2-nitropropane

C3H7NO2

CAS79-46-9
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
Danger

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Identification

CAS Number
79-46-9
EC Number
201-209-1
UN Number
2608
Index Number
609-002-00-1
PubChem CID
398

Physical-chemical properties

Molecular Formula
C3H7NO2
Molar Mass
89.09 g/mol
IUPAC Name
2-nitropropane

Chemical Identifiers

InChI
InChI=1S/C3H7NO2/c1-3(2)4(5)6/h3H,1-2H3
InChI Key
FGLBSLMDCBOPQK-UHFFFAOYSA-N

Overview

2-nitropropane (CAS 79-46-9) is a flammable nitroalkane solvent with significant industrial applications and notable safety considerations due to its carcinogenic properties. This colorless liquid organic compound serves as an important industrial solvent and chemical intermediate in various manufacturing processes. With its molecular formula C3H7NO2 and molecular weight of 89.09 g/mol, 2-nitropropane belongs to the nitroalkane family and exhibits characteristic properties that make it valuable for specific technical applications, despite requiring careful handling protocols. The compound is classified under multiple hazard categories, including Flammable Liquid Category 3 and Carcinogen Category 1B, necessitating comprehensive safety measures during storage, handling, and transportation. Its ADR Class 3 designation reflects its flammable nature, while the associated GHS pictograms (GHS02, GHS08, GHS07) clearly communicate the fire, health, and acute toxicity hazards to users. The "Danger" signal word emphasizes the serious nature of these risks. In industrial applications, 2-nitropropane functions primarily as a solvent for various polymers, resins, and coatings, particularly in specialized formulations where its unique solvating properties are essential. It also serves as an intermediate in organic synthesis processes and finds use in certain adhesive formulations. Unlike related compounds such as ethylbenzene or styrene, which are primarily used in polymer production, 2-nitropropane's nitro functionality provides distinct chemical reactivity patterns. The compound requires specialized handling equipment and trained personnel due to its hazardous classification, making proper supplier selection crucial for industrial users. OYSI provides technical-grade 2-nitropropane with comprehensive safety documentation and regulatory compliance support for European industrial customers.

Safety & Classification

Danger
Classification:

Flam. Liq. 3; Carc. 1B; Acute Tox. 4 *; Acute Tox. 4 *

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H350

May cause cancer.

H332

Harmful if inhaled.

H302

Harmful if swallowed.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2608
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping Name2-Nitropropan
Marine PollutantNo

Frequently Asked Questions

What is 2-nitropropane?

2-nitropropane is an organic chemical compound with the molecular formula C3H7NO2 and CAS number 79-46-9. It belongs to the nitroalkane family, featuring a nitro group (-NO2) attached to the central carbon of a propane chain. With a molecular weight of 89.09 g/mol, this substance is classified as a flammable liquid and carcinogen category 1B, requiring careful handling due to its significant health and safety hazards.

What are the physicochemical properties of 2-nitropropane?

2-nitropropane is a colorless liquid at room temperature with a characteristic sweet, fruity odor. It has moderate solubility in water and is miscible with most organic solvents including alcohols and ethers. The compound has a boiling point of approximately 120°C and a flash point around 24°C, making it a flammable liquid. Its density is higher than water at about 0.99 g/cm³.

What is 2-nitropropane used for?

2-nitropropane is primarily used as a solvent in industrial applications, particularly for cellulose compounds, resins, and dyes. It serves as an intermediate in organic synthesis and pharmaceutical manufacturing. The compound is also utilized in rocket propellants and as a fuel additive. Additionally, it finds applications in the production of specialty chemicals and as a reaction medium in various chemical processes requiring aprotic solvents.

How to handle 2-nitropropane safely?

2-nitropropane requires strict safety measures due to its carcinogenic and flammable properties. Use appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work in well-ventilated areas or under fume hoods to prevent inhalation. Eliminate ignition sources and use explosion-proof equipment. Ground all containers during transfer operations and avoid skin contact. Regular health monitoring is essential for workers with potential exposure.

How to store 2-nitropropane correctly?

2-nitropropane must be stored in cool, dry, well-ventilated areas away from heat sources and ignition points. Keep containers tightly sealed in original packaging, preferably in fireproof cabinets designed for flammable liquids. Store away from incompatible materials such as strong oxidizers, acids, and bases. Maintain storage temperature below 25°C and implement proper fire suppression systems. Regular inspection of containers for leaks is mandatory.

What to do in case of contact with 2-nitropropane?

Immediate action is crucial upon contact with 2-nitropropane. For skin contact, remove contaminated clothing and wash thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention. In case of eye contact, flush with clean water for 15 minutes and remove contact lenses if present. If ingested, do not induce vomiting and seek immediate medical care. Always consult emergency services for serious exposures.

How to dispose of 2-nitropropane appropriately?

2-nitropropane disposal must comply with local and national hazardous waste regulations due to its carcinogenic properties. The substance cannot be disposed of in regular waste streams and requires specialized treatment at licensed hazardous waste facilities. Incineration at high temperatures with appropriate emission controls is the preferred method. Small quantities should be collected in appropriate containers and handed over to certified waste management companies. Never discharge into sewers or environment.

How to transport 2-nitropropane?

2-nitropropane is classified under ADR as Class 3 (flammable liquids), Packing Group III for transportation purposes. It must be packaged in UN-approved containers with proper labeling including GHS02, GHS07, and GHS08 pictograms and 'Danger' signal word. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require ADR certification for dangerous goods transport. Ensure proper segregation from incompatible materials during shipping.

Is 2-nitropropane subject to specific regulations?

2-nitropropane is subject to extensive regulatory oversight under REACH, CLP, and occupational safety regulations due to its carcinogenic classification (Category 1B). It requires safety data sheets and proper hazard communication. Workplace exposure limits are strictly regulated, and employers must implement comprehensive risk assessments. The substance may face restrictions in certain applications and requires authorization for specific uses under REACH Annex XIV provisions.

Where to buy 2-nitropropane in Europe?

2-nitropropane is available through specialized chemical distributors in Europe, including OYSI, which supplies high-quality industrial chemicals across European markets. Due to its hazardous classification, purchase requires proper documentation, safety assessments, and compliance with regulatory requirements. Suppliers must provide comprehensive safety data sheets and ensure appropriate packaging. Contact OYSI's technical team for availability, specifications, and regulatory guidance for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.