Tricyclohexylstannanylium hydroxide

C18H34OSn

tricyclohexylstannanylium hydroxide

CAS13121-70-5
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
13121-70-5
EC Number
236-049-1
UN Number
2786
Index Number
050-002-00-0
PubChem CID
9864905

Physical-chemical properties

Molecular Formula
C18H34OSn
Molar Mass
385.20 g/mol
IUPAC Name
tricyclohexylstannanylium hydroxide

Chemical Identifiers

InChI
InChI=1S/3C6H11.H2O.Sn/c3*1-2-4-6-5-3-1;;/h3*1H,2-6H2;1H2;/q;;;;+1/p-1
InChI Key
WCMMILVIRZAPLE-UHFFFAOYSA-M

Overview

Tricyclohexylstannanylium hydroxide (CAS 13121-70-5) is an organotin compound characterized by its three cyclohexyl groups attached to a tin center with hydroxide functionality. This specialized organotin compound represents an important class of organometallic chemicals widely utilized in industrial applications. With the molecular formula C18H34OSn and a molecular weight of 385.2 g/mol, tricyclohexylstannanylium hydroxide exhibits the characteristic properties of tin-based organometallic compounds while maintaining unique reactivity due to its bulky cyclohexyl substituents and hydroxide group. The compound is classified under EC number 236-049-1 and requires careful handling protocols due to its toxicological profile. The substance presents moderate acute toxicity hazards across multiple exposure routes, as indicated by its Acute Tox. 4 classifications and Warning signal word. Safety considerations include its significant aquatic toxicity, classified as both Aquatic Acute 1 and Aquatic Chronic 1, necessitating strict environmental protection measures during handling and disposal. The compound displays GHS07 and GHS09 pictograms, reflecting both health hazards and environmental dangers. Transportation falls under ADR Class 6.1, indicating its toxic nature. Industrial applications of tricyclohexylstannanylium hydroxide primarily focus on catalytic processes and specialized chemical synthesis, where its unique tin-carbon framework provides specific reactivity patterns. The compound finds use in polymer chemistry and as an intermediate in fine chemical manufacturing. Unlike simpler organometallic compounds such as tellanylidenecadmium, this organotin derivative offers enhanced stability and selectivity in certain catalytic applications. OYSI maintains reliable supply chains for tricyclohexylstannanylium hydroxide, ensuring consistent availability for European industrial customers requiring this specialized organometallic compound.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; Acute Tox. 4 *; Acute Tox. 4 *; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H332

Harmful if inhaled.

H312

Harmful in contact with skin.

H302

Harmful if swallowed.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2786
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NameCyhexatin (ISO)
Marine PollutantNo

Frequently Asked Questions

What is tricyclohexylstannanylium hydroxide?

Tricyclohexylstannanylium hydroxide is an organotin compound with the molecular formula C18H34OSn and CAS number 13121-70-5. This chemical substance has a molecular weight of 385.2 g/mol and belongs to the class of organometallic compounds containing tin. It is classified as moderately toxic (Acute Tox. 4) and highly toxic to aquatic life, requiring careful handling and environmental protection measures during use.

What are the physicochemical properties of tricyclohexylstannanylium hydroxide?

Tricyclohexylstannanylium hydroxide is an organometallic compound containing tin with three cyclohexyl groups. The compound has a molecular weight of 385.2 g/mol and contains both organic cyclohexyl moieties and an inorganic tin-hydroxide functionality. As an organotin compound, it likely exhibits moderate polarity due to the presence of the hydroxide group, while the cyclohexyl groups contribute to its organic character and potential lipophilicity.

What is tricyclohexylstannanylium hydroxide used for?

Tricyclohexylstannanylium hydroxide is primarily used as a catalyst or reagent in organic synthesis and chemical manufacturing processes. Organotin compounds like this are commonly employed in polymerization reactions, as stabilizers in plastic production, and as intermediates in the synthesis of other organotin derivatives. Its specific application depends on its catalytic properties and the unique reactivity profile provided by the tin center and cyclohexyl substituents.

How to handle tricyclohexylstannanylium hydroxide safely?

Tricyclohexylstannanylium hydroxide requires careful handling due to its Acute Tox. 4 classification and GHS07 warning pictogram. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume hoods to avoid inhalation exposure. Prevent skin and eye contact, and avoid ingestion. Follow good chemical hygiene practices and have emergency procedures readily available.

How to store tricyclohexylstannanylium hydroxide correctly?

Tricyclohexylstannanylium hydroxide should be stored in a cool, dry place away from incompatible materials and ignition sources. Keep containers tightly sealed to prevent moisture ingress and contamination. Store in secondary containment to prevent environmental release, given its high aquatic toxicity (GHS09 pictogram). Maintain appropriate inventory controls and ensure storage areas have adequate ventilation and spill containment measures.

What to do in case of contact with tricyclohexylstannanylium hydroxide?

In case of skin contact with tricyclohexylstannanylium hydroxide, immediately remove contaminated clothing and wash affected areas thoroughly with soap and water for at least 15 minutes. If eye contact occurs, rinse immediately with clean water for 15-20 minutes and remove contact lenses if present. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention, providing the safety data sheet to healthcare providers.

How to dispose of tricyclohexylstannanylium hydroxide appropriately?

Tricyclohexylstannanylium hydroxide must be disposed of as hazardous waste through licensed waste management facilities due to its toxicity and environmental hazard classification. Never discharge to sewers, water bodies, or soil due to its high aquatic toxicity (Aquatic Acute 1, Aquatic Chronic 1). Contact certified hazardous waste disposal companies and follow local environmental regulations. Ensure proper waste classification and documentation for traceability and regulatory compliance.

How to transport tricyclohexylstannanylium hydroxide?

Tricyclohexylstannanylium hydroxide is classified as ADR Class 6.1 (toxic substances) Packing Group II, indicating moderate toxicity requiring specific transport precautions. Use appropriate UN-specification packaging and ensure proper labeling with hazard diamonds and shipping documentation. Drivers must hold ADR certification for Class 6.1 materials. Follow dangerous goods transport regulations including segregation requirements, loading restrictions, and emergency response information during transit.

Is tricyclohexylstannanylium hydroxide subject to specific regulations?

Tricyclohexylstannanylium hydroxide is subject to REACH regulation in Europe requiring registration for commercial use above tonnage thresholds. It falls under CLP classification as Acute Tox. 4 and aquatic hazard categories, mandating appropriate labeling and safety data sheets. The compound is not currently listed as a Substance of Very High Concern (SVHC). Users must comply with occupational safety regulations and environmental protection requirements for toxic substances.

Where to buy tricyclohexylstannanylium hydroxide in Europe?

Tricyclohexylstannanylium hydroxide is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers. OYSI provides reliable supply chains for organotin compounds with proper regulatory compliance and technical support. Contact OYSI directly for availability, specifications, packaging options, and delivery throughout Europe. Ensure your application complies with local regulations before ordering this regulated chemical substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.