Prop-2-enal

C3H4O

prop-2-enal

CAS107-02-8
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
107-02-8
EC Number
203-453-4
UN Number
1092
Index Number
605-008-00-3
PubChem CID
7847

Physical-chemical properties

Molecular Formula
C3H4O
Molar Mass
56.06 g/mol
IUPAC Name
prop-2-enal

Chemical Identifiers

InChI
InChI=1S/C3H4O/c1-2-3-4/h2-3H,1H2
InChI Key
HGINCPLSRVDWNT-UHFFFAOYSA-N

Overview

Prop-2-enal (CAS 107-02-8) is a highly reactive aldehyde with acute toxicity and corrosive properties, commonly known as acrolein. This three-carbon unsaturated aldehyde represents one of the most hazardous low molecular weight organic compounds in industrial chemistry. With its molecular formula C3H4O and characteristic pungent odor, prop-2-enal is classified under multiple danger categories including flammable liquid, acute toxicity, skin corrosion, and aquatic toxicity. The compound's dual functional groups - an aldehyde and an alkene - make it exceptionally reactive and valuable for various chemical synthesis applications, though requiring stringent safety protocols during handling and storage. The substance exhibits extreme acute toxicity across multiple exposure routes, earning it a Class 6.1 ADR classification for transport regulations. Its corrosive nature demands specialized containment systems and personal protective equipment. Unlike related compounds such as (E)-but-2-enal, prop-2-enal's shorter carbon chain contributes to its higher volatility and increased inhalation hazards. The compound's reactivity profile differs significantly from other toxic substances like aziridine, as its dual functional groups enable participation in both nucleophilic addition and polymerization reactions. Primary industrial applications include biocide and disinfectant manufacturing, where its antimicrobial properties prove valuable despite handling challenges. The compound serves as a crucial intermediate in acrylic acid production and finds use in specialized polymer synthesis. Additionally, prop-2-enal functions as a chemical warfare agent precursor, making it subject to strict regulatory oversight. OYSI maintains strategic partnerships with certified European manufacturers to ensure reliable supply of prop-2-enal for qualified industrial customers requiring this specialized chemical intermediate.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Acute Tox. 1; Acute Tox. 3; Acute Tox. 2; Skin Corr. 1B; Aquatic Acute 1; Aquatic C...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H300

Fatal if swallowed.

H314

Causes severe skin burns and eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1092
ADR Class6.1
Packing GroupI
Tunnel CodeC/D
Proper Shipping NameAcrolein, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is prop-2-enal?

Prop-2-enal is an organic compound with the molecular formula C3H4O and CAS number 107-02-8. It is an unsaturated aldehyde with a molecular weight of 56.06 g/mol. This chemical is classified as extremely hazardous due to its high acute toxicity, flammability, and corrosive properties. Prop-2-enal poses significant risks to human health and the environment, requiring careful handling and strict safety measures in industrial applications.

What are the physicochemical properties of prop-2-enal?

Prop-2-enal is a colorless to pale yellow liquid with a pungent, acrid odor at room temperature. It has a low boiling point and high volatility, making it readily evaporable. The compound is highly reactive due to its unsaturated aldehyde structure, containing both a carbon-carbon double bond and an aldehyde functional group. It is miscible with water and most organic solvents, and polymerizes easily under certain conditions.

What is prop-2-enal used for?

Prop-2-enal is primarily used as an intermediate in organic synthesis and chemical manufacturing. It serves as a building block for producing various chemicals, pharmaceuticals, and specialty compounds. The substance is utilized in research laboratories for organic reactions and as a reagent in analytical chemistry. Due to its high toxicity and hazardous properties, its applications are strictly controlled and limited to professional industrial settings with appropriate safety infrastructure.

How to handle prop-2-enal safely?

Prop-2-enal requires extreme safety precautions due to its acute toxicity and corrosive nature. Personnel must wear full protective equipment including chemical-resistant gloves, protective clothing, eye protection, and respiratory protection. Work must be conducted in well-ventilated areas or under fume hoods. Avoid skin and eye contact completely, and prevent inhalation of vapors. Only trained professionals should handle this substance in properly equipped facilities with emergency procedures in place.

How to store prop-2-enal correctly?

Prop-2-enal must be stored in a cool, dry, well-ventilated area away from heat sources and ignition points. Use tightly sealed, chemically compatible containers to prevent vapor release and contamination. Store separately from oxidizing agents, bases, and other incompatible materials. Maintain storage temperature below recommended limits and ensure proper labeling. Storage areas should have appropriate fire suppression systems and be accessible only to authorized, trained personnel with proper safety equipment.

What to do in case of contact with prop-2-enal?

Prop-2-enal contact requires immediate emergency response due to its extreme toxicity and corrosive properties. For skin contact, immediately flush with copious amounts of water for at least 15 minutes while removing contaminated clothing. In case of eye contact, rinse immediately with water and seek urgent medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical care. Always contact emergency services and poison control centers promptly.

How to dispose of prop-2-enal appropriately?

Prop-2-enal disposal must comply with local, national, and European hazardous waste regulations due to its classification as acute toxic and environmentally hazardous. The substance cannot be disposed of through regular waste streams and requires specialized hazardous waste treatment facilities. Contact licensed waste disposal companies experienced in handling toxic chemicals. Maintain proper documentation and disposal certificates. Never discharge into sewers, waterways, or the environment under any circumstances.

How to transport prop-2-enal?

Prop-2-enal is classified under ADR class 6.1 (toxic substances) with packing group I, indicating maximum danger level for transport. Transportation requires specialized hazardous goods packaging, proper labeling with GHS pictograms, and compliance with dangerous goods regulations. Only certified carriers with appropriate permits and training can transport this substance. Vehicles must carry emergency equipment and safety data sheets. International transport requires additional documentation and may be subject to route restrictions.

Is prop-2-enal subject to particular regulations?

Prop-2-enal is subject to strict European chemical regulations including REACH registration and CLP classification requirements. While not currently listed as a SVHC (Substance of Very High Concern), its extreme acute toxicity classification subjects it to stringent handling, labeling, and reporting obligations. Users must comply with occupational safety regulations, environmental protection laws, and potentially specific industry restrictions. Regular safety assessments and worker health monitoring may be mandatory in some jurisdictions.

Where to buy prop-2-enal in Europe?

Prop-2-enal is available through OYSI, a European distributor specializing in chemical products for professional and industrial applications. As a regulated hazardous substance, procurement requires proper business credentials, safety infrastructure verification, and compliance with legal requirements. OYSI provides technical support and ensures proper documentation for regulatory compliance. Purchase is restricted to qualified industrial users with appropriate handling facilities and trained personnel due to the substance's extreme hazardous properties.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.