2,4,6-trichlorophenol

C6H3Cl3O

CAS88-06-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Consulting for 2,4,6-trichlorophenol

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Identification

CAS Number
88-06-2
EC Number
201-795-9
UN Number
2020
Index Number
604-018-00-5
PubChem CID
6914

Physical-chemical properties

Molecular Formula
C6H3Cl3O
Molar Mass
197.40 g/mol
IUPAC Name
2,4,6-trichlorophenol

Chemical Identifiers

InChI
InChI=1S/C6H3Cl3O/c7-3-1-4(8)6(10)5(9)2-3/h1-2,10H
InChI Key
LINPIYWFGCPVIE-UHFFFAOYSA-N

Overview

2,4,6-Trichlorophenol (CAS 88-06-2) is a chlorinated phenolic compound with antiseptic and biocidal properties widely used in industrial applications. This organochlorine compound represents one of the most significant trichlorophenol isomers in industrial chemistry, characterized by its three chlorine atoms positioned at the 2, 4, and 6 positions on the benzene ring. With a molecular formula of C6H3Cl3O and molecular weight of 197.4 g/mol, 2,4,6-trichlorophenol appears as a white to pale yellow crystalline solid with a characteristic phenolic odor. The compound's chlorinated structure provides enhanced stability and antimicrobial efficacy compared to simpler phenolic compounds like 4-aminophenol, making it valuable for specialized industrial applications. Safety considerations are paramount when handling this substance, as it carries multiple hazard classifications including suspected carcinogenicity (Carc. 2) and acute toxicity (Acute Tox. 4). The compound exhibits skin and eye irritation properties and presents significant environmental concerns with aquatic toxicity classifications. Proper handling procedures, adequate ventilation, and appropriate personal protective equipment are essential during storage, transportation, and use. Industrial applications of 2,4,6-trichlorophenol primarily focus on its antimicrobial properties, serving as an intermediate in the synthesis of other chemicals and as a preservative in certain industrial formulations. The compound finds use in wood preservation treatments and as a precursor in the manufacture of herbicides and fungicides. Additionally, it serves specialized applications in laboratory research and chemical synthesis processes. OYSI provides high-quality 2,4,6-trichlorophenol to meet diverse industrial requirements across Europe, ensuring reliable supply chains for our technical customers' specialized applications.

Safety & Classification

Warning
Classification:

Carc. 2; Acute Tox. 4 *; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H302

Harmful if swallowed.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2020
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping Name2,4,6-Trichlorphenol, fest, frei von TCDD
Marine PollutantNo

Frequently Asked Questions

What is 2,4,6-trichlorophenol?

2,4,6-trichlorophenol is an organochlorine compound with the molecular formula C6H3Cl3O and CAS number 88-06-2. This chemical substance has a molecular weight of 197.4 g/mol and belongs to the phenol family with three chlorine atoms substituted at positions 2, 4, and 6 on the benzene ring. It is classified as a hazardous substance with carcinogenic, toxic, irritating, and environmentally harmful properties according to CLP regulation.

What are the physicochemical properties of 2,4,6-trichlorophenol?

2,4,6-trichlorophenol is typically a crystalline solid at room temperature with a characteristic phenolic odor. It appears as white to pale yellow crystals and has limited solubility in water but dissolves well in organic solvents like alcohols and ethers. The compound has a melting point around 69°C and is relatively stable under normal conditions. Its chlorinated structure makes it persistent in the environment and resistant to biodegradation.

What is 2,4,6-trichlorophenol used for?

2,4,6-trichlorophenol is primarily used as an intermediate in the synthesis of pesticides, fungicides, and herbicides. It serves as a precursor in the production of other chlorinated organic compounds and can be used in wood preservation treatments. The compound also finds applications in the manufacturing of dyes, pharmaceuticals, and specialty chemicals. Due to its antimicrobial properties, it may be used in certain disinfectant formulations, though its use is increasingly restricted due to environmental and health concerns.

How to handle 2,4,6-trichlorophenol safely?

2,4,6-trichlorophenol requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection when necessary. Work should be conducted in well-ventilated areas or under fume extraction systems to minimize inhalation exposure. Avoid skin and eye contact, and prevent ingestion. Use non-sparking tools and equipment, and ensure proper grounding to prevent static electricity buildup. Always follow good industrial hygiene practices and wash hands thoroughly after handling.

How to store 2,4,6-trichlorophenol correctly?

2,4,6-trichlorophenol should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from direct sunlight and heat sources. Keep containers away from incompatible materials such as strong oxidizers and bases. Storage areas should be equipped with appropriate spill containment measures and fire suppression systems. Maintain storage temperatures below 25°C when possible, and ensure containers are properly labeled according to CLP requirements. Regular inspection of storage conditions and container integrity is essential.

What to do in case of contact with 2,4,6-trichlorophenol?

In case of skin contact with 2,4,6-trichlorophenol, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for 15-20 minutes and remove contact lenses if easily removable. If inhaled, move the person to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms persist or in case of significant exposure.

How to dispose of 2,4,6-trichlorophenol properly?

2,4,6-trichlorophenol disposal must comply with local and national hazardous waste regulations as it is classified as dangerous waste. The substance should never be discharged into sewers, waterways, or soil due to its environmental toxicity. Disposal should be carried out through licensed hazardous waste treatment facilities capable of handling chlorinated organic compounds. Incineration at high temperatures in specialized facilities is typically the preferred disposal method. Always consult local environmental authorities for specific disposal requirements and approved waste management companies.

How to transport 2,4,6-trichlorophenol?

2,4,6-trichlorophenol is classified under ADR as Class 6.1 (Toxic substances), Packing Group III, indicating moderate toxicity for transport purposes. Transportation must comply with ADR regulations including proper packaging, labeling, and documentation requirements. Vehicles must carry appropriate placarding and emergency response information. Drivers require ADR certification for Class 6.1 substances. Packaging must meet UN specification standards and be properly sealed and labeled with the correct shipping name and hazard labels.

Is 2,4,6-trichlorophenol subject to specific regulations?

2,4,6-trichlorophenol is subject to various regulatory frameworks including REACH registration requirements for manufacture or import above one tonne per year. Under CLP regulation, it must be classified and labeled according to its hazard profile with appropriate warning pictograms (GHS07, GHS08, GHS09). The substance may be subject to restrictions under various national and EU regulations due to its carcinogenic and environmental properties. Users must comply with occupational exposure limits and environmental discharge restrictions where applicable.

Where to buy 2,4,6-trichlorophenol in Europe?

2,4,6-trichlorophenol is available through OYSI, a specialized European distributor of industrial chemicals. OYSI provides this substance to qualified industrial users with proper regulatory compliance and technical support. As a restricted chemical, purchases typically require demonstration of legitimate industrial use and compliance with relevant safety and environmental regulations. OYSI ensures proper packaging, documentation, and delivery according to ADR transport regulations throughout Europe, supporting customers with technical expertise and regulatory guidance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.