Tripotassium;phosphanide

H2K3P+2

tripotassium;phosphanide

CAS20770-41-6

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Identification

CAS Number
20770-41-6
EC Number
244-021-5
UN Number
2012
PubChem CID
62745

Physical-chemical properties

Molecular Formula
H2K3P+2
Molar Mass
150.28 g/mol
IUPAC Name
tripotassium;phosphanide

Chemical Identifiers

InChI
InChI=1S/3K.H2P/h;;;1H2/q3*+1;-1
InChI Key
UXNDEGTUDQHWPA-UHFFFAOYSA-N

Overview

Tripotassium phosphanide (CAS 20770-41-6) is an inorganic phosphide compound with highly reactive properties and specialized industrial applications. This chemical compound, with the molecular formula H2K3P+2 and a molecular weight of 150.285 g/mol, represents a unique class of phosphorus-containing materials characterized by the presence of three potassium cations associated with a phosphanide anion. The compound's structure places it within the broader family of alkali metal phosphides, sharing certain reactive characteristics with related compounds such as potassium sodium alloys, though exhibiting distinct chemical behavior due to its phosphorus component. The substance is classified under ADR Class 4.3, indicating its nature as a material that releases flammable gases when in contact with water. This classification reflects the compound's significant reactivity profile, particularly its tendency to undergo hydrolysis reactions in the presence of moisture, generating phosphine gas and potassium hydroxide. Such reactions require careful handling procedures and appropriate storage conditions to prevent uncontrolled gas evolution and potential safety hazards. In industrial applications, tripotassium phosphanide finds use primarily in specialized chemical synthesis processes, particularly as a reagent in organophosphorus chemistry where controlled phosphorus incorporation is required. The compound also serves applications in materials science research, specifically in the development of phosphide-based semiconducting materials. Additionally, it functions as a precursor in certain metallurgical processes where phosphorus doping of metallic systems is necessary. Given its specialized nature and handling requirements, tripotassium phosphanide is typically supplied to research institutions and specialized chemical manufacturers. OYSI maintains availability of this technical-grade compound for qualified industrial customers requiring phosphide chemistry solutions.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2012
ADR Class4.3
Packing GroupI
Tunnel CodeE
Proper Shipping NameKaliumphosphid
Marine PollutantNo

Frequently Asked Questions

What is tripotassium phosphanide?

Tripotassium phosphanide is an inorganic chemical compound with the molecular formula H2K3P+2 and CAS number 20770-41-6. This substance has a molecular weight of 150.285 g/mol and belongs to the family of phosphorus-containing compounds. It is characterized by the presence of three potassium atoms and phosphorus in its chemical structure, making it a specialized chemical reagent used in various industrial applications.

What are the physicochemical properties of tripotassium phosphanide?

Tripotassium phosphanide is a solid inorganic compound at room temperature with distinctive chemical properties related to its phosphorus and potassium content. As a phosphanide compound, it typically exhibits high reactivity, particularly with water and moisture. The presence of multiple potassium atoms contributes to its ionic character and potential solubility in polar solvents. Its molecular weight of 150.285 g/mol indicates moderate molecular complexity.

What is tripotassium phosphanide used for?

Tripotassium phosphanide serves as a specialized chemical reagent in various industrial and research applications. It is primarily used in synthetic chemistry as a source of phosphide ions and in the preparation of other phosphorus-containing compounds. Its applications may include use in semiconductor industry processes, as a reducing agent in specific chemical reactions, and in the synthesis of advanced materials requiring phosphorus incorporation.

How to handle tripotassium phosphanide safely?

Tripotassium phosphanide requires careful handling due to its reactive nature. Personnel should wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid contact with water, acids, and oxidizing agents. Use non-sparking tools and ensure proper grounding to prevent static electricity buildup during handling operations.

How to store tripotassium phosphanide correctly?

Tripotassium phosphanide must be stored in a cool, dry place away from moisture and incompatible materials. Keep containers tightly sealed in their original packaging and store in areas with controlled temperature and humidity. Separate from acids, oxidizing agents, and water sources. Storage areas should be well-ventilated and equipped with appropriate fire suppression systems. Regular inspection of containers for damage or deterioration is recommended.

What to do in case of contact with tripotassium phosphanide?

Tripotassium phosphanide contact requires immediate action depending on exposure type. For skin contact, remove contaminated clothing and rinse affected area thoroughly with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes while holding eyelids open. If inhaled, move person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention in all cases.

How to dispose of tripotassium phosphanide appropriately?

Tripotassium phosphanide disposal must comply with local and national hazardous waste regulations. This chemical cannot be disposed of through regular waste streams and requires specialized treatment by licensed hazardous waste disposal companies. Small quantities may need neutralization under controlled conditions before disposal. Always consult local environmental authorities and waste management specialists to ensure proper disposal procedures are followed according to applicable legislation.

How to transport tripotassium phosphanide?

Tripotassium phosphanide is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Group I, indicating high danger level. Transportation requires specialized packaging meeting UN specifications and proper hazardous materials documentation. Vehicles must carry appropriate placarding and emergency equipment. Only trained personnel certified in dangerous goods transport should handle shipments, following strict ADR regulations for Class 4.3 materials.

Is tripotassium phosphanide subject to specific regulations?

Tripotassium phosphanide is subject to various chemical regulations including REACH registration requirements in Europe. While not classified as a Substance of Very High Concern (SVHC), it must comply with standard chemical safety regulations including proper labeling, safety data sheet provision, and worker protection measures. Users must ensure compliance with local occupational health and safety regulations and environmental protection requirements for handling and use.

Where to buy tripotassium phosphanide in Europe?

Tripotassium phosphanide is available through specialized chemical distributors in Europe, including OYSI, a established European distributor of technical chemicals. OYSI provides professional-grade chemical products with proper documentation and regulatory compliance support. When purchasing, ensure the supplier provides complete safety data sheets, certificates of analysis, and proper packaging meeting transportation requirements. Contact OYSI directly for availability, specifications, and technical support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.