1,1-dimethylhydrazine

C2H8N2

CAS57-14-7
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
57-14-7
EC Number
200-316-0
UN Number
1163
Index Number
007-012-00-5
PubChem CID
5976

Physical-chemical properties

Molecular Formula
C2H8N2
Molar Mass
60.10 g/mol
IUPAC Name
1,1-dimethylhydrazine

Chemical Identifiers

InChI
InChI=1S/C2H8N2/c1-4(2)3/h3H2,1-2H3
InChI Key
RHUYHJGZWVXEHW-UHFFFAOYSA-N

Overview

1,1-dimethylhydrazine (CAS 57-14-7) is a highly toxic organic hydrazine compound with strong reducing properties and significant carcinogenic potential. This colorless, hygroscopic liquid represents one of the most hazardous members of the hydrazine family, requiring exceptional care in handling and storage. With its molecular formula C2H8N2 and molecular weight of 60.1 g/mol, 1,1-dimethylhydrazine exhibits unique chemical reactivity that makes it valuable in specialized industrial applications despite its severe health risks. The compound's classification under multiple danger categories including Carcinogen 1B, Acute Toxicity 3, Skin Corrosion 1B, and Flammable Liquid 2 reflects its comprehensive hazard profile that demands strict safety protocols. The substance's corrosive nature and high toxicity place it in ADR Class 6.1, requiring specialized transportation and storage conditions. Unlike structurally different compounds such as 1-chloro-4-isocyanatobenzene, 1,1-dimethylhydrazine's hydrazine backbone provides distinctive reducing capabilities that are exploited in specific chemical processes. Its hygroscopic properties and reactivity with oxidizing agents necessitate storage under inert atmosphere conditions to prevent decomposition and minimize exposure risks. Primary industrial applications include rocket fuel formulations where its hypergolic properties with oxidizers make it valuable for propulsion systems, specialized chemical synthesis as a reducing agent and intermediate, and research applications in pharmaceutical development. The compound's role in these sectors requires suppliers to maintain strict quality standards and comprehensive safety documentation. OYSI provides 1,1-dimethylhydrazine to qualified industrial customers with full regulatory compliance and technical support for safe handling procedures.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 1B; Acute Tox. 3 *; Acute Tox. 3 *; Skin Corr. 1B; Aquatic Chronic 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H350

May cause cancer.

H331

Toxic if inhaled.

H301

Toxic if swallowed.

H314

Causes severe skin burns and eye damage.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1163
ADR Class6.1
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameDimethylhydrazin, asymmetrisch
Marine PollutantNo

Frequently Asked Questions

What is 1,1-dimethylhydrazine?

1,1-dimethylhydrazine is a highly toxic organic compound with the molecular formula C2H8N2 and CAS number 57-14-7. This chemical substance has a molecular weight of 60.1 g/mol and belongs to the hydrazine family. It is classified as a flammable liquid, carcinogenic substance, and corrosive material. Due to its severe health hazards and environmental risks, it requires extremely careful handling and is subject to strict regulatory controls in industrial applications.

What are the physicochemical properties of 1,1-dimethylhydrazine?

1,1-dimethylhydrazine is a colorless to pale yellow liquid at room temperature with a characteristic ammonia-like odor. It has a molecular weight of 60.1 g/mol and is highly soluble in water due to its polar nature. The compound is hygroscopic, meaning it readily absorbs moisture from air. It exhibits high volatility and can form explosive vapor-air mixtures. The substance is chemically unstable and can decompose under certain conditions, releasing toxic vapors.

What is 1,1-dimethylhydrazine used for?

1,1-dimethylhydrazine is primarily used as a rocket fuel component, particularly as a hypergolic propellant in aerospace applications. It serves as a fuel that ignites spontaneously when mixed with oxidizers like nitrogen tetroxide. The compound is also utilized in specialized chemical synthesis processes and as an intermediate in pharmaceutical research. Due to its extreme toxicity and carcinogenic properties, its use is heavily restricted and limited to highly controlled industrial and research environments with appropriate safety measures.

How to handle 1,1-dimethylhydrazine safely?

1,1-dimethylhydrazine requires extreme safety precautions due to its carcinogenic, toxic, and corrosive properties. Personnel must wear full chemical-resistant suits, supplied-air respirators, and chemical-resistant gloves. Work should only be conducted in well-ventilated areas or under fume hoods with emergency shower facilities nearby. Avoid any skin contact, inhalation, or ingestion. Use only non-sparking tools due to its flammable nature. Emergency response procedures and trained personnel must be readily available during handling operations.

How to store 1,1-dimethylhydrazine correctly?

1,1-dimethylhydrazine must be stored in tightly sealed, compatible containers in a cool, dry, well-ventilated area away from heat sources and ignition points. Storage areas should be equipped with fire suppression systems and emergency containment measures. Keep separated from oxidizing agents, acids, and incompatible materials. Containers should be made of suitable materials that resist corrosion. Storage facilities must comply with local regulations for carcinogenic substances and include appropriate warning signs and restricted access controls.

What to do in case of contact with 1,1-dimethylhydrazine?

1,1-dimethylhydrazine exposure requires immediate emergency response due to its severe toxicity. For skin contact, immediately remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. If inhaled, move the person to fresh air immediately. In case of eye contact, rinse thoroughly with water for at least 15 minutes. Seek immediate medical attention in all exposure cases. Do not induce vomiting if ingested. Contact emergency services and provide the safety data sheet to medical personnel.

How to dispose of 1,1-dimethylhydrazine properly?

1,1-dimethylhydrazine disposal must be handled by licensed hazardous waste disposal companies due to its classification as carcinogenic and toxic waste. The substance cannot be disposed of through normal waste streams or sewage systems. Disposal methods typically involve high-temperature incineration in specialized facilities equipped to handle toxic emissions. All disposal activities must comply with local and European waste regulations, including proper documentation and tracking. Small quantities may require neutralization procedures before disposal, but only by qualified professionals.

How to transport 1,1-dimethylhydrazine?

1,1-dimethylhydrazine is classified under ADR regulations as Class 6.1 (toxic substances), Packing Group I, indicating maximum danger level. Transportation requires specialized containers meeting UN specification standards and proper hazard labeling with appropriate pictograms. Only authorized carriers with permits for dangerous goods can transport this substance. Shipping documentation must include emergency response information and proper shipping names. Vehicle operators need specialized training for toxic material transport, and emergency response equipment must be available during transit.

Is 1,1-dimethylhydrazine subject to specific regulations?

1,1-dimethylhydrazine is subject to extensive European regulations under REACH and CLP due to its carcinogenic classification (Category 1B). The substance requires registration and safety data sheet provision. Its use may be restricted or require authorization under REACH Annex XVII. Workplace exposure limits apply under occupational health regulations. As a carcinogenic substance, it requires special labeling with danger pictograms and warning statements. Import, export, and use may require permits from relevant authorities in EU member states.

Where to buy 1,1-dimethylhydrazine in Europe?

1,1-dimethylhydrazine is available through specialized chemical distributors like OYSI, which serves the European market with industrial-grade chemicals. Due to its extremely hazardous nature and regulatory restrictions, purchases typically require proof of legitimate use, appropriate handling facilities, and compliance with safety regulations. Buyers must demonstrate proper storage capabilities and trained personnel. OYSI can provide guidance on regulatory compliance and safety requirements for this controlled substance, ensuring proper documentation and safe delivery to qualified customers.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.