Tetraethyl silicate

C8H20O4Si

tetraethyl silicate

CAS78-10-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
78-10-4
EC Number
201-083-8
UN Number
1292
Index Number
014-005-00-0
PubChem CID
6517

Physical-chemical properties

Molecular Formula
C8H20O4Si
Molar Mass
208.33 g/mol
IUPAC Name
tetraethyl silicate

Chemical Identifiers

InChI
InChI=1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3
InChI Key
BOTDANWDWHJENH-UHFFFAOYSA-N

Overview

Tetraethyl silicate (CAS 78-10-4) is an organosilicon compound with excellent hydrolysis properties and film-forming capabilities used extensively as a crosslinking agent in industrial applications. This colorless liquid, also known by its IUPAC designation tetraethyl silicate, serves as a crucial intermediate in silicone chemistry and surface treatment technologies. With the molecular formula C8H20O4Si and a molecular weight of 208.33 g/mol, this versatile compound exhibits unique reactivity that makes it valuable across multiple industrial sectors. Upon exposure to moisture, tetraethyl silicate undergoes controlled hydrolysis to form silica networks, a property that distinguishes it from simpler organic compounds like 1,4-xylene which lacks this silicon-based functionality. The compound presents specific safety considerations that require careful handling protocols. Classified as a flammable liquid (Category 3) and acute toxin (Category 4), tetraethyl silicate requires appropriate ventilation and fire prevention measures during storage and use. It can cause eye irritation and specific target organ toxicity following single exposure, necessitating the use of personal protective equipment including safety goggles and respiratory protection in poorly ventilated areas. Industrial applications of tetraethyl silicate span several key sectors. In the coatings industry, it functions as a crosslinking agent for high-performance protective coatings, particularly those requiring exceptional durability and chemical resistance. The electronics sector utilizes this compound in the production of specialized films and as a precursor for silicon dioxide layers in semiconductor manufacturing. Additionally, it serves as an important intermediate in the synthesis of various organosilicon materials and surface treatment agents. OYSI maintains reliable supplies of tetraethyl silicate to support diverse European industrial applications, ensuring consistent quality and regulatory compliance for technical customers.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; Acute Tox. 4 *; STOT SE 3; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H332

Harmful if inhaled.

H335

May cause respiratory irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1292
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping NameTetraethylsilicat
Marine PollutantNo

Frequently Asked Questions

What is tetraethyl silicate?

Tetraethyl silicate is an organosilicon compound with the molecular formula C8H20O4Si and CAS number 78-10-4. It appears as a colorless liquid with a molecular weight of 208.33 g/mol. This silicon ester is classified as a flammable liquid with moderate toxicity and eye irritation properties. It is widely used in industrial applications as a silica source and cross-linking agent in various chemical processes.

What are the physicochemical properties of tetraethyl silicate?

Tetraethyl silicate is a colorless, transparent liquid with a characteristic mild odor. It has a molecular weight of 208.33 g/mol and is soluble in most organic solvents but hydrolyzes slowly in water to form silicic acid and ethanol. The compound exhibits moderate volatility and is classified as a Category 3 flammable liquid, indicating it has a flash point above 23°C but below 60°C.

What is tetraethyl silicate used for?

Tetraethyl silicate is primarily used as a precursor for silica production in sol-gel processes and as a cross-linking agent in silicone polymer manufacturing. It serves as a binder in investment casting, a consolidant for stone and concrete preservation, and a source of silica in the production of optical fibers and electronic components. Additionally, it is utilized in coatings, adhesives, and as a stabilizer in various industrial formulations.

How to handle tetraethyl silicate safely?

Tetraethyl silicate requires careful handling due to its flammable and toxic properties. Use appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Ensure adequate ventilation to prevent vapor accumulation and avoid ignition sources. Handle in well-ventilated areas away from heat, sparks, and flames. The substance can cause eye irritation and respiratory effects, so avoid inhalation and direct contact with skin and eyes.

How to store tetraethyl silicate correctly?

Tetraethyl silicate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources, ignition sources, and direct sunlight. Keep containers upright and ensure proper grounding to prevent static electricity buildup. Store separately from strong oxidizers, acids, and water to prevent unwanted reactions. Maintain storage temperature below 25°C and ensure fire suppression systems are available in storage areas.

What to do in case of contact with tetraethyl silicate?

In case of skin contact with tetraethyl silicate, immediately remove contaminated clothing and wash the affected area with plenty of soap and water for at least 15 minutes. For eye contact, rinse immediately with clean water for at least 15 minutes and seek medical attention. If inhaled, move to fresh air immediately. If swallowed, do not induce vomiting and seek immediate medical attention. Always consult a physician in case of exposure.

How to dispose of tetraethyl silicate appropriately?

Tetraethyl silicate must be disposed of as hazardous waste in accordance with local, national, and EU waste regulations. Do not discharge into sewers, waterways, or soil. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities can be neutralized through controlled hydrolysis, but this should only be performed by trained personnel. Always follow local environmental regulations and obtain proper waste codes for disposal documentation.

How to transport tetraethyl silicate?

Tetraethyl silicate is classified under ADR as Class 3 (flammable liquids), Packing Group III, indicating moderate danger during transport. It must be packaged in UN-approved containers with proper labeling including GHS02 and GHS07 pictograms and 'Warning' signal word. Transport vehicles must carry appropriate fire extinguishing equipment and emergency information. Drivers require ADR training and vehicles must display proper hazard identification numbers and placards.

Is tetraethyl silicate subject to specific regulations?

Tetraethyl silicate is subject to EU REACH regulation requiring registration for quantities above one tonne per year. It is classified under CLP regulation with hazard classes including Flammable Liquid 3, Acute Toxicity 4, STOT SE 3, and Eye Irritation 2. It is not currently listed as a SVHC substance. Users must comply with workplace exposure limits, safety data sheet requirements, and proper labeling according to GHS standards.

Where to buy tetraethyl silicate in Europe?

Tetraethyl silicate is available through OYSI, a specialized European distributor of technical chemicals. OYSI supplies high-quality tetraethyl silicate with proper documentation including safety data sheets, certificates of analysis, and regulatory compliance information. As a professional chemical distributor, OYSI ensures reliable supply chains and technical support for industrial customers across Europe requiring this specialized organosilicon compound for their manufacturing processes.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.