1,1,2,2-tetrachloroethane

C2H2Cl4

CAS79-34-5
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
79-34-5
EC Number
201-197-8
UN Number
1702
Index Number
602-015-00-3
PubChem CID
6591

Physical-chemical properties

Molecular Formula
C2H2Cl4
Molar Mass
167.80 g/mol
IUPAC Name
1,1,2,2-tetrachloroethane

Chemical Identifiers

InChI
InChI=1S/C2H2Cl4/c3-1(4)2(5)6/h1-2H
InChI Key
QPFMBZIOSGYJDE-UHFFFAOYSA-N

Overview

1,1,2,2-Tetrachloroethane (CAS 79-34-5) is a chlorinated hydrocarbon solvent with high density and excellent degreasing properties. This symmetrical tetrachlorinated ethane derivative represents an important member of the chlorinated aliphatic hydrocarbon family, sharing structural similarities with other halogenated solvents used in industrial applications. With its molecular formula C2H2Cl4 and molecular weight of 167.8 g/mol, 1,1,2,2-tetrachloroethane exhibits distinctive physicochemical properties that make it valuable for specialized industrial processes requiring powerful solvent capabilities. The compound demonstrates exceptional solvent power for oils, greases, and various organic materials, while maintaining chemical stability under controlled conditions. Its high boiling point and density distinguish it from lighter chlorinated solvents, enabling specific applications where these properties are advantageous. However, the substance requires careful handling protocols due to its classification under GHS06 and GHS09 pictograms, indicating both acute toxicity (Acute Tox. 1 and 2) and environmental hazards (Aquatic Chronic 2). Primary industrial applications include use as a specialized degreasing agent in metal processing operations, as an intermediate in chemical synthesis pathways, and as a component in certain formulations requiring high-performance chlorinated solvents. Unlike compounds such as N-methylaniline which serves different industrial functions, 1,1,2,2-tetrachloroethane's unique chlorinated structure provides specific advantages in applications demanding robust degreasing capabilities. The compound falls under ADR transport class 6.1, requiring appropriate shipping and storage protocols to ensure safe handling throughout the supply chain. OYSI maintains availability of 1,1,2,2-tetrachloroethane for qualified industrial customers requiring this specialized chlorinated solvent for their technical applications.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 1; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H310

Fatal in contact with skin.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Fatal

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1702
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name1,1,2,2-Tetrachlorethan
Marine PollutantNo

Frequently Asked Questions

What is 1,1,2,2-tetrachloroethane?

1,1,2,2-tetrachloroethane is a chlorinated hydrocarbon solvent with the molecular formula C2H2Cl4 and CAS number 79-34-5. This organic compound has a molecular weight of 167.8 g/mol and belongs to the family of chloroethanes. It appears as a colorless liquid with a characteristic sweet odor and is classified as highly toxic with acute toxicity categories 1 and 2. The substance also poses environmental risks, particularly to aquatic ecosystems with chronic toxicity effects.

What are the physicochemical properties of 1,1,2,2-tetrachloroethane?

1,1,2,2-tetrachloroethane is a dense, colorless liquid at room temperature with a sweet, chloroform-like odor. It has low solubility in water but is miscible with most organic solvents including alcohols, ethers, and other chlorinated compounds. The substance has a high vapor pressure and can readily evaporate at ambient conditions. Its density is significantly higher than water, and it exhibits good chemical stability under normal storage conditions while being non-flammable.

What is 1,1,2,2-tetrachloroethane used for?

1,1,2,2-tetrachloroethane is primarily used as an industrial solvent and chemical intermediate in manufacturing processes. It serves as a feedstock for producing other chlorinated compounds and is utilized in specialized cleaning applications where strong solvency power is required. The substance finds application in metal degreasing operations, though its use has been significantly restricted due to health and environmental concerns. It may also be used in laboratory settings for specific analytical procedures under controlled conditions.

How to handle 1,1,2,2-tetrachloroethane safely?

Safe handling of 1,1,2,2-tetrachloroethane requires strict adherence to safety protocols due to its high toxicity classification. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas or under fume extraction systems. Direct skin and eye contact must be avoided at all costs. Work should be conducted in controlled environments with proper ventilation systems to prevent vapor accumulation and potential inhalation exposure.

How to store 1,1,2,2-tetrachloroethane correctly?

1,1,2,2-tetrachloroethane must be stored in tightly sealed, chemically compatible containers in cool, dry, well-ventilated areas away from heat sources and direct sunlight. Storage areas should be equipped with appropriate containment measures and emergency response equipment. The substance should be kept separate from incompatible materials including strong bases, metals, and oxidizing agents. Regular inspection of containers for leaks or deterioration is essential, and storage areas must comply with local regulations for toxic substances.

What to do in case of contact with 1,1,2,2-tetrachloroethane?

Immediate emergency response is critical for any contact with 1,1,2,2-tetrachloroethane due to its acute toxicity. For skin contact, remove contaminated clothing and rinse affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, flush immediately with clean water and seek medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. For ingestion, do not induce vomiting and seek immediate medical care while providing safety data sheet information to medical personnel.

How to dispose of 1,1,2,2-tetrachloroethane appropriately?

Proper disposal of 1,1,2,2-tetrachloroethane requires compliance with hazardous waste regulations and must be handled by licensed waste management companies. The substance cannot be disposed of through regular waste streams due to its toxicity and environmental impact. Incineration at high temperatures in specialized facilities equipped with appropriate emission controls is typically required. Empty containers must also be treated as hazardous waste. Consult local environmental authorities and waste management specialists for specific disposal requirements and authorized facilities.

How to transport 1,1,2,2-tetrachloroethane?

Transportation of 1,1,2,2-tetrachloroethane is regulated under ADR classification 6.1 (toxic substances) with packing group II designation. The substance requires proper hazardous goods packaging, labeling with appropriate danger diamonds, and documentation including transport documents and safety data sheets. Vehicles must be equipped with emergency response equipment and drivers must hold valid dangerous goods transportation certificates. Shipping containers must meet UN specification requirements and display the correct hazard identification numbers and environmental hazard markings.

Is 1,1,2,2-tetrachloroethane subject to specific regulations?

1,1,2,2-tetrachloroethane is subject to extensive regulatory oversight under multiple frameworks including REACH registration requirements, CLP classification and labeling regulations, and various national restrictions on use and handling. The substance faces increasing regulatory scrutiny due to its high toxicity and environmental impact, though it is not currently listed as a SVHC (Substance of Very High Concern). Users must comply with occupational exposure limits, environmental discharge restrictions, and proper notification requirements for industrial use.

Where to buy 1,1,2,2-tetrachloroethane in Europe?

1,1,2,2-tetrachloroethane is available through specialized chemical distributors in Europe, with OYSI serving as a reliable supplier for industrial customers requiring this regulated substance. Due to its toxic classification and regulatory restrictions, procurement requires proper documentation, end-use declarations, and compliance with safety and handling protocols. OYSI provides technical support and regulatory guidance to ensure customers meet all legal requirements for purchase, handling, and use of this controlled chemical substance in their specific applications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.