Trimagnesium bis(phosphorus(3-))

Mg3P2

trimagnesium bis(phosphorus(3-))

CAS12057-74-8
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
12057-74-8
EC Number
235-023-7
UN Number
2011
Index Number
015-005-00-3
PubChem CID
61546

Physical-chemical properties

Molecular Formula
Mg3P2
Molar Mass
134.86 g/mol
IUPAC Name
trimagnesium bis(phosphorus(3-))

Chemical Identifiers

InChI
InChI=1S/3Mg.2P/q3*+2;2*-3
InChI Key
VUBDMGXNLNDGIY-UHFFFAOYSA-N

Overview

Trimagnesium bis(phosphorus(3-)) (CAS 12057-74-8) is an inorganic phosphide compound with highly reactive water-sensitive properties and significant toxicity hazards. This binary compound, with the molecular formula Mg3P2 and molecular weight of 134.86 g/mol, represents a critical material in specialized industrial applications requiring phosphorus compounds. The substance exhibits extreme reactivity with water and moisture, leading to its classification under ADR Class 4.3 as a dangerous good that releases flammable gases when in contact with water. This reaction typically produces phosphine gas, contributing to its acute toxicity classifications across multiple exposure routes. The compound's hazard profile demands rigorous handling protocols, as indicated by its GHS danger classification encompassing flammability (GHS02), acute toxicity (GHS06), and environmental hazards (GHS09). Its Water-react. 1 classification signifies the highest level of water reactivity, while multiple acute toxicity categories (Acute Tox. 1, 2, and 3) reflect varying degrees of harm through different exposure pathways. The Aquatic Acute 1 classification highlights its severe environmental impact on aquatic ecosystems. Industrial applications of trimagnesium bis(phosphorus(3-)) primarily center on semiconductor manufacturing, where it serves as a phosphorus source in specialized processes, and in the production of phosphine gas for controlled industrial reactions. The compound also finds use in metallurgical applications requiring precise phosphorus addition. Similar phosphide compounds like aluminum phosphorus(3-) and tricalcium bis(phosphorus(3-)) share comparable reactivity profiles and industrial applications, though each offers distinct advantages based on the specific metallic component. OYSI maintains availability of trimagnesium bis(phosphorus(3-)) for qualified industrial customers requiring this specialized phosphide compound for technical applications.

Safety & Classification

Danger
Classification:

Water-react. 1; Acute Tox. 1; Acute Tox. 3; Acute Tox. 2; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H260

In contact with water releases flammable gases which may ignite spontaneously.

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H300

Fatal if swallowed.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2011
ADR Class4.3
Packing GroupI
Tunnel CodeE
Proper Shipping NameMagnesiumphosphid
Marine PollutantNo

Frequently Asked Questions

What is trimagnesium bis(phosphorus(3-))?

Trimagnesium bis(phosphorus(3-)) is an inorganic compound with the molecular formula Mg3P2 and CAS number 12057-74-8. This magnesium phosphide has a molecular weight of 134.86 g/mol and appears as a crystalline solid. It is classified as a highly dangerous substance due to its water-reactive properties, acute toxicity, and environmental hazards. The compound belongs to the phosphide family and is primarily used in industrial applications requiring phosphorus-containing materials.

What are the physicochemical properties of trimagnesium bis(phosphorus(3-))?

Trimagnesium bis(phosphorus(3-)) is a solid crystalline compound that reacts violently with water, releasing toxic phosphine gas. It has a molecular weight of 134.86 g/mol and is insoluble in water due to its reactive nature. The compound is stable under dry conditions but decomposes rapidly upon contact with moisture or acids. Its water-reactive classification (Water-react. 1) indicates it poses significant hazards when exposed to humidity or aqueous solutions.

What is trimagnesium bis(phosphorus(3-)) used for?

Trimagnesium bis(phosphorus(3-)) is primarily used in specialized industrial applications as a source of phosphorus and magnesium. It serves as a precursor in the synthesis of other phosphorus compounds and materials science applications. The compound may be utilized in metallurgical processes, semiconductor manufacturing, and as a reagent in chemical research. Due to its highly toxic and reactive nature, its use is restricted to controlled industrial environments with appropriate safety measures.

How to handle trimagnesium bis(phosphorus(3-)) safely?

Safe handling of trimagnesium bis(phosphorus(3-)) requires complete personal protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing. Work must be conducted in well-ventilated areas or under inert atmosphere to prevent moisture contact. The compound's acute toxicity classifications (Acute Tox. 1, 2, and 3) demand extreme caution. Never allow contact with water or acids, and ensure emergency procedures are in place for phosphine gas exposure.

How to store trimagnesium bis(phosphorus(3-)) correctly?

Trimagnesium bis(phosphorus(3-)) must be stored in tightly sealed, moisture-proof containers under dry, inert conditions. Storage areas should be cool, well-ventilated, and completely dry to prevent water contact that would generate toxic phosphine gas. The compound is incompatible with water, acids, and oxidizing agents. Storage facilities must comply with regulations for water-reactive substances and include appropriate fire suppression systems suitable for Class 4.3 materials.

What to do in case of contact with trimagnesium bis(phosphorus(3-))?

Immediate action is critical due to the compound's acute toxicity ratings. For skin contact, brush off dry material without using water, then seek immediate medical attention. In case of inhalation, move to fresh air immediately and provide oxygen if breathing is difficult. Never use water for cleanup as this generates toxic phosphine gas. Contact emergency services immediately and inform them of the phosphine gas hazard. All exposure cases require immediate professional medical treatment.

How to dispose of trimagnesium bis(phosphorus(3-)) appropriately?

Disposal of trimagnesium bis(phosphorus(3-)) must be conducted by licensed hazardous waste disposal companies due to its multiple danger classifications. The compound cannot be disposed of in normal waste streams and requires specialized treatment facilities capable of handling water-reactive and acutely toxic materials. Disposal must comply with local and European waste regulations for dangerous substances. Never attempt disposal by water treatment due to phosphine gas generation risks.

How to transport trimagnesium bis(phosphorus(3-))?

Trimagnesium bis(phosphorus(3-)) is classified under ADR Class 4.3 (substances which, in contact with water, emit flammable gases), Packing Group I, indicating maximum danger level. Transportation requires specialized packaging that prevents moisture ingress and complies with dangerous goods regulations. Vehicles must carry appropriate placards and emergency information. Only trained personnel with dangerous goods certification should handle transportation, following strict ADR requirements for water-reactive substances.

Is trimagnesium bis(phosphorus(3-)) subject to specific regulations?

Trimagnesium bis(phosphorus(3-)) is subject to extensive regulatory controls under European legislation including REACH registration requirements and CLP classification. It is not listed as an SVHC substance but requires strict compliance with occupational health regulations due to its acute toxicity classifications. The compound falls under dangerous goods transportation regulations (ADR) and workplace exposure limits. Users must maintain safety data sheets and implement appropriate risk management measures.

Where to buy trimagnesium bis(phosphorus(3-)) in Europe?

Trimagnesium bis(phosphorus(3-)) is available through OYSI, a European distributor specializing in technical chemical products. As a professional chemical distributor, OYSI can provide this specialized compound with appropriate documentation, safety data sheets, and regulatory compliance support. Given the compound's hazardous nature and regulatory requirements, purchase is typically restricted to qualified industrial users with appropriate handling facilities and safety protocols in place.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.