Methylhydrazine
CH6N2
methylhydrazine
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Identification
- CAS Number
- 60-34-4
- EC Number
- 200-471-4
- UN Number
- 1244
- Index Number
- 612-292-00-2
- PubChem CID
- 6061
Physical-chemical properties
- Molecular Formula
- CH6N2
- Molar Mass
- 46.07 g/mol
- IUPAC Name
- methylhydrazine
Chemical Identifiers
- InChI
- InChI=1S/CH6N2/c1-3-2/h3H,2H2,1H3
- InChI Key
- HDZGCSFEDULWCS-UHFFFAOYSA-N
Overview
Methylhydrazine (CAS 60-34-4) is a highly toxic hydrazine derivative with carcinogenic properties and strong reducing capabilities. Methylhydrazine represents a critical chemical compound in specialized industrial applications, particularly valued for its exceptional performance as a rocket fuel component and chemical intermediate. This colorless to slightly yellow liquid exhibits highly reactive properties due to its hydrazine functional group, making it both valuable and hazardous in industrial processes. The compound's molecular structure (CH6N2) incorporates a methylated hydrazine backbone, distinguishing it from other nitrogen-containing compounds such as chloromethylbenzene, which serves different industrial purposes despite sharing certain reactive characteristics. The substance carries significant safety considerations, classified under GHS08 pictogram with a "Danger" signal word and Carc. 1B classification, indicating confirmed carcinogenic potential. Its ADR transport classification of 6.1 reflects its toxic nature, requiring specialized handling protocols and containment systems throughout storage and distribution processes. The compound's high reactivity necessitates careful temperature control and inert atmosphere conditions to prevent unwanted decomposition or combustion reactions. Primary industrial applications include aerospace propulsion systems, where methylhydrazine functions as a hypergolic fuel component, pharmaceutical intermediate synthesis, and specialized chemical manufacturing processes requiring strong reducing agents. The compound's unique combination of high energy density and controllable reactivity makes it particularly valuable in applications demanding precise chemical performance specifications. OYSI maintains availability of methylhydrazine through our specialized hazardous materials distribution network, ensuring compliance with European chemical regulations and providing comprehensive safety documentation for qualified industrial customers requiring this critical chemical intermediate.
Safety & Classification
Carc. 1B
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
May cause cancer.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Transport (ADR)
| UN Number | 1244 |
| ADR Class | 6.1 |
| Packing Group | I |
| Tunnel Code | C/D |
| Proper Shipping Name | Methylhydrazin |
| Marine Pollutant | No |
Frequently Asked Questions
What is methylhydrazine?
Methylhydrazine is a highly toxic organic compound with the chemical formula CH6N2 and CAS number 60-34-4. This colorless liquid belongs to the hydrazine family and has a molecular weight of 46.072 g/mol. It is classified as a Category 1B carcinogen under GHS regulations, indicating strong evidence of carcinogenic potential in humans. The substance requires extreme caution in handling due to its severe health hazards and is primarily used in specialized industrial applications where its unique chemical properties are essential.
What are the physicochemical properties of methylhydrazine?
Methylhydrazine is a colorless to slightly yellow liquid at room temperature with a strong, ammonia-like odor. The compound is highly polar and completely miscible with water, alcohols, and many organic solvents. It has a boiling point of approximately 87°C and a melting point around -52°C. The substance is hygroscopic, readily absorbing moisture from air, and is highly reactive with oxidizing agents. Its high polarity and hydrogen bonding capability make it an effective solvent for various chemical processes.
What is methylhydrazine used for?
Methylhydrazine is primarily used as a rocket fuel component and propellant in aerospace applications due to its high energy density and hypergolic properties. It serves as a key intermediate in pharmaceutical synthesis, particularly in the production of certain medications and active pharmaceutical ingredients. The compound is also utilized in chemical research as a reducing agent and in the synthesis of specialized organic compounds. Additionally, it finds limited use in certain industrial processes requiring strong reducing conditions or specific chemical transformations.
How to handle methylhydrazine safely?
Methylhydrazine requires extreme safety precautions due to its carcinogenic and toxic nature. Personnel must wear full chemical-resistant suits, supplied-air respiratory protection, and chemical-resistant gloves when handling this substance. Work should only be conducted in well-ventilated areas or under fume hoods with adequate exhaust systems. Avoid any skin or eye contact, and ensure emergency shower and eyewash stations are immediately accessible. All handling operations should be performed by trained personnel following strict safety protocols and local regulations.
How to store methylhydrazine correctly?
Methylhydrazine must be stored in tightly sealed, corrosion-resistant containers made of stainless steel or compatible materials in cool, dry, well-ventilated areas away from heat sources and direct sunlight. The storage area should be separated from oxidizing agents, acids, and combustible materials due to potential violent reactions. Temperature should be maintained below 25°C, and the storage facility must have appropriate fire suppression systems. Access should be restricted to authorized personnel only, with proper hazard communication and emergency response procedures in place.
What to do in case of contact with methylhydrazine?
Immediate medical attention is required for any exposure to methylhydrazine due to its extreme toxicity. For skin contact, remove contaminated clothing and flush the affected area with large amounts of water for at least 15 minutes. In case of eye contact, irrigate immediately with clean water for at least 15 minutes and seek urgent medical care. If inhaled, move the person to fresh air and provide artificial respiration if breathing has stopped. Never induce vomiting if ingested, and contact emergency medical services immediately while providing supportive care.
How to dispose of methylhydrazine appropriately?
Methylhydrazine disposal must be conducted through licensed hazardous waste disposal companies in accordance with local and international environmental regulations. The substance cannot be disposed of through normal waste streams due to its carcinogenic classification and environmental toxicity. Small quantities may be neutralized through controlled chemical treatment by qualified professionals, but this requires specialized equipment and expertise. All disposal activities must be documented and comply with REACH regulations and national hazardous waste management laws. Contact environmental authorities for specific disposal requirements in your region.
How to transport methylhydrazine?
Methylhydrazine is classified under ADR as Class 6.1 (Toxic substances) with Packing Group I, indicating maximum danger level for transport. It requires specialized packaging in UN-approved containers with proper hazard labels and documentation. Transport must be conducted by certified carriers with appropriate emergency response capabilities and equipment. Vehicles must carry emergency response information and spill containment materials. The shipment requires proper declaration, safety data sheets, and compliance with international dangerous goods regulations including IMDG for sea transport and IATA for air transport.
Is methylhydrazine subject to particular regulations?
Methylhydrazine is subject to extensive regulatory control due to its carcinogenic classification (Carc. 1B) under CLP regulations and its toxic properties. It falls under REACH registration requirements for manufacturing and import in the European Union, requiring comprehensive safety assessments and exposure scenarios. The substance is regulated under occupational health and safety legislation with strict workplace exposure limits. Additional restrictions may apply for certain uses, and handling requires compliance with national chemical safety regulations, environmental protection laws, and specialized licensing requirements in many jurisdictions.
Where to buy methylhydrazine in Europe?
Methylhydrazine is available through OYSI, a specialized European distributor of technical chemicals with expertise in handling hazardous substances. Due to its highly regulated nature and extreme toxicity, purchase requires proper licensing, demonstrated legitimate use, and compliance with all applicable safety and environmental regulations. OYSI provides comprehensive technical support, safety documentation, and regulatory guidance to ensure compliant procurement and handling. Customers must meet strict qualification criteria and provide detailed information about intended use and safety management systems before purchase approval.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.