYSI directly to discuss your specific requirements and obtain current availability information.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.