Tripotassium;phosphanide

H2K3P+2

tripotassium;phosphanide

CAS20770-41-6

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Identification

CAS Number
20770-41-6
EC Number
244-021-5
UN Number
2012
PubChem CID
62745

Physical-chemical properties

Molecular Formula
H2K3P+2
Molar Mass
150.28 g/mol
IUPAC Name
tripotassium;phosphanide

Chemical Identifiers

InChI
InChI=1S/3K.H2P/h;;;1H2/q3*+1;-1
InChI Key
UXNDEGTUDQHWPA-UHFFFAOYSA-N

Overview

Tripotassium phosphanide (CAS 20770-41-6) is an inorganic potassium-phosphorus compound with highly reactive properties and specialized industrial applications. This chemical compound, with the molecular formula H2K3P+2 and a molecular weight of 150.285 g/mol, represents a significant class of alkali metal phosphides used in advanced chemical processes. Tripotassium phosphanide is characterized by its ionic structure, where three potassium cations are associated with a phosphanide anion, creating a compound with distinct reactivity patterns typical of metal phosphides. The compound exhibits considerable reactivity, particularly in the presence of moisture and oxygen, which necessitates careful handling protocols. Its classification under ADR Class 4.3 indicates its nature as a substance that emits flammable gases when in contact with water, requiring specialized storage conditions in inert atmospheres and moisture-free environments. This reactivity profile places it in a similar category to other alkali metal compounds such as potassium sodium alloys, which also demonstrate high reactivity with water and require comparable safety measures. Industrial applications of tripotassium phosphanide primarily focus on specialized chemical synthesis processes, including the production of advanced phosphorus-containing compounds and as an intermediate in organophosphorus chemistry. The compound also finds use in materials science applications, particularly in the development of specialized ceramics and electronic materials where controlled phosphorus incorporation is required. Additionally, it serves as a precursor in the synthesis of phosphine derivatives used in various catalytic processes. The unique properties of tripotassium phosphanide make it valuable for applications requiring precise stoichiometric control of potassium and phosphorus content, distinguishing it from simpler phosphorus compounds in demanding industrial processes. OYSI provides tripotassium phosphanide to qualified industrial customers throughout Europe, ensuring proper handling and compliance with applicable safety regulations.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2012
ADR Class4.3
Packing GroupI
Tunnel CodeE
Proper Shipping NameKaliumphosphid
Marine PollutantNo

Frequently Asked Questions

What is tripotassium phosphanide?

Tripotassium phosphanide is an inorganic chemical compound with the formula H2K3P+2 and CAS number 20770-41-6. This potassium-phosphorus compound has a molecular weight of 150.285 g/mol and belongs to the family of alkali metal phosphides. It is characterized by its unique ionic structure containing potassium cations and phosphanide anions, making it a specialized chemical reagent used in various industrial applications.

What are the physicochemical properties of tripotassium phosphanide?

Tripotassium phosphanide is a solid inorganic compound at room temperature with distinctive physicochemical characteristics. As a potassium phosphide derivative, it typically exhibits high reactivity, particularly with water and moisture. The compound's ionic nature contributes to its solubility behavior and thermal stability. Its molecular structure, containing both hydrogen and potassium ions bonded to phosphorus, influences its chemical reactivity and handling requirements in industrial processes.

What is tripotassium phosphanide used for?

Tripotassium phosphanide serves as a specialized chemical reagent in various industrial and research applications. Its primary uses include acting as a reducing agent in organic synthesis, serving as a phosphorus source in specialized chemical reactions, and functioning as an intermediate in the production of other phosphorus-containing compounds. The compound is particularly valuable in advanced materials science and specialized chemical manufacturing processes requiring controlled phosphorus chemistry.

How to handle tripotassium phosphanide safely?

Tripotassium phosphanide requires careful handling using appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Due to its reactive nature, avoid contact with water and moisture. Use non-sparking tools and ensure all equipment is properly grounded. Emergency washing facilities should be readily accessible during handling operations.

How to store tripotassium phosphanide correctly?

Tripotassium phosphanide must be stored in tightly sealed, moisture-proof containers in a cool, dry, well-ventilated area away from incompatible materials. Keep the compound away from water, acids, and oxidizing agents to prevent dangerous reactions. Storage areas should be equipped with appropriate fire suppression systems and maintained at stable temperatures. Regular inspection of containers for signs of degradation or moisture ingress is essential for safe storage.

What to do in case of contact with tripotassium phosphanide?

Immediate action is required for any contact with tripotassium phosphanide. For skin contact, remove contaminated clothing and wash the affected area thoroughly with plenty of water for at least 15 minutes. In case of eye contact, flush immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move the person to fresh air and provide oxygen if breathing is difficult. Seek immediate medical attention for all exposure incidents.

How to dispose of tripotassium phosphanide appropriately?

Tripotassium phosphanide disposal must comply with local and national hazardous waste regulations. The compound should never be disposed of in regular waste streams or sewage systems due to its reactive nature. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may require neutralization under controlled conditions before disposal. Always consult local environmental authorities for specific disposal requirements and approved treatment facilities.

How to transport tripotassium phosphanide?

Tripotassium phosphanide is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group I, indicating high danger level. Transportation requires specialized packaging meeting UN specifications and proper hazard labeling. Only certified carriers with appropriate permits can transport this material. Documentation must include proper shipping names, hazard classes, and emergency response information. Vehicles must be equipped with appropriate emergency equipment and placarding.

Is tripotassium phosphanide subject to particular regulations?

Tripotassium phosphanide is subject to various chemical safety regulations including REACH registration requirements in Europe. Under the CLP regulation, specific classification and labeling requirements may apply based on hazard assessment. The compound is not currently identified as a Substance of Very High Concern (SVHC). Users must comply with occupational safety regulations, transportation laws (ADR), and local environmental protection requirements for handling and use.

Where to buy tripotassium phosphanide in Europe?

Tripotassium phosphanide is available through OYSI, a specialized European distributor of technical chemicals. As an established chemical supplier, OYSI provides this compound to industrial customers across Europe with appropriate technical documentation and safety data sheets. Professional buyers can contact OYSI directly to inquire about availability, specifications, and delivery options. Proper documentation of intended use may be required for purchase due to the compound's specialized nature.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.