Tris(nickel(2+)) diarsorite

As2Ni3O6

tris(nickel(2+)) diarsorite

CAS74646-29-0
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
74646-29-0
UN Number
3077
Index Number
028-042-00-5
PubChem CID
22754412

Physical-chemical properties

Molecular Formula
As2Ni3O6
Molar Mass
421.92 g/mol
IUPAC Name
tris(nickel(2+)) diarsorite

Chemical Identifiers

InChI
InChI=1S/2AsO3.3Ni/c2*2-1(3)4;;;/q2*-3;3*+2
InChI Key
QCJOGAKGLZETET-UHFFFAOYSA-N

Overview

Tris(nickel(2+)) diarsorite (CAS 74646-29-0) is an inorganic arsenic-nickel compound with significant industrial applications and notable safety considerations. This specialized chemical compound, with the molecular formula As2Ni3O6 and molecular weight of 421.92 g/mol, represents a complex oxide structure containing both nickel and arsenic components. The substance belongs to the category of mixed metal oxides and is classified under ADR Class 9 for transportation purposes, indicating its status as a miscellaneous dangerous substance requiring careful handling protocols. The compound presents significant safety challenges due to its comprehensive hazard profile. It is classified as a Category 1A carcinogen, indicating sufficient evidence of carcinogenic potential to humans. Additionally, it demonstrates specific target organ toxicity following repeated exposure (STOT RE 1) and acts as a skin sensitizer. The environmental impact is equally concerning, with classifications for both acute and chronic aquatic toxicity, necessitating strict containment measures to prevent environmental release. From a chemical perspective, tris(nickel(2+)) diarsorite shares structural similarities with other metal chalcogenide compounds such as sulfanylidenenickel and tellanylidenenickel, though its arsenic-oxide framework provides distinct properties. The GHS classification system assigns danger pictograms GHS08, GHS07, and GHS09, reflecting its health hazards and environmental risks. Industrial applications typically include specialized catalytic processes, advanced materials synthesis, and certain metallurgical operations where the unique combination of nickel and arsenic properties is essential. The compound may also find use in specialized ceramic formulations and electronic component manufacturing. OYSI maintains availability of tris(nickel(2+)) diarsorite for qualified industrial customers with appropriate handling capabilities and regulatory compliance frameworks.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameTrinickel-bis(arsenit)
Marine PollutantNo

Frequently Asked Questions

What is tris(nickel(2+)) diarsorite?

Tris(nickel(2+)) diarsorite is an inorganic compound with the molecular formula As2Ni3O6 and CAS number 74646-29-0. This substance contains both nickel and arsenic elements in its structure, with a molecular weight of 421.92 g/mol. It is classified as a Category 1A carcinogen and poses significant health and environmental risks, requiring careful handling and strict safety measures in industrial applications.

What are the physicochemical properties of tris(nickel(2+)) diarsorite?

Tris(nickel(2+)) diarsorite is an inorganic solid compound with a molecular formula As2Ni3O6 and molecular weight of 421.92 g/mol. As a nickel-arsenic compound, it typically appears as a crystalline solid. Due to the presence of both nickel and arsenic in its structure, it exhibits properties characteristic of transition metal arsenates, though specific physical properties like color and solubility depend on the exact crystalline form.

What is tris(nickel(2+)) diarsorite used for?

Tris(nickel(2+)) diarsorite is primarily used in specialized industrial applications requiring specific nickel-arsenic compounds. Its applications may include use as a catalyst precursor, in metallurgical processes, or in specialized chemical synthesis. Given its high toxicity classification as a Category 1A carcinogen, its use is restricted to professional industrial settings with appropriate safety controls and regulatory compliance measures in place.

How to handle tris(nickel(2+)) diarsorite safely?

Tris(nickel(2+)) diarsorite requires extreme caution due to its Category 1A carcinogen classification and skin sensitization potential. Essential safety measures include wearing full protective equipment (respiratory protection, chemical-resistant gloves, protective clothing), working in well-ventilated areas or fume hoods, and avoiding skin contact and inhalation. Only trained personnel should handle this substance, following strict occupational safety protocols and regular health monitoring procedures.

How to store tris(nickel(2+)) diarsorite correctly?

Tris(nickel(2+)) diarsorite must be stored in a secure, dry, well-ventilated area away from incompatible materials and heat sources. Storage areas should be restricted to authorized personnel only, with appropriate warning signs and emergency procedures. The substance should be kept in original, tightly sealed containers to prevent contamination and exposure. Storage facilities must comply with local regulations for carcinogenic substances and environmental protection requirements.

What to do in case of contact with tris(nickel(2+)) diarsorite?

Immediate action is required if contact occurs with tris(nickel(2+)) diarsorite. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move to fresh air immediately and seek medical attention. For eye contact, flush with clean water for 15 minutes. Given its carcinogenic nature, seek immediate medical advice in all exposure cases and inform healthcare providers of the substance involved.

How to dispose of tris(nickel(2+)) diarsorite appropriately?

Tris(nickel(2+)) diarsorite must be disposed of as hazardous waste through licensed waste management companies specializing in carcinogenic and heavy metal-containing materials. The substance cannot be disposed of in regular waste streams due to its toxicity and environmental hazard classification. Disposal must comply with national and EU waste regulations, including proper documentation and tracking. Empty containers should also be treated as hazardous waste requiring professional disposal.

How to transport tris(nickel(2+)) diarsorite?

Tris(nickel(2+)) diarsorite is classified under ADR Class 9 (Miscellaneous dangerous goods), Packing Group III for transportation purposes. It must be transported in appropriate UN-specification packaging with proper labeling including GHS pictograms (GHS07, GHS08, GHS09) and hazard information. Transport requires documentation including safety data sheets and emergency response information. Only certified carriers experienced in handling carcinogenic substances should transport this material.

Is tris(nickel(2+)) diarsorite subject to specific regulations?

Tris(nickel(2+)) diarsorite is subject to strict European regulations under REACH and CLP due to its carcinogenic classification. As a Category 1A carcinogen, it faces restrictions on use and requires authorization for certain applications. The substance must be registered under REACH, properly classified and labeled according to CLP regulation, and handled according to occupational safety directives. Additional national restrictions may apply for carcinogenic substances in workplace environments.

Where to buy tris(nickel(2+)) diarsorite in Europe?

Tris(nickel(2+)) diarsorite is available through specialized chemical distributors like OYSI, which supplies technical chemicals across Europe. Due to its hazardous nature and regulatory requirements, purchase is restricted to qualified industrial users with appropriate safety facilities and regulatory compliance. Buyers must demonstrate legitimate industrial use, proper handling capabilities, and compliance with REACH registration requirements before procurement can be arranged through authorized European distributors.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.