2,4-dinitroaniline

C6H5N3O4

CAS97-02-9
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for 2,4-dinitroaniline

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
97-02-9
EC Number
202-553-5
UN Number
1596
Index Number
612-040-00-1
PubChem CID
7321

Physical-chemical properties

Molecular Formula
C6H5N3O4
Molar Mass
183.12 g/mol
IUPAC Name
2,4-dinitroaniline

Chemical Identifiers

InChI
InChI=1S/C6H5N3O4/c7-5-2-1-4(8(10)11)3-6(5)9(12)13/h1-3H,7H2
InChI Key
LXQOQPGNCGEELI-UHFFFAOYSA-N

Overview

2,4-dinitroaniline (CAS 97-02-9) is an aromatic nitro compound characterized by high toxicity and environmental persistence. This yellow crystalline organic compound belongs to the dinitroaniline family and serves as an important intermediate in chemical manufacturing processes. With its molecular formula C6H5N3O4 and molecular weight of 183.12 g/mol, 2,4-dinitroaniline features two nitro groups attached to an aniline backbone, which significantly influences its chemical reactivity and biological activity. The compound exhibits notable safety concerns, classified under multiple acute toxicity categories and requiring careful handling protocols. Its hazard profile includes acute toxicity through oral, dermal, and inhalation routes, specific target organ toxicity following repeated exposure, and chronic aquatic toxicity. The presence of GHS06, GHS08, and GHS09 pictograms emphasizes its dangerous nature to both human health and environmental systems. Transportation falls under ADR Class 6.1, reflecting its toxic properties. In industrial applications, 2,4-dinitroaniline primarily functions as a chemical intermediate in dye and pigment synthesis, where its aromatic structure provides essential chromophoric properties. The compound also finds use in pharmaceutical intermediate production and serves as a precursor in specialty chemical manufacturing. Unlike related compounds such as 3-chloro-4-nitroaniline, which contains a chlorine substituent, 2,4-dinitroaniline's dual nitro groups confer distinct reactivity patterns essential for specific synthetic pathways. Proper storage requires controlled temperature conditions and protection from light and moisture to maintain product stability and prevent decomposition. OYSI maintains reliable supply chains for 2,4-dinitroaniline to support European industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Danger
Classification:

Acute Tox. 2 *; Acute Tox. 1; Acute Tox. 2 *; STOT RE 2 *; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H330

Fatal if inhaled.

H310

Fatal in contact with skin.

H300

Fatal if swallowed.

H373

May cause damage to organs through prolonged or repeated exposure.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Fatal

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1596
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name2,4-Dinitroanilin, fest
Marine PollutantNo

Frequently Asked Questions

What is 2,4-dinitroaniline?

2,4-dinitroaniline is an organic chemical compound with the molecular formula C6H5N3O4 and CAS number 97-02-9. It belongs to the nitroaniline family, characterized by an aniline structure with two nitro groups positioned at the 2 and 4 positions on the benzene ring. With a molecular weight of 183.12 g/mol, this compound is classified as highly hazardous due to its acute toxicity and potential for causing specific target organ toxicity upon repeated exposure.

What are the physicochemical properties of 2,4-dinitroaniline?

2,4-dinitroaniline typically appears as yellow to orange crystalline solid at room temperature. The compound has limited water solubility due to its aromatic structure and nitro substituents. It exhibits stability under normal conditions but may decompose when exposed to high temperatures or strong reducing agents. The presence of electron-withdrawing nitro groups significantly affects its chemical reactivity and makes it less basic compared to unsubstituted aniline.

What is 2,4-dinitroaniline used for?

2,4-dinitroaniline is primarily used as an intermediate in the synthesis of dyes, pigments, and other organic compounds in the chemical industry. It serves as a precursor for manufacturing various azo dyes and serves in pharmaceutical synthesis pathways. The compound is also utilized in research and analytical chemistry applications. Its specific chemical structure makes it valuable for producing specialized chemical products requiring nitroaniline derivatives.

How to handle 2,4-dinitroaniline safely?

2,4-dinitroaniline requires strict safety measures due to its high acute toxicity classification. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin contact and ingestion completely. Emergency eyewash stations and safety showers should be readily accessible, and all handling procedures must follow established chemical safety protocols.

How to store 2,4-dinitroaniline correctly?

2,4-dinitroaniline must be stored in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep containers tightly sealed and store separately from strong reducing agents, bases, and oxidizing substances. The storage area should be equipped with appropriate containment measures and access should be restricted to trained personnel only. Regular inspection of containers for damage or leakage is essential to maintain safe storage conditions.

What to do in case of contact with 2,4-dinitroaniline?

Immediate action is critical due to the compound's high toxicity. For skin contact, remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. If inhaled, move person to fresh air immediately and seek medical attention. In case of eye contact, rinse thoroughly with water for several minutes. If ingested, do not induce vomiting and seek immediate medical care. Always consult a physician and provide the safety data sheet.

How to dispose of 2,4-dinitroaniline properly?

2,4-dinitroaniline disposal must comply with local and European waste regulations due to its hazardous classification. The compound cannot be disposed of in regular waste streams and requires specialized hazardous waste treatment. Contact licensed waste disposal companies experienced in handling toxic organic compounds. Incineration at high temperatures in approved facilities is typically the preferred disposal method. Always maintain proper documentation and follow waste tracking requirements throughout the disposal process.

How to transport 2,4-dinitroaniline?

2,4-dinitroaniline is classified under ADR as Class 6.1 (toxic substances), Packing Group II, indicating significant transport hazards. Packages must bear appropriate UN identification numbers and hazard labels including GHS06, GHS08, and GHS09 pictograms with 'Danger' signal word. Only authorized carriers trained in dangerous goods transport should handle shipments. Proper documentation including transport documents and emergency response information must accompany all shipments according to ADR regulations.

Is 2,4-dinitroaniline subject to specific regulations?

2,4-dinitroaniline is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification standards. The compound's high acute toxicity and environmental hazard classifications trigger specific handling, labeling, and documentation obligations. While not currently listed as an SVHC substance, its toxic properties require compliance with occupational exposure limits and environmental protection measures. Users must maintain safety data sheets and follow all applicable national chemical safety regulations.

Where to buy 2,4-dinitroaniline in Europe?

2,4-dinitroaniline is available through OYSI, a specialized European distributor of technical chemicals. As an experienced supplier of hazardous chemicals, OYSI ensures proper handling, documentation, and regulatory compliance for this highly toxic compound. Professional customers can contact OYSI directly to discuss specific requirements, quantities, and delivery options. All sales include comprehensive safety documentation and technical support to ensure safe handling and regulatory compliance throughout the supply chain.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.