Prop-2-enenitrile

C3H3N

prop-2-enenitrile

CAS107-13-1
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
107-13-1
EC Number
203-466-5
UN Number
1093
Index Number
608-003-00-4
PubChem CID
7855

Physical-chemical properties

Molecular Formula
C3H3N
Molar Mass
53.06 g/mol
IUPAC Name
prop-2-enenitrile

Chemical Identifiers

InChI
InChI=1S/C3H3N/c1-2-3-4/h2H,1H2
InChI Key
NLHHRLWOUZZQLW-UHFFFAOYSA-N

Overview

Prop-2-enenitrile (CAS 107-13-1) is an unsaturated aliphatic nitrile with high reactivity and significant toxicological properties. This three-carbon nitrile compound, also known by its IUPAC designation prop-2-enenitrile, represents a critical intermediate in various chemical synthesis processes. With the molecular formula C3H3N and a molecular weight of 53.06 g/mol, this substance combines the reactive characteristics of both alkene and nitrile functional groups, making it valuable for numerous industrial applications while requiring stringent safety protocols. The compound exhibits significant hazard classifications including flammable liquid category 2, carcinogen category 1B, and acute toxicity category 3 across multiple exposure routes. The presence of GHS pictograms GHS02, GHS08, GHS06, GHS05, and GHS09 indicates its flammable, health hazardous, toxic, corrosive, and environmentally dangerous properties. Its ADR classification as class 3 confirms its status as a dangerous good requiring specialized transport conditions. Prop-2-enenitrile finds primary applications in polymer synthesis, pharmaceutical intermediate production, and specialty chemical manufacturing. The compound serves as a monomer in acrylic polymer production and as a building block for various nitrogen-containing organic compounds. Unlike structurally different compounds such as 5-bromo-1,2,3-trifluorobenzene, prop-2-enenitrile's unsaturated nitrile structure provides unique reactivity patterns essential for specific synthetic pathways. Safety considerations are paramount when handling this substance, requiring appropriate ventilation, personal protective equipment, and adherence to strict storage protocols to mitigate its carcinogenic and acute toxicity risks. OYSI provides prop-2-enenitrile to qualified industrial customers across Europe, ensuring compliance with all relevant safety and regulatory requirements for this specialized chemical intermediate.

Safety & Classification

Danger
Classification:

Flam. Liq. 2; Carc. 1B; Acute Tox. 3 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; Skin Irrit. 2;...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H225

Highly flammable liquid and vapour.

H350

May cause cancer.

H331

Toxic if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H317

May cause an allergic skin reaction.

H411

Toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1093
ADR Class3
Packing GroupI
Tunnel CodeC/E
Proper Shipping NameAcrylnitril, stabilisiert
Marine PollutantNo

Frequently Asked Questions

What is prop-2-enenitrile?

Prop-2-enenitrile is an organic chemical compound with the molecular formula C3H3N and CAS number 107-13-1. This nitrile compound has a molecular weight of 53.06 g/mol and is classified as a highly hazardous substance due to its carcinogenic, toxic, and flammable properties. It appears as a colorless liquid with a pungent odor and is highly reactive, making it an important intermediate in chemical synthesis processes.

What are the physicochemical properties of prop-2-enenitrile?

Prop-2-enenitrile is a colorless liquid with a sharp, pungent odor characteristic of nitriles. It has a molecular weight of 53.06 g/mol and is highly volatile and flammable. The compound is miscible with most organic solvents and has limited solubility in water. It polymerizes readily, especially when exposed to heat, light, or alkaline conditions, which makes it chemically unstable and reactive under normal storage conditions.

What is prop-2-enenitrile used for?

Prop-2-enenitrile is primarily used as a monomer in the production of acrylic fibers, plastics, and synthetic rubbers through polymerization processes. It serves as an important intermediate in organic synthesis for manufacturing various chemicals including pharmaceuticals, pesticides, and specialty chemicals. The compound is also used in the production of carbon fiber precursors and as a starting material for creating other nitrile compounds in industrial chemical processes.

How to handle prop-2-enenitrile safely?

Prop-2-enenitrile requires extreme caution during handling due to its carcinogenic and toxic properties. Always wear appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas or fume hoods. Avoid skin contact, inhalation, and ingestion completely. Use only in designated chemical handling areas with emergency shower and eyewash stations readily available. Keep away from heat sources, sparks, and open flames due to its flammable nature.

How to store prop-2-enenitrile correctly?

Prop-2-enenitrile must be stored in a cool, dry, well-ventilated area away from heat sources, direct sunlight, and ignition sources. Keep containers tightly sealed in a fireproof storage cabinet designed for flammable liquids. Store separately from oxidizing agents, acids, and bases to prevent dangerous reactions. Maintain storage temperature below 25°C and add stabilizers to prevent polymerization. Regular inspection of containers for leaks or deterioration is essential due to the compound's reactive nature.

What to do in case of contact with prop-2-enenitrile?

Immediate action is critical following prop-2-enenitrile exposure due to its high toxicity. For skin contact, immediately remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. In case of eye contact, rinse continuously with water and seek immediate medical attention. If inhaled, move to fresh air immediately and provide oxygen if breathing is difficult. For ingestion, do not induce vomiting and seek emergency medical care immediately while providing supportive treatment.

How to dispose of prop-2-enenitrile properly?

Prop-2-enenitrile disposal must comply with local and international hazardous waste regulations due to its classification as dangerous waste. The substance cannot be disposed of in regular waste streams and requires treatment at licensed hazardous waste facilities equipped for toxic and flammable materials. Small quantities should be collected in appropriate containers and labeled clearly before transport to authorized disposal facilities. Incineration at high temperatures in specialized facilities is typically the preferred disposal method.

How to transport prop-2-enenitrile?

Prop-2-enenitrile is classified under ADR Class 3 (Flammable Liquids), Packing Group I, indicating it poses the highest level of danger during transport. Transportation requires specialized packaging meeting UN specifications and proper hazard labeling with GHS pictograms including flammable, toxic, and health hazard symbols. Only certified carriers trained in dangerous goods handling can transport this substance. Emergency response information and safety data sheets must accompany shipments at all times.

Is prop-2-enenitrile subject to specific regulations?

Prop-2-enenitrile is subject to extensive regulatory control under multiple frameworks including REACH registration requirements in Europe and CLP classification as Category 1B carcinogen. The compound requires safety data sheets, proper labeling with danger signal words, and specific handling protocols. Its carcinogenic classification means it falls under occupational exposure limits and requires workplace monitoring. Additionally, its transport is regulated under ADR dangerous goods regulations and may be subject to import/export licensing requirements.

Where to buy prop-2-enenitrile in Europe?

Prop-2-enenitrile is available through specialized chemical distributors in Europe, including OYSI, which supplies high-quality chemical products to industrial customers across the European market. Due to its hazardous classification, purchase requires proper documentation, safety protocols, and compliance with regulatory requirements. Buyers must demonstrate appropriate handling capabilities, storage facilities, and safety training. Contact OYSI's technical team for availability, specifications, and regulatory compliance support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.