1,1,2,2-tetrachloroethane

C2H2Cl4

CAS79-34-5
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
79-34-5
EC Number
201-197-8
UN Number
1702
Index Number
602-015-00-3
PubChem CID
6591

Physical-chemical properties

Molecular Formula
C2H2Cl4
Molar Mass
167.80 g/mol
IUPAC Name
1,1,2,2-tetrachloroethane

Chemical Identifiers

InChI
InChI=1S/C2H2Cl4/c3-1(4)2(5)6/h1-2H
InChI Key
QPFMBZIOSGYJDE-UHFFFAOYSA-N

Overview

1,1,2,2-Tetrachloroethane (CAS 79-34-5) is a chlorinated hydrocarbon solvent with high toxicity and environmental persistence concerns. This organochlorine compound represents one of the more hazardous members of the chlorinated ethane family, characterized by its four chlorine atoms attached to a two-carbon backbone. As a dense, colorless liquid with a sweet ethereal odor, 1,1,2,2-tetrachloroethane exhibits excellent solvent properties for various organic compounds, making it valuable in specialized industrial applications despite its significant safety considerations. The substance's chemical structure provides exceptional stability and dissolving power, particularly for fats, oils, waxes, and certain polymers. However, these same properties contribute to its environmental persistence and bioaccumulation potential. Unlike some related compounds such as N-methylaniline, which finds broader application in chemical synthesis, 1,1,2,2-tetrachloroethane requires stringent handling protocols due to its classification as Acute Tox. 1 and Acute Tox. 2 under GHS regulations. Primary industrial applications include use as a chemical intermediate in the production of other chlorinated compounds, as a specialized solvent for cleaning and degreasing operations in controlled environments, and in certain extraction processes where its unique solvent properties are essential. The compound's high boiling point and chemical stability make it particularly suitable for high-temperature industrial processes. Safety considerations are paramount when working with this substance, requiring appropriate personal protective equipment, adequate ventilation, and strict adherence to occupational exposure limits. Environmental release must be prevented due to its aquatic chronic toxicity classification. OYSI maintains reliable supply chains for 1,1,2,2-tetrachloroethane to serve specialized industrial customers throughout Europe, ensuring proper documentation and regulatory compliance for all shipments.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 1; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H310

Fatal in contact with skin.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Fatal

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1702
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name1,1,2,2-Tetrachlorethan
Marine PollutantNo

Frequently Asked Questions

What is 1,1,2,2-tetrachloroethane?

1,1,2,2-tetrachloroethane is a chlorinated organic solvent with the chemical formula C2H2Cl4 and CAS number 79-34-5. This synthetic chemical compound belongs to the family of chloroalkanes and has a molecular weight of 167.8 g/mol. It is classified as highly toxic with acute toxicity categories 1 and 2, making it extremely dangerous to human health. The substance also poses environmental risks, particularly to aquatic ecosystems with chronic toxicity effects.

What are the physicochemical properties of 1,1,2,2-tetrachloroethane?

1,1,2,2-tetrachloroethane is a colorless liquid at room temperature with a characteristic sweet, chloroform-like odor. It has a high density due to its chlorine content and is sparingly soluble in water but miscible with most organic solvents including alcohols and ethers. The compound is volatile and can easily evaporate at ambient conditions. Its high chlorine content makes it chemically stable under normal conditions but potentially reactive under certain circumstances.

What is 1,1,2,2-tetrachloroethane used for?

1,1,2,2-tetrachloroethane is primarily used as an industrial solvent and chemical intermediate in specialized applications. It serves as a solvent for resins, waxes, and other organic materials in industrial processes. The compound is also utilized as an intermediate in the synthesis of other chlorinated compounds and in certain analytical chemistry applications. Due to its high toxicity classification, its use is heavily restricted and limited to professional industrial applications with appropriate safety measures.

How to handle 1,1,2,2-tetrachloroethane safely?

1,1,2,2-tetrachloroethane must be handled with extreme caution due to its Acute Tox. 1 and 2 classifications. Essential protective equipment includes chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas or fume hoods. Workers must wear appropriate protective clothing to prevent skin contact. All handling should occur in controlled environments with proper ventilation systems. Emergency procedures and safety data sheets must be readily available, and only trained personnel should work with this highly toxic substance.

How to store 1,1,2,2-tetrachloroethane correctly?

1,1,2,2-tetrachloroethane must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat sources and incompatible materials. Storage areas should be equipped with appropriate containment measures and maintained at stable temperatures. The substance should be kept away from strong oxidizing agents, alkali metals, and bases. Secondary containment is recommended to prevent environmental contamination. Access should be restricted to authorized personnel only, with proper labeling including GHS06 and GHS09 pictograms clearly visible.

What to do in case of contact with 1,1,2,2-tetrachloroethane?

Immediate action is crucial due to the substance's high toxicity. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. In case of eye contact, flush thoroughly with water and seek immediate medical attention. If inhaled, move the person to fresh air immediately and provide artificial respiration if breathing has stopped. For ingestion, do not induce vomiting and seek emergency medical care immediately. Always contact poison control centers and provide safety data sheet information to medical personnel.

How to dispose of 1,1,2,2-tetrachloroethane properly?

1,1,2,2-tetrachloroethane must be disposed of as hazardous waste through licensed waste management facilities due to its high toxicity and environmental classification. The substance cannot be disposed of in regular waste streams or sewerage systems. Disposal must comply with local, national, and EU waste regulations including the Waste Framework Directive. Professional waste contractors specializing in toxic chemicals should handle collection and treatment. Documentation and waste tracking certificates are required for proper regulatory compliance and environmental protection.

How to transport 1,1,2,2-tetrachloroethane?

1,1,2,2-tetrachloroethane is classified under ADR Class 6.1 (toxic substances) Packing Group II, indicating high transport risk. Transportation requires appropriate UN-specification packaging, proper labeling with toxic substance markings, and transport documents including safety data sheets. Vehicles must carry appropriate emergency equipment and drivers need ADR certification for dangerous goods. Segregation from incompatible materials is mandatory. Transport should follow the shortest reasonable routes with emergency response procedures readily available throughout the journey.

Is 1,1,2,2-tetrachloroethane subject to particular regulations?

1,1,2,2-tetrachloroethane is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification obligations. While not currently listed as a Substance of Very High Concern (SVHC), its high toxicity classification triggers strict handling and use restrictions. The substance falls under workplace safety regulations requiring specialized training and control measures. Industrial users must implement risk management measures and may face restrictions on certain applications. Regular monitoring and reporting obligations apply to commercial users and suppliers.

Where to buy 1,1,2,2-tetrachloroethane in Europe?

1,1,2,2-tetrachloroethane is available through specialized chemical distributors like OYSI, which supplies industrial chemicals across Europe. Due to its high toxicity classification and regulatory restrictions, procurement requires proper business credentials, safety certifications, and intended use declarations. Suppliers must verify customer qualifications and end-use applications before sales. Purchase typically involves minimum order quantities, specialized packaging, and compliance documentation. Contact OYSI's technical team for availability, specifications, and regulatory compliance support for your specific industrial application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.