Buta-1,3-diene
C4H6
buta-1,3-diene
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Identification
- CAS Number
- 106-99-0
- EC Number
- 203-450-8
- UN Number
- 1010
- Index Number
- 601-013-00-X
- PubChem CID
- 7845
Physical-chemical properties
- Molecular Formula
- C4H6
- Molar Mass
- 54.09 g/mol
- IUPAC Name
- buta-1,3-diene
Chemical Identifiers
- InChI
- InChI=1S/C4H6/c1-3-4-2/h3-4H,1-2H2
- InChI Key
- KAKZBPTYRLMSJV-UHFFFAOYSA-N
Overview
Buta-1,3-diene (CAS 106-99-0) is a conjugated diene hydrocarbon with high reactivity and significant industrial importance as a polymer building block. This colorless gas represents one of the most commercially significant dienes in the chemical industry, serving as a fundamental building block for synthetic rubber production and various polymer applications. With its molecular formula C4H6 and conjugated double bond system, buta-1,3-diene exhibits exceptional reactivity that makes it invaluable for polymerization processes. The compound's conjugated structure provides unique chemical properties that distinguish it from other simple hydrocarbons, enabling specialized applications in materials science and industrial chemistry. Safety considerations are paramount when handling buta-1,3-diene, as it carries multiple hazard classifications including flammable gas, carcinogenic, and mutagenic properties. The substance requires specialized storage and handling protocols due to its gaseous nature under standard conditions and significant health hazards. Proper ventilation, gas detection systems, and personal protective equipment are essential for safe industrial use. The primary industrial applications of buta-1,3-diene center on synthetic rubber manufacturing, particularly styrene-butadiene rubber (SBR) and polybutadiene rubber production. These materials find extensive use in tire manufacturing, automotive components, and various elastomeric applications. Additionally, the compound serves as a precursor for specialty chemicals and serves in copolymerization processes alongside other monomers. Unlike simpler compounds such as chloromethane, buta-1,3-diene's conjugated system enables complex polymerization reactions that create high-performance materials. OYSI provides technical-grade buta-1,3-diene to European industrial customers, supporting applications across the polymer and specialty chemicals sectors with comprehensive technical documentation and regulatory compliance support.
Safety & Classification
Flam. Gas 1; Press. Gas; Carc. 1A; Muta. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 1010 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | B/D |
| Proper Shipping Name | Buta-1,3-dien, stabilisiert, unter Druck verflüssigt |
| Marine Pollutant | No |
Frequently Asked Questions
What is buta-1,3-diene?
Buta-1,3-diene is a highly flammable organic compound with the molecular formula C4H6 and CAS number 106-99-0. This conjugated diene consists of four carbon atoms connected by alternating single and double bonds, making it a key building block in polymer chemistry. With a molecular weight of 54.09 g/mol, it exists as a colorless gas under normal conditions and is classified as extremely hazardous due to its carcinogenic and mutagenic properties.
What are the physicochemical properties of buta-1,3-diene?
Buta-1,3-diene is a colorless gas at room temperature with a characteristic mild aromatic odor. It has a boiling point of -4.4°C and a melting point of -108.9°C, making it gaseous under normal atmospheric conditions. The compound is slightly soluble in water but readily dissolves in organic solvents like alcohol and ether. It polymerizes easily and can form explosive peroxides when exposed to air and light.
What is buta-1,3-diene used for?
Buta-1,3-diene is primarily used as a monomer in the production of synthetic rubber, particularly styrene-butadiene rubber (SBR) and polybutadiene rubber. It serves as a crucial raw material in manufacturing tires, footwear, and various rubber products. Additionally, it's employed in producing acrylonitrile-butadiene-styrene (ABS) plastics, latex paints, and as an intermediate in synthesizing other chemical compounds in the petrochemical industry.
How to handle buta-1,3-diene safely?
Buta-1,3-diene requires extreme caution due to its carcinogenic properties and high flammability. Personnel must wear appropriate respiratory protection, chemical-resistant gloves, and protective clothing. Work areas must have adequate ventilation and explosion-proof equipment. Eliminate all ignition sources including static electricity, sparks, and hot surfaces. Use only in well-ventilated areas or fume hoods, and ensure emergency shower and eyewash stations are readily accessible.
How to store buta-1,3-diene correctly?
Buta-1,3-diene must be stored in pressurized containers in cool, well-ventilated areas away from heat sources, sparks, and open flames. Storage areas should be equipped with explosion-proof electrical equipment and adequate fire suppression systems. Keep containers tightly sealed and protected from light to prevent polymerization. Store away from oxidizing agents and ensure proper grounding of equipment to prevent static electricity buildup.
What to do in case of contact with buta-1,3-diene?
Immediate evacuation from the exposure area to fresh air is essential in case of inhalation. Remove contaminated clothing and wash affected skin thoroughly with soap and water for at least 15 minutes. For eye contact, flush immediately with clean water for 15 minutes. Seek immediate medical attention in all cases of exposure, emphasizing the carcinogenic nature of the substance to medical personnel. Do not induce vomiting if ingested.
How to dispose of buta-1,3-diene appropriately?
Buta-1,3-diene disposal must comply with local and national hazardous waste regulations as it's classified as carcinogenic waste. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never discharge into drains, waterways, or the environment. Small quantities may be allowed to evaporate in well-ventilated areas away from ignition sources, but only under controlled conditions and with proper authorization from environmental authorities.
How to transport buta-1,3-diene?
Buta-1,3-diene is classified under ADR Class 2 (gases) for transportation purposes. It must be transported in appropriate pressure vessels designed for flammable gases, with proper labeling including GHS02, GHS04, and GHS08 pictograms. Vehicles must be equipped with appropriate fire extinguishers and emergency equipment. Transportation requires compliance with dangerous goods regulations, proper documentation, and trained personnel certified for hazardous materials transport.
Is buta-1,3-diene subject to specific regulations?
Buta-1,3-diene is subject to strict regulations under REACH and CLP due to its classification as Carcinogenic 1A and Mutagenic 1B. It requires special handling procedures under occupational health and safety regulations, with mandatory exposure monitoring and health surveillance for workers. The substance is also regulated under various national chemical safety laws and may be subject to import/export licensing requirements in certain jurisdictions.
Where to buy buta-1,3-diene in Europe?
OYSI serves as a reliable European distributor for buta-1,3-diene, providing high-quality chemical products to industrial customers across Europe. As a specialized chemical distributor, OYSI ensures proper handling, documentation, and compliance with all relevant safety and regulatory requirements. Contact OYSI directly for availability, technical specifications, and regulatory documentation. Due to the hazardous nature of this substance, purchases are restricted to qualified industrial users only.
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Buta-1,3-diene is a dangerous good. We support you with labeling, packaging, and transport documentation.
Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.