Sulfanylidenenickel

NiS

sulfanylidenenickel

CAS12137-12-1
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
12137-12-1
UN Number
3077
Index Number
028-041-00-X
PubChem CID
28094

Physical-chemical properties

Molecular Formula
NiS
Molar Mass
90.76 g/mol
IUPAC Name
sulfanylidenenickel

Chemical Identifiers

InChI
InChI=1S/Ni.S
InChI Key
WWNBZGLDODTKEM-UHFFFAOYSA-N

Overview

Sulfanylidenenickel (CAS 12137-12-1) is an inorganic nickel sulfide compound with significant industrial applications and notable health hazards requiring careful handling protocols. This binary compound, consisting of nickel and sulfur in a 1:1 stoichiometric ratio, represents one of the most commercially important nickel sulfide phases. With its molecular formula NiS and molecular weight of 90.76 g/mol, sulfanylidenenickel exhibits the characteristic properties of transition metal sulfides, including semiconducting behavior and thermal stability under appropriate conditions. The compound's crystalline structure contributes to its utility in various industrial processes, particularly where controlled chemical reactivity and specific electronic properties are required. Safety considerations are paramount when handling sulfanylidenenickel due to its classification as a Category 1A carcinogen and respiratory sensitizer. The compound displays the GHS08, GHS07, and GHS09 pictograms, indicating serious health hazards including carcinogenic potential, skin sensitization, and environmental toxicity. As a Class 9 ADR substance, it requires specialized transport and storage protocols. Workers must implement comprehensive protective measures including appropriate ventilation systems and personal protective equipment to prevent inhalation or skin contact. Industrial applications of sulfanylidenenickel include its use as a catalyst precursor in hydrogenation and desulfurization processes, where its controlled reactivity proves valuable. The compound also serves in specialized metallurgical applications and as an intermediate in the production of other nickel-containing materials. Related compounds such as selanylidenenickel and tellanylidenenickel share similar structural characteristics but exhibit different reactivity profiles suited to specific applications. OYSI provides sulfanylidenenickel to qualified industrial customers with comprehensive technical documentation and safety data sheets to ensure proper handling and regulatory compliance.

Safety & Classification

Danger
Classification:

Carc. 1A; STOT RE 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H372

Causes damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameTrinickeltetrasulfid
Marine PollutantNo

Frequently Asked Questions

What is sulfanylidenenickel?

Sulfanylidenenickel is an inorganic compound with the chemical formula NiS, also known as nickel sulfide. This chemical substance has a molecular weight of 90.76 g/mol and is classified as a Category 1A carcinogen under CLP regulation. It belongs to the transition metal sulfide family and is considered highly hazardous due to its carcinogenic properties and potential for causing respiratory sensitization and environmental damage.

What are the physicochemical properties of sulfanylidenenickel?

Sulfanylidenenickel appears as a dark-colored solid compound at room temperature, typically presenting as black or dark gray crystals or powder. As a metal sulfide, it exhibits low solubility in water but may dissolve in acidic solutions. The compound is stable under normal conditions but can release toxic sulfur compounds when heated to decomposition. Its density and melting point are characteristic of transition metal sulfides.

What is sulfanylidenenickel used for?

Sulfanylidenenickel is primarily used in industrial applications including metallurgy, electronics manufacturing, and as a catalyst in certain chemical processes. It serves as a precursor in the production of other nickel compounds and finds applications in specialized alloy production. Due to its hazardous classification as a Category 1A carcinogen, its use is strictly regulated and limited to professional industrial settings with appropriate safety controls.

How to handle sulfanylidenenickel safely?

Sulfanylidenenickel requires extreme caution during handling due to its carcinogenic properties. Personnel must wear complete respiratory protection, chemical-resistant gloves, and protective clothing to prevent skin contact and inhalation. Work should be conducted in well-ventilated areas or under fume extraction systems. All handling procedures must comply with occupational exposure limits and cancer prevention protocols. Regular health monitoring of exposed workers is essential.

How to store sulfanylidenenickel correctly?

Sulfanylidenenickel must be stored in tightly sealed containers in a dry, cool, and well-ventilated area away from incompatible materials. Storage areas should be equipped with appropriate containment measures and restricted access due to the carcinogenic nature of the substance. Containers should be clearly labeled with hazard warnings and kept away from heat sources, acids, and oxidizing agents to prevent dangerous reactions.

What to do in case of contact with sulfanylidenenickel?

Skin contact with sulfanylidenenickel requires immediate removal of contaminated clothing and thorough washing with soap and water for at least 15 minutes. In case of inhalation, move the person to fresh air immediately and seek medical attention. Eye contact necessitates immediate flushing with clean water for 15 minutes. Due to the carcinogenic properties, all exposure incidents require prompt medical evaluation and documentation.

How to dispose of sulfanylidenenickel appropriately?

Sulfanylidenenickel disposal must comply with hazardous waste regulations as it is classified as carcinogenic and environmentally hazardous. The substance cannot be disposed of in regular waste streams and requires specialized treatment by licensed hazardous waste management facilities. Disposal methods typically involve high-temperature incineration or secure landfill disposal. All disposal activities must be documented and comply with local environmental regulations.

How to transport sulfanylidenenickel?

Sulfanylidenenickel is classified under ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. Packages must bear appropriate hazard labels including GHS08, GHS07, and GHS09 pictograms with 'Danger' signal word. Transportation requires proper documentation, appropriate packaging specifications, and compliance with dangerous goods regulations. Vehicles must carry emergency response information and appropriate safety equipment.

Is sulfanylidenenickel subject to specific regulations?

Sulfanylidenenickel is subject to strict regulatory oversight under REACH and CLP regulations due to its classification as a Category 1A carcinogen. The substance requires comprehensive safety data sheets, exposure scenario development, and risk management measures. Its carcinogenic classification triggers specific workplace health surveillance requirements and may be subject to authorization procedures. Environmental release is strictly controlled under aquatic toxicity regulations.

Where to buy sulfanylidenenickel in Europe?

Sulfanylidenenickel is available through OYSI, a specialized European distributor of technical chemical products. As a regulated carcinogenic substance, procurement requires verification of legitimate industrial use and compliance with safety regulations. OYSI provides comprehensive documentation including safety data sheets and regulatory compliance support. Purchase is restricted to qualified industrial users with appropriate handling facilities and safety protocols in place.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.