1,1,2,2-tetrafluoroethene

C2F4

CAS116-14-3
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
116-14-3
EC Number
204-126-9
UN Number
1081
Index Number
602-110-00-X
PubChem CID
8301

Physical-chemical properties

Molecular Formula
C2F4
Molar Mass
100.01 g/mol
IUPAC Name
1,1,2,2-tetrafluoroethene

Chemical Identifiers

InChI
InChI=1S/C2F4/c3-1(4)2(5)6
InChI Key
BFKJFAAPBSQJPD-UHFFFAOYSA-N

Overview

1,1,2,2-Tetrafluoroethene (CAS 116-14-3) is a fluorinated alkene gas with exceptional chemical stability and industrial polymerization properties. This colorless, odorless gas represents a critical building block in fluorochemical manufacturing, serving as a monomer for producing high-performance fluoropolymers. With its molecular formula C2F4 and molecular weight of 100.01 g/mol, tetrafluoroethylene exhibits remarkable thermal and chemical resistance due to the strong carbon-fluorine bonds in its structure. The compound's symmetrical tetrafluorinated ethene configuration makes it highly reactive for polymerization processes while maintaining extraordinary stability in its polymer form. Safety considerations are paramount when handling this material, as it carries a Carc. 1B classification under GHS regulations with the danger signal word and GHS08 pictogram indicating potential carcinogenic properties. The substance falls under ADR Class 2 for transportation, requiring specialized handling protocols and proper ventilation systems. Unlike simpler compounds such as nitrous oxide, tetrafluoroethylene demands rigorous safety measures due to its carcinogenic potential. Primary industrial applications include the production of polytetrafluoroethylene (PTFE), commonly known as Teflon, for non-stick coatings and chemical-resistant equipment. The compound also serves in manufacturing fluoroelastomers for aerospace and automotive sealing applications, as well as specialty films for electronic and medical device industries. These applications leverage the unique properties imparted by the tetrafluoroethylene monomer, including chemical inertness, low friction coefficients, and exceptional temperature resistance. OYSI provides 1,1,2,2-tetrafluoroethene to qualified industrial customers throughout Europe, ensuring compliance with all relevant safety and transportation regulations for this specialized fluorochemical.

Safety & Classification

Danger
Classification:

Carc. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1081
ADR Class2
Packing Group
Tunnel CodeB/D
Proper Shipping NameTetrafluorethylen, stabilisiert, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is 1,1,2,2-tetrafluoroethene?

1,1,2,2-tetrafluoroethene is a fluorinated organic compound with the molecular formula C2F4 and CAS number 116-14-3. This colorless gas belongs to the perfluorinated alkene family and has a molecular weight of 100.01 g/mol. It is classified as a Category 1B carcinogen under GHS classification, requiring careful handling and strict safety protocols in industrial applications.

What are the physicochemical properties of 1,1,2,2-tetrafluoroethene?

1,1,2,2-tetrafluoroethene is a colorless gas at room temperature with high chemical stability due to its fluorine atoms. It exhibits low reactivity under normal conditions, has poor water solubility, and demonstrates excellent thermal resistance. The compound's perfluorinated structure gives it unique properties including low surface tension and inertness to most chemical reagents, making it valuable for specialized applications.

What is 1,1,2,2-tetrafluoroethene used for?

1,1,2,2-tetrafluoroethene serves primarily as a monomer in the production of specialized fluoropolymers and copolymers. It is used in manufacturing high-performance materials for aerospace, electronics, and chemical processing industries. The compound also finds applications in producing fluorinated coatings, specialty plastics, and as an intermediate in the synthesis of other fluorochemicals requiring exceptional chemical resistance and thermal stability.

How to handle 1,1,2,2-tetrafluoroethene safely?

1,1,2,2-tetrafluoroethene must be handled with extreme caution due to its Category 1B carcinogenic classification. Personnel must wear appropriate respiratory protection, chemical-resistant gloves, and protective clothing. Work should be conducted in well-ventilated areas or under fume hoods. Regular health monitoring is essential, and exposure must be minimized through engineering controls and strict adherence to occupational exposure limits and safety protocols.

How to store 1,1,2,2-tetrafluoroethene correctly?

1,1,2,2-tetrafluoroethene should be stored in appropriate pressure vessels designed for compressed gases in cool, dry, well-ventilated areas away from heat sources and ignition. Storage areas must be clearly marked with appropriate hazard warnings and restricted to authorized personnel only. Regular inspection of containers and safety systems is required, and emergency response equipment should be readily available in storage areas.

What to do in case of contact with 1,1,2,2-tetrafluoroethene?

Immediate evacuation from the exposure area is critical if 1,1,2,2-tetrafluoroethene contact occurs. For inhalation exposure, move the person to fresh air immediately and seek medical attention. In case of skin contact, remove contaminated clothing and wash thoroughly with water. Eye contact requires immediate irrigation with clean water for at least 15 minutes followed by medical evaluation. Always seek professional medical advice promptly.

How to dispose of 1,1,2,2-tetrafluoroethene appropriately?

1,1,2,2-tetrafluoroethene disposal must comply with local and international hazardous waste regulations due to its carcinogenic properties. The substance should never be released into the environment and requires specialized treatment by licensed waste management facilities. Proper documentation, labeling, and chain of custody procedures are mandatory. Consult local environmental authorities for specific disposal requirements and approved treatment methods.

How to transport 1,1,2,2-tetrafluoroethene?

1,1,2,2-tetrafluoroethene is classified under ADR Class 2 (gases) for transportation purposes. It must be shipped in approved pressure vessels with proper labeling, documentation, and placarding according to dangerous goods regulations. Transportation requires specialized carriers licensed for hazardous materials, appropriate emergency response information, and compliance with routing restrictions. Proper packaging and marking are essential for safe transport.

Is 1,1,2,2-tetrafluoroethene subject to specific regulations?

1,1,2,2-tetrafluoroethene is subject to comprehensive regulations under REACH and CLP in Europe due to its carcinogenic classification. It requires registration, safety data sheets, and strict labeling with GHS08 pictogram and 'Danger' signal word. Occupational exposure limits, workplace monitoring, and health surveillance may be mandatory. Users must comply with chemical safety assessments and risk management measures as specified in regulatory frameworks.

Where to buy 1,1,2,2-tetrafluoroethene in Europe?

1,1,2,2-tetrafluoroethene is available through OYSI, a specialized European distributor of technical chemicals with expertise in hazardous materials handling. OYSI provides comprehensive regulatory support, proper documentation, and ensures compliance with European chemical regulations. As a professional supplier, OYSI can assist with technical specifications, safety requirements, and proper handling procedures for industrial applications requiring this specialized fluorochemical.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.