Triphenylstannyl acetate

C20H18O2Sn

triphenylstannyl acetate

CAS900-95-8
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
900-95-8
EC Number
212-984-0
UN Number
2786
Index Number
050-003-00-6
PubChem CID
16682804

Physical-chemical properties

Molecular Formula
C20H18O2Sn
Molar Mass
409.10 g/mol
IUPAC Name
triphenylstannyl acetate

Chemical Identifiers

InChI
InChI=1S/3C6H5.C2H4O2.Sn/c3*1-2-4-6-5-3-1;1-2(3)4;/h3*1-5H;1H3,(H,3,4);/q;;;;+1/p-1
InChI Key
WDQNIWFZKXZFAY-UHFFFAOYSA-M

Overview

Triphenylstannyl acetate (CAS 900-95-8) is an organotin compound with significant toxicological properties and specialized industrial applications. This organometallic compound belongs to the triphenyltin family, characterized by three phenyl groups bonded to a central tin atom with an acetate functional group. With a molecular formula of C20H18O2Sn and molecular weight of 409.1 g/mol, triphenylstannyl acetate represents a sophisticated chemical intermediate used in various industrial processes. The compound shares structural similarities with related organotin compounds such as triphenylstannanylium hydroxide, though each exhibits distinct reactivity profiles and application areas. The substance presents significant safety considerations, classified under multiple hazard categories including carcinogenicity (Category 2), reproductive toxicity (Category 2), and acute toxicity across multiple exposure routes. The presence of GHS pictograms including GHS08 (health hazard), GHS06 (skull and crossbones), GHS05 (corrosion), and GHS09 (environmental hazard) underscores the need for stringent handling protocols. Its ADR classification as Class 6.1 reflects its toxic nature during transportation, requiring specialized logistics considerations. Primary industrial applications include its use as a catalyst in organic synthesis reactions, particularly in polymerization processes where organotin compounds demonstrate exceptional catalytic efficiency. The compound also serves as a precursor for manufacturing other specialized organotin derivatives and finds application in certain biocide formulations where its antimicrobial properties prove valuable. OYSI maintains availability of triphenylstannyl acetate through our European distribution network, ensuring compliance with REACH regulations and providing comprehensive technical support for safe handling and application protocols.

Safety & Classification

Danger
Classification:

Carc. 2; Repr. 2; Acute Tox. 2 *; Acute Tox. 3 *; Acute Tox. 3 *; STOT SE 3; STOT RE 1; Skin Irri...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H351

Suspected of causing cancer.

H330

Fatal if inhaled.

H311

Toxic in contact with skin.

H301

Toxic if swallowed.

H335

May cause respiratory irritation.

H372

Causes damage to organs through prolonged or repeated exposure.

H315

Causes skin irritation.

H318

Causes serious eye damage.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Fatal

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Toxic

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number2786
ADR Class6.1
Packing GroupI
Tunnel CodeC/E
Proper Shipping NameFentinacetat (ISO)
Marine PollutantNo

Frequently Asked Questions

What is triphenylstannyl acetate?

Triphenylstannyl acetate is an organotin compound with the molecular formula C20H18O2Sn and CAS number 900-95-8. This chemical substance has a molecular weight of 409.1 g/mol and belongs to the family of triphenyltin derivatives. It is classified as a highly hazardous substance with multiple health risks including carcinogenic and reproductive toxicity properties. The compound requires careful handling due to its acute toxicity and potential for causing serious organ damage.

What are the physicochemical properties of triphenylstannyl acetate?

Triphenylstannyl acetate is an organotin compound that typically appears as a solid at room temperature. As an organometallic acetate derivative, it contains tin coordinated with three phenyl groups and an acetate moiety. The compound has a molecular weight of 409.1 g/mol and exhibits properties typical of organotin compounds, including potential light sensitivity and moisture sensitivity. Specific physical properties such as melting point, solubility, and appearance may vary depending on purity and storage conditions.

What is triphenylstannyl acetate used for?

Triphenylstannyl acetate is primarily used as a specialized chemical reagent in organic synthesis and research applications. As an organotin compound, it may serve as a catalyst or intermediate in various chemical reactions, particularly in organometallic chemistry. Due to its high toxicity profile and classification as carcinogenic and reproductive toxin, its applications are typically limited to controlled laboratory and industrial settings where appropriate safety measures can be implemented.

How to handle triphenylstannyl acetate safely?

Triphenylstannyl acetate requires strict safety protocols due to its acute toxicity and carcinogenic properties. Personal protective equipment must include chemical-resistant gloves, safety goggles, and respiratory protection in well-ventilated areas or fume hoods. Avoid skin contact, inhalation, and ingestion at all costs. Work in controlled environments with appropriate engineering controls. Emergency shower and eyewash stations should be readily accessible. Only trained personnel should handle this substance following established safety procedures.

How to store triphenylstannyl acetate correctly?

Triphenylstannyl acetate must be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. As an organotin compound, it should be protected from moisture, heat, and direct sunlight. Storage areas must be restricted to authorized personnel only due to its high toxicity classification. Containers should be properly labeled with hazard information and stored in secondary containment systems to prevent accidental release or exposure.

What to do in case of contact with triphenylstannyl acetate?

Immediate action is critical due to the acute toxicity of triphenylstannyl acetate. In case of skin contact, immediately remove contaminated clothing and flush affected area with plenty of water for at least 15 minutes. For eye contact, rinse thoroughly with water and seek immediate medical attention. If inhaled, move to fresh air immediately. If ingested, do not induce vomiting and seek emergency medical care. Always contact poison control or emergency services for exposure incidents.

How to dispose of triphenylstannyl acetate properly?

Triphenylstannyl acetate disposal must comply with hazardous waste regulations due to its toxic properties and environmental impact potential. The substance cannot be disposed of through regular waste streams and requires specialized hazardous waste treatment. Contact licensed hazardous waste disposal companies for proper collection and treatment. Follow local, national, and EU waste regulations including proper labeling, documentation, and transport requirements. Never discharge into drains, soil, or water bodies.

How to transport triphenylstannyl acetate?

Triphenylstannyl acetate is classified under ADR Class 6.1 (Toxic substances) Packing Group I, indicating high toxicity requiring strict transport regulations. Packages must meet UN specification requirements for toxic substances with appropriate hazard labels and documentation. Transport vehicles must carry emergency response information and proper shipping papers. Only certified dangerous goods transport companies should handle shipment, ensuring compliance with international transport regulations for toxic materials.

Is triphenylstannyl acetate subject to specific regulations?

Triphenylstannyl acetate is subject to comprehensive chemical safety regulations under EU REACH and CLP frameworks. Its classification as carcinogenic (Category 2) and reproductive toxin (Category 2) triggers specific authorization and restriction requirements. Users must comply with occupational exposure limits, worker protection measures, and environmental release controls. The substance requires safety data sheets, hazard communication, and may be subject to additional national restrictions due to its high toxicity profile.

Where to buy triphenylstannyl acetate in Europe?

Triphenylstannyl acetate is available through OYSI, a specialized European distributor of technical chemicals and laboratory reagents. As a controlled substance with high toxicity classification, procurement requires compliance with regulatory requirements and proper documentation. OYSI provides technical support and ensures proper handling throughout the supply chain. Contact OYSI directly for availability, technical specifications, safety documentation, and regulatory compliance assistance for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.