Chloromercury

Cl2Hg2

chloromercury

CAS10112-91-1
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
10112-91-1
EC Number
233-307-5
UN Number
2025
Index Number
080-003-00-1
PubChem CID
24956

Physical-chemical properties

Molecular Formula
Cl2Hg2
Molar Mass
472.09 g/mol
IUPAC Name
chloromercury

Chemical Identifiers

InChI
InChI=1S/2ClH.2Hg/h2*1H;;/q;;2*+1/p-2
InChI Key
ZOMNIUBKTOKEHS-UHFFFAOYSA-L

Overview

Chloromercury (CAS 10112-91-1) is an inorganic mercury compound with significant toxicological properties and environmental impact concerns. This organomercury compound, with the molecular formula Cl2Hg2 and molecular weight of 472.09 g/mol, represents a class of mercury-containing chemicals that require careful handling and specialized knowledge for safe industrial use. Also known by its EC number 233-307-5, chloromercury exhibits properties that make it valuable in specific technical applications while demanding strict safety protocols due to its hazardous nature. The compound is classified under multiple danger categories including Acute Toxicity Category 4, Specific Target Organ Toxicity Single Exposure Category 3, and both acute and chronic aquatic toxicity Category 1. These classifications reflect its potential impact on human health and environmental systems. The assigned GHS pictograms GHS07 and GHS09 indicate both health hazards and environmental dangers, while the ADR classification 6.1 designates it as a toxic substance for transportation purposes. From a safety perspective, chloromercury can cause skin and eye irritation, and its aquatic toxicity profile necessitates careful environmental management. Unlike simpler halogenated compounds such as 1,2-dichlorobenzene, chloromercury's mercury content requires specialized disposal and handling procedures. The compound finds applications in analytical chemistry, specialized catalytic processes, and certain industrial synthesis reactions where mercury-based chemistry is required. Industrial users typically employ chloromercury in laboratory settings for specific analytical procedures and in controlled manufacturing processes where its unique chemical properties are essential. As a technical chemical distributor, OYSI provides chloromercury to qualified industrial customers across Europe, ensuring proper documentation and compliance with all relevant chemical safety regulations.

Safety & Classification

Warning
Classification:

Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Irritant

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2025
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameQuecksilber(I)-chlorid
Marine PollutantNo

Frequently Asked Questions

What is chloromercury?

Chloromercury is an inorganic mercury compound with the chemical formula Cl2Hg2 and CAS number 10112-91-1. This substance has a molecular weight of 472.09 g/mol and belongs to the family of mercury halides. It is classified as a hazardous chemical with multiple danger classes including acute toxicity, specific target organ toxicity, skin and eye irritation, and environmental hazards. The compound requires careful handling due to its toxic properties and environmental impact.

What are the physicochemical properties of chloromercury?

Chloromercury is a solid inorganic compound at room temperature with the molecular formula Cl2Hg2. The substance has a molar mass of 472.09 g/mol and contains mercury in its chemical structure. As a mercury-containing compound, it typically appears as a crystalline solid. Its physical properties require careful consideration during handling due to the presence of mercury, which contributes to its hazardous classification and environmental concerns.

What is chloromercury used for?

Chloromercury serves as a specialized chemical reagent primarily in research and analytical applications. The compound is typically used in laboratory settings for specific chemical synthesis processes and analytical procedures where mercury-containing compounds are required. Due to its hazardous nature and environmental impact, its use is generally restricted to professional and industrial applications with appropriate safety measures and regulatory compliance in place.

How to handle chloromercury safely?

Chloromercury requires strict safety precautions including appropriate personal protective equipment such as chemical-resistant gloves, safety goggles, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Given its Acute Tox. 4 classification and skin/eye irritant properties, direct contact must be avoided. Personnel should be trained in mercury compound handling procedures and emergency response protocols before working with this substance.

How to store chloromercury correctly?

Chloromercury must be stored in a secure, well-ventilated area away from incompatible materials and heat sources. The substance should be kept in its original, tightly sealed containers to prevent contamination and exposure. Storage areas should be restricted to authorized personnel only, with appropriate labeling displaying GHS07 and GHS09 pictogrammes and warning signals. Temperature and humidity control may be necessary to maintain product stability and prevent degradation.

What to do in case of contact with chloromercury?

Chloromercury exposure requires immediate first aid measures depending on the contact route. For skin contact, remove contaminated clothing and rinse affected areas thoroughly with water for at least 15 minutes. In case of eye contact, flush immediately with clean water and seek medical attention. If inhaled, move the person to fresh air immediately. Due to its toxic properties, medical evaluation should be sought promptly after any exposure incident, regardless of severity.

How to dispose of chloromercury properly?

Chloromercury disposal requires specialized hazardous waste management procedures due to its mercury content and environmental toxicity classification (Aquatic Acute 1, Aquatic Chronic 1). The substance must be collected and disposed of through licensed hazardous waste contractors following local and European regulations. It cannot be disposed of in regular waste streams or sewage systems. Proper documentation and waste tracking procedures must be maintained throughout the disposal process.

How to transport chloromercury?

Chloromercury is classified under ADR Class 6.1 (Toxic substances), Packing Group III for transportation purposes. The substance requires appropriate packaging, labeling, and documentation according to dangerous goods regulations. Transport vehicles must comply with ADR requirements for toxic substances, and drivers need proper training and certification. Shipping documentation must include proper shipping names, hazard classes, and emergency response information for safe transport across European borders.

Is chloromercury subject to specific regulations?

Chloromercury is subject to extensive European chemical regulations including REACH registration requirements and CLP classification and labeling obligations. The substance is not currently listed as an SVHC (Substance of Very High Concern), but its mercury content may subject it to additional restrictions under various environmental and occupational health regulations. Companies handling this substance must ensure compliance with national mercury regulations and maintain appropriate safety data sheets and exposure assessments.

Where to buy chloromercury in Europe?

Chloromercury is available through specialized chemical distributors such as OYSI, a European distributor of technical chemicals. Due to its hazardous classification and regulatory requirements, procurement typically requires proper documentation, safety qualifications, and compliance verification. Professional customers should contact OYSI directly for availability, technical specifications, and regulatory support. Purchase may be restricted to qualified industrial and research users with appropriate handling capabilities and permits.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.