Methylhydrazine

CH6N2

methylhydrazine

CAS60-34-4
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
60-34-4
EC Number
200-471-4
UN Number
1244
Index Number
612-292-00-2
PubChem CID
6061

Physical-chemical properties

Molecular Formula
CH6N2
Molar Mass
46.07 g/mol
IUPAC Name
methylhydrazine

Chemical Identifiers

InChI
InChI=1S/CH6N2/c1-3-2/h3H,2H2,1H3
InChI Key
HDZGCSFEDULWCS-UHFFFAOYSA-N

Overview

Methylhydrazine (CAS 60-34-4) is a highly reactive hydrazine derivative with potent rocket fuel properties and significant carcinogenic hazards. This colorless, hygroscopic liquid represents one of the most important hydrazine compounds in aerospace and chemical industries. With its molecular formula CH6N2 and molecular weight of 46.072 g/mol, methylhydrazine exhibits exceptional fuel characteristics that have made it indispensable for space propulsion systems. The compound's high energy density and hypergolic properties with oxidizers like nitrogen tetroxide enable reliable ignition without external ignition sources, making it particularly valuable for spacecraft maneuvering systems and satellite propulsion. From a safety perspective, methylhydrazine presents serious health hazards, classified as a Category 1B carcinogen under GHS regulations with the danger signal word and GHS08 pictogram. Its ADR Class 6.1 classification reflects its toxic nature, requiring stringent handling protocols and specialized storage conditions. The compound's volatility and potential for skin absorption necessitate comprehensive personal protective equipment and engineering controls during industrial operations. Primary industrial applications include rocket and spacecraft propulsion, where methylhydrazine serves as a monopropellant or bipropellant fuel component. The pharmaceutical industry utilizes it as an intermediate in drug synthesis, while the polymer sector employs it in specialized chemical processes. Unlike simpler compounds such as chloromethylbenzene used in standard organic synthesis, methylhydrazine's unique reactivity profile makes it irreplaceable in high-energy applications. OYSI provides methylhydrazine to qualified industrial customers with comprehensive technical documentation and safety guidance to ensure compliant handling and application.

Safety & Classification

Danger
Classification:

Carc. 1B

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H350

May cause cancer.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Transport (ADR)

UN Number1244
ADR Class6.1
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameMethylhydrazin
Marine PollutantNo

Frequently Asked Questions

What is methylhydrazine?

Methylhydrazine is an organic chemical compound with the molecular formula CH6N2 and CAS number 60-34-4. This hazardous substance has a molecular weight of 46.072 g/mol and is classified as a Category 1B carcinogen under the GHS system. It belongs to the hydrazine family of compounds and is considered extremely dangerous, requiring the 'Danger' signal word and GHS08 pictogram for health hazards on safety labels.

What are the physicochemical properties of methylhydrazine?

Methylhydrazine is a colorless to pale yellow liquid at room temperature with a characteristic ammonia-like or fishy odor. It is highly soluble in water and most organic solvents due to its polar nature. The compound is hygroscopic, meaning it readily absorbs moisture from air. It has a relatively low molecular weight of 46.072 g/mol and exhibits basic properties in aqueous solutions, similar to other hydrazine derivatives.

What is methylhydrazine used for?

Methylhydrazine is primarily used as a rocket fuel component and propellant in aerospace applications due to its high energy content and hypergolic properties. It serves as a fuel in satellite thrusters and spacecraft propulsion systems. In the chemical industry, it acts as an intermediate in pharmaceutical synthesis and as a precursor for various nitrogen-containing compounds. However, its use is heavily restricted due to its carcinogenic properties and extreme toxicity.

How to handle methylhydrazine safely?

Methylhydrazine requires extreme safety precautions during handling due to its carcinogenic and toxic nature. Personnel must wear full chemical-resistant suits, supplied-air respiratory protection, and chemical-resistant gloves. Work should only be conducted in well-ventilated areas or under fume hoods with adequate exhaust systems. Avoid any skin contact, inhalation, or ingestion. Emergency shower and eyewash stations must be readily accessible, and only trained professionals should handle this substance.

How to store methylhydrazine correctly?

Methylhydrazine must be stored in tightly sealed containers made of compatible materials such as stainless steel or specialized chemical-resistant plastics. Store in cool, dry, well-ventilated areas away from heat sources, ignition sources, and incompatible materials including oxidizers and acids. The storage area should be secured with restricted access, proper labeling, and emergency response equipment. Temperature control and regular container inspection are essential to prevent degradation and potential hazards.

What to do in case of contact with methylhydrazine?

Immediate action is critical in case of methylhydrazine exposure. For skin contact, remove contaminated clothing and flush the affected area with copious amounts of water for at least 15 minutes. If inhaled, move the person to fresh air immediately and provide oxygen if breathing is difficult. For eye contact, flush with water for 15 minutes while holding eyelids open. Seek immediate medical attention in all cases and inform medical personnel about the carcinogenic nature of the substance.

How to dispose of methylhydrazine appropriately?

Methylhydrazine disposal must comply with strict hazardous waste regulations due to its carcinogenic classification. The substance cannot be disposed of through normal waste streams and requires specialized hazardous waste treatment facilities. Contact licensed hazardous waste disposal companies for proper collection and destruction. Incineration at high temperatures in approved facilities is typically the preferred method. Never attempt to neutralize or dispose of this substance without professional guidance and regulatory compliance.

How to transport methylhydrazine?

Methylhydrazine is classified as ADR Class 6.1 (toxic substances) Packing Group I, indicating the highest level of danger for toxic materials. Transportation requires UN-specification packaging and proper dangerous goods documentation. Vehicles must display appropriate hazard placards and carry emergency response information. Only certified drivers with dangerous goods training can transport this substance. Special routing restrictions may apply, and emergency response procedures must be established before transport begins.

Is methylhydrazine subject to specific regulations?

Methylhydrazine is subject to extensive regulatory oversight due to its carcinogenic properties. Under EU REACH regulation, it requires registration and authorization for commercial use. The CLP regulation mandates specific hazard classification as Carc. 1B with corresponding labeling requirements. National and international restrictions limit its availability to authorized users only. Export/import permits may be required, and workplace exposure limits are strictly regulated under occupational health and safety legislation.

Where to buy methylhydrazine in Europe?

Methylhydrazine is available through specialized chemical distributors like OYSI, which serves the European market for technical chemicals. Due to its hazardous nature and regulatory restrictions, purchase requires proper authorization, end-use documentation, and compliance with safety regulations. OYSI can provide guidance on regulatory requirements and proper handling procedures. Contact OYSI's technical team for availability, specifications, and regulatory compliance support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.