2-hydroxyethyl prop-2-enoate

C5H8O3

CAS818-61-1
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
818-61-1
EC Number
212-454-9
UN Number
2922
Index Number
607-072-00-8
PubChem CID
13165

Physical-chemical properties

Molecular Formula
C5H8O3
Molar Mass
116.11 g/mol
IUPAC Name
2-hydroxyethyl prop-2-enoate

Chemical Identifiers

InChI
InChI=1S/C5H8O3/c1-2-5(7)8-4-3-6/h2,6H,1,3-4H2
InChI Key
OMIGHNLMNHATMP-UHFFFAOYSA-N

Overview

2-hydroxyethyl prop-2-enoate (CAS 818-61-1) is an acrylic ester monomer with reactive vinyl functionality and hydroxyl group for crosslinking applications. This versatile chemical compound, also known by its IUPAC name 2-hydroxyethyl prop-2-enoate, represents an important member of the hydroxyalkyl acrylate family used extensively in polymer chemistry and coating formulations. With the molecular formula C5H8O3 and a molecular weight of 116.11 g/mol, this clear liquid monomer combines the reactivity of an acrylic double bond with the functionality of a primary hydroxyl group, making it particularly valuable for creating crosslinked polymer networks. The compound exhibits significant safety considerations, classified under multiple hazard categories including acute toxicity, skin corrosion, and skin sensitization. Its classification as Acute Tox. 3, Skin Corr. 1B, and Skin Sens. 1 requires careful handling with appropriate personal protective equipment. The substance also presents aquatic toxicity concerns (Aquatic Acute 1) and is classified under ADR Class 8 for transport purposes, indicating its corrosive properties. Industrial applications of 2-hydroxyethyl prop-2-enoate span across multiple sectors, particularly in the formulation of UV-curable coatings, adhesives, and sealants where its dual functionality enables both polymerization and crosslinking. The compound serves as a key building block in acrylic resin production and finds extensive use in dental materials and biomedical applications. Unlike simpler compounds such as pentanedial, this acrylate monomer offers superior film-forming properties and durability in protective coating applications. OYSI maintains reliable supplies of 2-hydroxyethyl prop-2-enoate to support European industrial customers across various technical applications, ensuring consistent quality and regulatory compliance for demanding manufacturing processes.

Safety & Classification

Danger
Classification:

Acute Tox. 3 *; Skin Corr. 1B; Skin Sens. 1; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H311

Toxic in contact with skin.

H314

Causes severe skin burns and eye damage.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2922
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping Name2-Hydroxyethylacrylat, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is 2-hydroxyethyl prop-2-enoate?

2-hydroxyethyl prop-2-enoate is an organic chemical compound with the molecular formula C5H8O3 and CAS number 818-61-1. This acrylate ester has a molecular weight of 116.11 g/mol and belongs to the family of hydroxyalkyl acrylates. It is classified as a hazardous substance with corrosive and sensitizing properties, requiring careful handling in industrial applications.

What are the physicochemical properties of 2-hydroxyethyl prop-2-enoate?

2-hydroxyethyl prop-2-enoate is typically a clear to slightly yellow liquid at room temperature with a characteristic acrylic odor. As an acrylate ester containing a hydroxyl group, it exhibits good solubility in polar solvents and water. The compound has a relatively low molecular weight of 116.11 g/mol and contains both hydrophilic and hydrophobic functional groups, making it useful as a reactive intermediate in polymer chemistry.

What is 2-hydroxyethyl prop-2-enoate used for?

2-hydroxyethyl prop-2-enoate is primarily used as a monomer in the production of acrylic polymers and copolymers. It serves as a reactive diluent in UV-curable coatings, adhesives, and inks. The compound is also utilized in the manufacture of hydrogels, textile finishes, and as a crosslinking agent in various polymer applications due to its hydroxyl functionality that enables further chemical modifications.

How to handle 2-hydroxyethyl prop-2-enoate safely?

2-hydroxyethyl prop-2-enoate must be handled with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing due to its Skin Corr. 1B classification. Work in well-ventilated areas or under fume hoods to avoid inhalation. Prevent skin and eye contact as the substance can cause severe burns and sensitization. Emergency eyewash and shower facilities should be readily accessible in work areas.

How to store 2-hydroxyethyl prop-2-enoate correctly?

2-hydroxyethyl prop-2-enoate should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight to prevent polymerization. Keep containers tightly closed and store in original packaging. Due to its corrosive nature, use appropriate containment materials and avoid contact with incompatible substances such as strong bases, oxidizing agents, and metals. Temperature control is essential to maintain product stability.

What to do in case of contact with 2-hydroxyethyl prop-2-enoate?

In case of skin contact with 2-hydroxyethyl prop-2-enoate, immediately remove contaminated clothing and flush the affected area with plenty of water for at least 15 minutes. For eye contact, rinse thoroughly with water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Seek immediate medical attention in all cases due to the substance's corrosive properties and potential for causing chemical burns.

How to dispose of 2-hydroxyethyl prop-2-enoate properly?

2-hydroxyethyl prop-2-enoate must be disposed of in accordance with local, national, and international environmental regulations as hazardous waste. The substance cannot be discharged into sewers or waterways due to its aquatic toxicity classification (Aquatic Acute 1). Contact licensed waste disposal companies for proper treatment and disposal. Empty containers should also be handled as hazardous waste and properly cleaned before disposal or recycling.

How to transport 2-hydroxyethyl prop-2-enoate?

2-hydroxyethyl prop-2-enoate is classified as ADR Class 8 (Corrosive substances), Packing Group II, requiring specific transport regulations compliance. Packages must bear appropriate hazard labels and be properly marked with the correct shipping name and UN number. Use approved packaging suitable for corrosive liquids and ensure vehicles are equipped for transporting dangerous goods with trained personnel and proper documentation.

Is 2-hydroxyethyl prop-2-enoate subject to specific regulations?

2-hydroxyethyl prop-2-enoate is subject to REACH regulation for registration and evaluation within the EU. The substance must comply with CLP regulation for classification, labeling, and packaging requirements, displaying GHS06, GHS05, and GHS09 pictograms with 'Danger' signal word. It is not currently listed as an SVHC (Substance of Very High Concern) but requires compliance with occupational safety and environmental protection standards.

Where to buy 2-hydroxyethyl prop-2-enoate in Europe?

2-hydroxyethyl prop-2-enoate is available through OYSI, a specialized European distributor of technical chemicals. OYSI provides this substance to industrial customers across Europe with proper documentation, safety data sheets, and regulatory compliance support. As a professional chemical supplier, OYSI ensures quality products meeting European standards and provides technical support for safe handling and application guidance to customers in various industries.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.