1,2-dichlorobenzene
C6H4Cl2
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Identification
- CAS Number
- 95-50-1
- EC Number
- 202-425-9
- UN Number
- 1591
- Index Number
- 602-034-00-7
- PubChem CID
- 7239
Physical-chemical properties
- Molecular Formula
- C6H4Cl2
- Molar Mass
- 147.00 g/mol
- IUPAC Name
- 1,2-dichlorobenzene
Chemical Identifiers
- InChI
- InChI=1S/C6H4Cl2/c7-5-3-1-2-4-6(5)8/h1-4H
- InChI Key
- RFFLAFLAYFXFSW-UHFFFAOYSA-N
Overview
1,2-dichlorobenzene (CAS 95-50-1) is an aromatic chlorinated hydrocarbon characterized by its ortho-substitution pattern and moderate toxicity profile. This organic compound, also known as ortho-dichlorobenzene, represents one of three isomeric forms of dichlorobenzene where two chlorine atoms are attached to adjacent carbon positions on the benzene ring. With a molecular formula of C6H4Cl2 and molecular weight of 147 g/mol, 1,2-dichlorobenzene appears as a colorless to pale yellow liquid with a characteristic aromatic odor. The compound exhibits moderate volatility and limited water solubility, making it particularly useful as an industrial solvent and chemical intermediate. From a safety perspective, 1,2-dichlorobenzene is classified under multiple hazard categories including acute toxicity category 4, skin and eye irritation category 2, and specific target organ toxicity category 3. The substance poses significant environmental concerns with acute and chronic aquatic toxicity classifications, requiring careful handling and disposal procedures. Transport regulations classify it under ADR class 6.1, reflecting its toxic nature during transportation. Industrial applications primarily focus on its solvent properties and role as a chemical intermediate. The compound serves effectively as a solvent for waxes, gums, resins, and oils in manufacturing processes. It functions as an important intermediate in the production of specialized chemicals and pharmaceuticals, where its selective reactivity proves valuable. Additionally, 1,2-dichlorobenzene finds use in metal degreasing operations, similar to applications involving other chlorinated compounds like 2-(2,4,5-trichlorophenoxy)acetic acid in specialized industrial processes. OYSI maintains reliable supply chains for 1,2-dichlorobenzene to support European industrial customers requiring this versatile chlorinated aromatic compound.
Safety & Classification
Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
Eye Contact
Measures if substance gets into the eyes
First Aid Actions
- +P305IF IN EYES:
- +P351Rinse cautiously with water for several minutes.
- +P338Remove contact lenses, if present and easy to do. Continue rinsing.
- +P313Get medical advice/attention.
Related hazard statements:
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1591 |
| ADR Class | 6.1 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | o-Dichlorbenzen |
| Marine Pollutant | No |
Frequently Asked Questions
What is 1,2-dichlorobenzene?
1,2-dichlorobenzene is an organochlorine compound with the molecular formula C6H4Cl2 and CAS number 95-50-1. This aromatic compound consists of a benzene ring with two chlorine atoms attached to adjacent carbon atoms (ortho position). With a molecular weight of 147 g/mol, it belongs to the dichlorobenzene isomer family and is classified as a hazardous chemical requiring proper handling and safety measures.
What are the physicochemical properties of 1,2-dichlorobenzene?
1,2-dichlorobenzene is a colorless to pale yellow liquid at room temperature with a characteristic aromatic odor. It has a boiling point of approximately 180°C and a melting point of -17°C. The compound is practically insoluble in water but readily soluble in organic solvents such as alcohol, ether, and benzene. It has a density higher than water and exhibits low volatility at ambient temperatures.
What is 1,2-dichlorobenzene used for?
1,2-dichlorobenzene serves primarily as an industrial solvent and chemical intermediate in various manufacturing processes. It is commonly used in the production of dyes, pesticides, and other organic chemicals. The compound also finds applications as a degreasing agent, in metal cleaning operations, and as a process solvent in chemical synthesis. Additionally, it may be used in specialized applications requiring its specific solvent properties.
How to handle 1,2-dichlorobenzene safely?
1,2-dichlorobenzene requires careful handling due to its classification as Acute Tox. 4, Skin Irrit. 2, and Eye Irrit. 2. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation to prevent inhalation exposure. Avoid direct skin and eye contact, and never eat, drink, or smoke while handling. Work in well-ventilated areas or use local exhaust ventilation systems.
How to store 1,2-dichlorobenzene correctly?
1,2-dichlorobenzene should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Keep containers upright and protected from physical damage. Store separately from incompatible materials such as strong oxidizing agents, strong bases, and reactive metals. Ensure storage areas are equipped with appropriate spill containment measures and maintain temperatures below 25°C when possible.
What to do in case of contact with 1,2-dichlorobenzene?
In case of skin contact with 1,2-dichlorobenzene, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. For eye contact, rinse immediately with plenty of clean water for at least 15 minutes while holding eyelids open. If inhaled, move the person to fresh air immediately. Seek medical attention if irritation persists or if symptoms develop. Never induce vomiting if swallowed.
How to dispose of 1,2-dichlorobenzene properly?
1,2-dichlorobenzene must be disposed of as hazardous waste in accordance with local, national, and international regulations. Never dispose of it down drains, into soil, or with regular waste. Contact licensed hazardous waste disposal companies for proper treatment and disposal. The waste classification includes both toxicity and aquatic environment hazard categories. Ensure proper waste characterization and documentation for regulatory compliance before disposal.
How to transport 1,2-dichlorobenzene?
1,2-dichlorobenzene is classified under ADR as Class 6.1 (toxic substances) Packing Group III, indicating moderate toxicity during transport. It must be packaged in UN-approved containers with proper labeling including GHS07 and GHS09 pictograms and 'Warning' signal word. Transport documents must include the proper shipping name, UN number, and hazard class. Vehicles must carry appropriate emergency equipment and drivers require ADR certification for toxic materials.
Is 1,2-dichlorobenzene subject to specific regulations?
1,2-dichlorobenzene is subject to various European regulations including REACH registration requirements and CLP classification as Acute Tox. 4, STOT SE 3, Skin Irrit. 2, Eye Irrit. 2, and Aquatic hazard categories. While not currently listed as an SVHC (Substance of Very High Concern), it requires safety data sheets and appropriate hazard communication. Users must comply with occupational exposure limits and environmental protection measures under relevant national implementations.
Where to buy 1,2-dichlorobenzene in Europe?
1,2-dichlorobenzene is available through OYSI, a European distributor of technical chemicals specializing in industrial and professional applications. OYSI provides this regulated substance to qualified customers with proper documentation, safety data sheets, and regulatory compliance support. As a specialized chemical distributor, OYSI ensures product quality, proper packaging, and adherence to European chemical regulations including REACH and CLP requirements for professional users.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.