1,1-dichloroprop-1-ene

C3H4Cl2

CAS563-58-6
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
Danger

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Identification

CAS Number
563-58-6
EC Number
209-253-3
UN Number
2047
Index Number
602-031-00-0
PubChem CID
11245

Physical-chemical properties

Molecular Formula
C3H4Cl2
Molar Mass
110.97 g/mol
IUPAC Name
1,1-dichloroprop-1-ene

Chemical Identifiers

InChI
InChI=1S/C3H4Cl2/c1-2-3(4)5/h2H,1H3
InChI Key
ZAIDIVBQUMFXEC-UHFFFAOYSA-N

Overview

1,1-dichloroprop-1-ene (CAS 563-58-6) is a halogenated alkene compound with flammable properties and significant toxicity concerns. This chlorinated organic compound, with the molecular formula C3H4Cl2 and molecular weight of 110.97 g/mol, represents an important intermediate in various chemical synthesis processes. The substance is characterized by its double bond structure and two chlorine substituents at the first carbon position, which contribute to its reactive nature and specific chemical properties. From a safety perspective, 1,1-dichloroprop-1-ene presents multiple hazards requiring careful handling protocols. Classified as a Category 2 flammable liquid under GHS regulations, it carries the "Danger" signal word and displays both flame (GHS02) and skull and crossbones (GHS06) pictograms. The compound exhibits acute toxicity (Category 3) and poses chronic aquatic environmental concerns (Category 3). These characteristics necessitate appropriate storage conditions, personal protective equipment, and ventilation systems during handling and processing operations. The compound shares structural similarities with other halogenated compounds, though it differs significantly from substances like prop-2-enenitrile in terms of functional groups and reactivity patterns. Its chemical behavior is influenced by both the alkene functionality and the presence of chlorine atoms, making it valuable in specific synthetic applications. Primary industrial applications include its use as a chemical intermediate in organic synthesis, particularly in the production of specialized polymers and pharmaceutical intermediates. The compound also finds application in certain solvent formulations and as a building block for more complex chlorinated compounds. OYSI maintains reliable supply chains for 1,1-dichloroprop-1-ene, ensuring consistent availability for qualified industrial customers across European markets.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Acute Tox. 3 *; Aquatic Chronic 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H301

Toxic if swallowed.

H412

Harmful to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2047
ADR Class3
Packing GroupII
Tunnel CodeD/E
Proper Shipping Name1,1-Dichlorpropen
Marine PollutantNo

Frequently Asked Questions

What is 1,1-dichloroprop-1-ene?

1,1-dichloroprop-1-ene is an organochlorine compound with the molecular formula C3H4Cl2 and CAS number 563-58-6. This chemical substance has a molecular weight of 110.97 g/mol and belongs to the class of halogenated alkenes. It is classified as a flammable liquid with acute toxicity properties and poses chronic hazards to aquatic environments. The compound requires careful handling due to its dangerous classification under GHS regulations.

What are the physicochemical properties of 1,1-dichloroprop-1-ene?

1,1-dichloroprop-1-ene is a volatile organic compound that typically exists as a colorless liquid at room temperature. As a halogenated alkene, it exhibits low water solubility but good solubility in organic solvents. The compound has a characteristic chemical odor typical of chlorinated hydrocarbons. Its molecular structure contains a double bond with two chlorine atoms attached to the same carbon, making it reactive and flammable.

What is 1,1-dichloroprop-1-ene used for?

1,1-dichloroprop-1-ene is primarily used as an intermediate in organic synthesis and chemical manufacturing processes. It serves as a building block for producing various chlorinated compounds and can be utilized in polymer chemistry applications. The compound may also find use in specialized industrial processes requiring halogenated alkenes. Its reactivity makes it valuable for creating more complex molecular structures in pharmaceutical and agrochemical industries.

How to handle 1,1-dichloroprop-1-ene safely?

1,1-dichloroprop-1-ene requires strict safety measures due to its flammable and toxic properties. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume hoods to prevent inhalation exposure. Eliminate all ignition sources as the substance is classified as Flam. Liq. 2. Emergency procedures and safety data sheets should be readily available.

How to store 1,1-dichloroprop-1-ene correctly?

1,1-dichloroprop-1-ene must be stored in a cool, dry, well-ventilated area away from heat sources and ignition points. Use only approved containers made of compatible materials, typically glass or specific metal containers. Keep away from oxidizing agents and incompatible substances that could cause dangerous reactions. Storage areas should be equipped with appropriate fire suppression systems and spill containment measures due to the flammable nature of the compound.

What to do in case of contact with 1,1-dichloroprop-1-ene?

Immediate action is required upon contact with 1,1-dichloroprop-1-ene due to its acute toxicity. For skin contact, remove contaminated clothing and wash affected areas thoroughly with soap and water. In case of eye contact, flush immediately with clean water for at least 15 minutes. If inhaled, move the person to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention. Always consult the safety data sheet for specific first aid measures.

How to dispose of 1,1-dichloroprop-1-ene properly?

1,1-dichloroprop-1-ene must be disposed of according to local, national, and European waste regulations as a hazardous chemical waste. The substance cannot be disposed of through regular waste streams due to its toxicity and environmental impact. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Incineration at approved high-temperature facilities is typically required. Empty containers should also be treated as hazardous waste due to potential residual contamination.

How to transport 1,1-dichloroprop-1-ene?

1,1-dichloroprop-1-ene is classified under ADR Class 3 (flammable liquids), Packing Group II, indicating moderate danger level for transport. Shipments must comply with dangerous goods regulations including proper packaging, labeling, and documentation. Vehicles must be equipped with appropriate safety equipment and drivers require dangerous goods training certification. Transport should avoid extreme temperatures and routes through densely populated areas when possible.

Is 1,1-dichloroprop-1-ene subject to specific regulations?

1,1-dichloroprop-1-ene is subject to European REACH regulation requiring registration for import and use above certain tonnages. The substance falls under CLP classification with GHS pictograms GHS02 and GHS06, requiring appropriate hazard communication. While not currently listed as an SVHC (Substance of Very High Concern), it may be subject to national restrictions or monitoring programs. Users must comply with occupational health and safety regulations and environmental protection laws.

Where to buy 1,1-dichloroprop-1-ene in Europe?

1,1-dichloroprop-1-ene is available through OYSI, a specialized European distributor of technical chemicals and laboratory reagents. OYSI provides reliable supply chains across European markets with proper documentation and regulatory compliance. As a hazardous substance requiring careful handling, procurement should only be through qualified chemical distributors who can ensure proper packaging, labeling, and transportation according to ADR regulations and safety requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.