9-ethenylcarbazole

C14H11N

CAS1484-13-5
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
1484-13-5
EC Number
216-055-0
UN Number
2811
Index Number
613-169-00-6
PubChem CID
15143

Physical-chemical properties

Molecular Formula
C14H11N
Molar Mass
193.24 g/mol
IUPAC Name
9-ethenylcarbazole

Chemical Identifiers

InChI
InChI=1S/C14H11N/c1-2-15-13-9-5-3-7-11(13)12-8-4-6-10-14(12)15/h2-10H,1H2
InChI Key
KKFHAJHLJHVUDM-UHFFFAOYSA-N

Overview

9-Ethenylcarbazole (CAS 1484-13-5) is an organic nitrogen-containing compound with reactive vinyl functionality and carbazole backbone structure. This versatile chemical intermediate belongs to the carbazole family, characterized by its tricyclic aromatic structure featuring a central pyrrole ring fused between two benzene rings, with an ethenyl (vinyl) group attached to the nitrogen atom. The compound appears as a solid material with a molecular weight of 193.24 g/mol and exhibits unique photophysical properties that make it valuable in various industrial applications. From a safety perspective, 9-ethenylcarbazole requires careful handling due to its classification as a Category 2 mutagen and Category 4 acute toxicant. The compound can cause skin irritation and sensitization, necessitating appropriate personal protective equipment during handling. Its environmental classification as Aquatic Acute 1 indicates potential harm to aquatic organisms, requiring controlled disposal and storage procedures. The ADR Class 6.1 classification confirms its toxic nature for transportation purposes. The primary industrial applications of 9-ethenylcarbazole include its use as a monomer in polymer synthesis, particularly in the production of specialized conducting polymers and photoactive materials. Its carbazole structure makes it valuable in organic electronics applications, including OLED materials and photovoltaic devices. Additionally, the compound serves as an intermediate in pharmaceutical synthesis and specialty chemical manufacturing. Unlike simpler aromatic compounds such as 4-aminophenol, 9-ethenylcarbazole offers enhanced electronic properties due to its extended conjugated system. OYSI provides reliable access to 9-ethenylcarbazole for European industrial customers, ensuring consistent quality and regulatory compliance for demanding technical applications.

Safety & Classification

Warning
Classification:

Muta. 2; Acute Tox. 4 *; Acute Tox. 4 *; Skin Irrit. 2; Skin Sens. 1; Aquatic Acute 1; Aquatic Ch...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H315

Causes skin irritation.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2811
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name9-Vinylcarbazol
Marine PollutantNo

Frequently Asked Questions

What is 9-ethenylcarbazole?

9-ethenylcarbazole is an organic compound with the molecular formula C14H11N and CAS number 1484-13-5. It belongs to the carbazole family, featuring a vinyl group attached to the nitrogen atom of the carbazole ring system. With a molecular weight of 193.24 g/mol, this compound is classified as hazardous with mutagenic properties and various toxicity concerns, requiring careful handling in industrial applications.

What are the physicochemical properties of 9-ethenylcarbazole?

9-ethenylcarbazole is a solid organic compound at room temperature, typically appearing as crystalline material. As a carbazole derivative, it exhibits aromatic stability and contains a nitrogen heteroatom within its ring structure. The compound has limited water solubility due to its aromatic nature but shows better solubility in organic solvents. Its vinyl functionality makes it reactive toward polymerization reactions.

What is 9-ethenylcarbazole used for?

9-ethenylcarbazole is primarily used as a monomer in polymer synthesis and as an intermediate in organic chemistry. Its vinyl group enables polymerization reactions, making it valuable for producing specialized polymers with carbazole units. The compound finds applications in materials science, particularly in the development of conductive polymers, optoelectronic materials, and advanced composite materials where carbazole's electronic properties are desired.

How to handle 9-ethenylcarbazole safely?

9-ethenylcarbazole requires careful handling due to its mutagenic and toxic properties. Personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing must be worn. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation. Avoid skin contact and ingestion. The compound is classified as a skin irritant and sensitizer, requiring immediate washing if contact occurs.

How to store 9-ethenylcarbazole correctly?

9-ethenylcarbazole should be stored in a cool, dry place away from heat sources and direct sunlight. The compound must be kept in tightly sealed containers to prevent moisture absorption and oxidation. Due to its vinyl functionality, storage should avoid conditions that could trigger polymerization. Keep away from strong oxidizing agents and maintain storage temperatures below recommended limits to ensure product stability and safety.

What to do in case of contact with 9-ethenylcarbazole?

9-ethenylcarbazole contact requires immediate action due to its toxic and irritating properties. For skin contact, immediately remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush with clean water for 15 minutes while holding eyelids open. If ingested or inhaled, seek immediate medical attention and provide safety data sheet information to medical personnel.

How to dispose of 9-ethenylcarbazole properly?

9-ethenylcarbazole disposal must comply with local hazardous waste regulations due to its toxic and mutagenic properties. The compound cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies for proper handling. Containers should be completely emptied and may require special treatment. Never discharge into sewers, water bodies, or soil due to its aquatic toxicity classification.

How to transport 9-ethenylcarbazole?

9-ethenylcarbazole is classified under ADR Class 6.1 (Toxic substances), Packaging Group II, indicating significant transport hazards. Transportation requires appropriate dangerous goods packaging, labeling with toxic substance markings, and proper documentation including transport emergency cards. Vehicles must comply with ADR regulations for toxic substances. Only trained personnel should handle shipments, and emergency procedures must be available during transport.

Is 9-ethenylcarbazole subject to specific regulations?

9-ethenylcarbazole is subject to multiple European regulations including REACH registration requirements and CLP classification obligations. The compound is classified with GHS pictograms GHS08, GHS07, and GHS09, indicating health, irritation, and environmental hazards. While not currently listed as SVHC, its mutagenic classification (Muta. 2) requires compliance with occupational exposure limits and risk assessment procedures under workplace safety regulations.

Where to buy 9-ethenylcarbazole in Europe?

9-ethenylcarbazole is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this compound with full regulatory compliance including proper classification, safety data sheets, and transport documentation. As a professional chemical distributor, OYSI ensures product quality and regulatory adherence for industrial customers across Europe requiring this specialized carbazole derivative for their manufacturing processes.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.