Tricalcium bis(phosphorus(3-))

Ca3P2

tricalcium bis(phosphorus(3-))

CAS1305-99-3
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
1305-99-3
EC Number
215-142-0
UN Number
1360
Index Number
015-003-00-2
PubChem CID
14780

Physical-chemical properties

Molecular Formula
Ca3P2
Molar Mass
182.18 g/mol
IUPAC Name
tricalcium bis(phosphorus(3-))

Chemical Identifiers

InChI
InChI=1S/3Ca.2P/q3*+2;2*-3
InChI Key
HMJZRBDFJAQGEY-UHFFFAOYSA-N

Overview

Tricalcium bis(phosphorus(3-)) (CAS 1305-99-3) is an inorganic calcium phosphide compound with highly reactive water-sensitive properties and significant toxicity hazards. This binary ionic compound, represented by the molecular formula Ca3P2 and molecular weight of 182.18 g/mol, belongs to the metal phosphide family of chemicals. The substance exhibits extreme reactivity with water, releasing toxic phosphine gas upon contact with moisture or aqueous solutions, which accounts for its classification under ADR class 4.3 as a dangerous water-reactive material. The compound's hazard profile includes acute toxicity categories 1-3, eye damage category 1, and aquatic acute toxicity category 1, requiring the "Danger" signal word and multiple GHS pictograms including flammable, toxic, corrosive, and environmental hazard symbols. The material's primary safety concerns stem from its violent reaction with water and the subsequent generation of phosphine (PH3), a highly toxic and flammable gas. This characteristic necessitates strict moisture exclusion during storage and handling, typically requiring inert atmosphere conditions and specialized containment systems. Similar reactivity patterns are observed in related compounds such as trimagnesium bis(phosphorus(3-)) and trizinc bis(phosphorus(3-)), which share comparable water-reactive properties within the metal phosphide family. Industrial applications for tricalcium bis(phosphorus(3-)) include use as a reducing agent in metallurgical processes, as a precursor for specialized phosphorus-containing compounds, and in certain semiconductor manufacturing applications where controlled phosphine generation is required. OYSI provides tricalcium bis(phosphorus(3-)) to qualified industrial customers with appropriate handling capabilities and safety infrastructure.

Safety & Classification

Danger
Classification:

Water-react. 1; Acute Tox. 1; Acute Tox. 3; Acute Tox. 2; Eye Dam. 1; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H260

In contact with water releases flammable gases which may ignite spontaneously.

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H300

Fatal if swallowed.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Fatal

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1360
ADR Class4.3
Packing GroupI
Tunnel CodeE
Proper Shipping NameCalciumphosphid
Marine PollutantNo

Frequently Asked Questions

What is tricalcium bis(phosphorus(3-))?

Tricalcium bis(phosphorus(3-)) is an inorganic compound with the molecular formula Ca3P2 and CAS number 1305-99-3. This substance has a molecular weight of 182.18 g/mol and belongs to the category of calcium phosphides. It is classified as a highly hazardous chemical with multiple danger classes including water-reactive properties, acute toxicity, eye damage potential, and aquatic toxicity. The compound requires careful handling due to its dangerous nature and regulatory classification under various safety frameworks.

What are the physicochemical properties of tricalcium bis(phosphorus(3-))?

Tricalcium bis(phosphorus(3-)) is a solid inorganic compound that exhibits water-reactive properties as indicated by its Water-react. 1 classification. The substance demonstrates high chemical reactivity, particularly with water, which can lead to dangerous reactions. Its molecular structure Ca3P2 indicates the presence of calcium and phosphorus elements in a 3:2 ratio. The compound's hazardous nature is evidenced by its classification requiring GHS pictograms for flammable, toxic, corrosive, and environmental hazard warnings.

What is tricalcium bis(phosphorus(3-)) used for?

Tricalcium bis(phosphorus(3-)) is primarily used in specialized industrial applications where calcium phosphide compounds are required. Due to its highly hazardous classification and water-reactive properties, its applications are limited to controlled industrial processes. The substance may be utilized in specific chemical synthesis reactions or as an intermediate in the production of other calcium or phosphorus-containing compounds. Its use requires specialized facilities and expertise due to the significant safety risks associated with handling this dangerous chemical.

How to handle tricalcium bis(phosphorus(3-)) safely?

Tricalcium bis(phosphorus(3-)) requires extreme caution during handling due to its Danger signal word and multiple hazard classifications. Personnel must wear appropriate personal protective equipment including chemical-resistant gloves, eye protection, and respiratory protection. The substance should only be handled in well-ventilated areas or under controlled atmospheric conditions. Avoid contact with water due to its water-reactive properties. Work should be conducted by trained professionals familiar with highly toxic and reactive chemicals, following strict safety protocols and emergency procedures.

How to store tricalcium bis(phosphorus(3-)) correctly?

Tricalcium bis(phosphorus(3-)) must be stored in a dry, secure area away from water and moisture due to its Water-react. 1 classification. Storage containers should be tightly sealed and made of compatible materials that resist chemical interaction. The storage area must be well-ventilated and equipped with appropriate fire safety measures. Keep away from incompatible substances and ensure access is restricted to authorized personnel only. Temperature and humidity control are essential to prevent unintended reactions and maintain product stability.

What to do in case of contact with tricalcium bis(phosphorus(3-))?

Tricalcium bis(phosphorus(3-)) exposure requires immediate emergency response due to its Acute Tox. classifications and Eye Dam. 1 properties. For skin contact, immediately remove contaminated clothing and flush affected area with copious amounts of water. In case of eye contact, rinse immediately with water for at least 15 minutes and seek urgent medical attention. If inhaled, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical care. Always contact poison control centers and emergency services promptly.

How to dispose of tricalcium bis(phosphorus(3-)) appropriately?

Tricalcium bis(phosphorus(3-)) disposal must comply with local and international hazardous waste regulations due to its multiple danger classifications. The substance cannot be disposed of through normal waste streams and requires specialized hazardous waste treatment facilities. Disposal methods must account for its water-reactive properties and high toxicity levels. Contact certified hazardous waste disposal companies that can handle Class 4.3 dangerous goods. All disposal activities must be documented and performed in accordance with environmental protection regulations and safety protocols.

How to transport tricalcium bis(phosphorus(3-))?

Tricalcium bis(phosphorus(3-)) is classified under ADR Class 4.3, Packing Group I, indicating it is a dangerous substance that reacts with water to emit flammable gases. Transport requires specialized dangerous goods packaging, labeling, and documentation. Vehicles must be equipped for Class 4.3 transport and drivers must hold appropriate dangerous goods certifications. The substance must be kept dry during transport and protected from moisture. All transport activities must comply with ADR/RID regulations and international dangerous goods transport requirements.

Is tricalcium bis(phosphorus(3-)) subject to specific regulations?

Tricalcium bis(phosphorus(3-)) is subject to extensive regulatory oversight under multiple frameworks including CLP regulation due to its hazardous classification, and REACH registration requirements for chemical substances. The compound's classification requires compliance with workplace safety regulations, environmental protection laws, and dangerous goods transport regulations. While not currently listed as an SVHC substance, its high toxicity and environmental hazard classifications mean it falls under strict handling, storage, and disposal regulations across European jurisdictions.

Where to buy tricalcium bis(phosphorus(3-)) in Europe?

Tricalcium bis(phosphorus(3-)) is available through OYSI, a specialized European distributor of technical chemicals. Due to the substance's highly hazardous nature and regulatory requirements, procurement is limited to qualified industrial customers with appropriate handling capabilities and regulatory compliance. OYSI provides technical support and regulatory documentation to ensure proper handling and compliance. Customers must demonstrate adequate safety infrastructure and trained personnel before purchase approval. Contact OYSI directly for availability, technical specifications, and regulatory guidance for this controlled substance.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.