Tetraethyl silicate

C8H20O4Si

tetraethyl silicate

CAS78-10-4
GHS02 Gefahrensymbol: Entzündbar – Flamme
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
78-10-4
EC Number
201-083-8
UN Number
1292
Index Number
014-005-00-0
PubChem CID
6517

Physical-chemical properties

Molecular Formula
C8H20O4Si
Molar Mass
208.33 g/mol
IUPAC Name
tetraethyl silicate

Chemical Identifiers

InChI
InChI=1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3
InChI Key
BOTDANWDWHJENH-UHFFFAOYSA-N

Overview

Tetraethyl silicate (CAS 78-10-4) is an organosilicon compound with hydrolytic properties and excellent film-forming characteristics for industrial coating applications. This colorless liquid, also known by its IUPAC name tetraethyl silicate, represents a crucial intermediate in silicone chemistry and surface treatment technologies. With the molecular formula C8H20O4Si and a molecular weight of 208.33 g/mol, tetraethyl silicate serves as a versatile silicon source that readily undergoes hydrolysis to form silica networks. The compound's ability to crosslink and polymerize makes it particularly valuable in applications requiring durable, protective coatings. From a safety perspective, tetraethyl silicate is classified as a flammable liquid (Class 3) with moderate toxicity concerns. The substance carries GHS02 and GHS07 pictograms, indicating flammability and health hazards including acute toxicity and eye irritation. Proper handling requires adequate ventilation and personal protective equipment, as the compound can cause specific target organ toxicity following single exposure, particularly affecting the respiratory system. Industrial applications of tetraethyl silicate span multiple sectors, with primary uses in protective coatings for metals and glass substrates, where it provides excellent adhesion and corrosion resistance. The compound also serves as a precursor in sol-gel processes for producing high-purity silica materials and ceramic components. Additionally, it functions as a crosslinking agent in silicone-based formulations, offering similar versatility to other industrial solvents like 4-methoxy-4-methylpentan-2-one in specialized applications. OYSI maintains reliable supplies of tetraethyl silicate to support European industrial customers across coating, ceramics, and specialty chemical manufacturing sectors.

Safety & Classification

Warning
Classification:

Flam. Liq. 3; Acute Tox. 4 *; STOT SE 3; Eye Irrit. 2

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H226

Flammable liquid and vapour.

H332

Harmful if inhaled.

H335

May cause respiratory irritation.

H319

Causes serious eye irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1292
ADR Class3
Packing GroupIII
Tunnel CodeD/E
Proper Shipping NameTetraethylsilicat
Marine PollutantNo

Frequently Asked Questions

What is tetraethyl silicate?

Tetraethyl silicate is an organosilicon compound with the chemical formula C8H20O4Si and CAS number 78-10-4. It is a silicon ester formed by the reaction of silicic acid with ethanol. With a molecular weight of 208.33 g/mol, this compound serves as an important precursor in silica chemistry and materials science applications.

What are the physicochemical properties of tetraethyl silicate?

Tetraethyl silicate is typically a colorless liquid at room temperature with a characteristic alcoholic odor. It has limited solubility in water but is miscible with most organic solvents including alcohols and ethers. The compound is classified as a flammable liquid (Class 3) and exhibits moderate volatility under standard conditions.

What is tetraethyl silicate used for?

Tetraethyl silicate is primarily used as a precursor for silica production in sol-gel processes, ceramic manufacturing, and glass coating applications. It serves as a crosslinking agent in polymer chemistry, a binder in refractory materials, and a source of silica in the production of optical fibers and semiconductor materials.

How to handle tetraethyl silicate safely?

Tetraethyl silicate requires careful handling due to its flammable nature and potential health hazards. Wear appropriate PPE including safety goggles, gloves, and protective clothing. Work in well-ventilated areas away from ignition sources. The compound can cause eye irritation and has acute toxicity properties, requiring careful exposure control measures.

How to store tetraethyl silicate correctly?

Tetraethyl silicate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from heat sources and incompatible materials. Keep away from strong acids, bases, and oxidizing agents. Storage areas should be equipped with appropriate fire suppression systems due to its flammable liquid classification (Flam. Liq. 3).

What to do in case of contact with tetraethyl silicate?

In case of skin contact with tetraethyl silicate, immediately remove contaminated clothing and wash the affected area with plenty of water. For eye contact, rinse immediately with water for at least 15 minutes and seek medical attention due to its eye irritant properties. If inhaled, move to fresh air immediately and seek medical advice if respiratory irritation occurs.

How to dispose of tetraethyl silicate appropriately?

Tetraethyl silicate must be disposed of according to local and national hazardous waste regulations. As a flammable liquid with toxic properties, it cannot be disposed of in regular waste streams. Contact licensed hazardous waste disposal companies and follow all applicable environmental regulations for proper treatment and disposal of this chemical substance.

How to transport tetraethyl silicate?

Tetraethyl silicate is classified under ADR as Class 3 (flammable liquids), Packing Group III. Transportation requires appropriate UN-approved packaging, proper labeling with GHS02 and GHS07 pictograms, and compliance with dangerous goods transport regulations. Vehicles must be equipped with appropriate safety equipment and documentation for hazardous material transport.

Is tetraethyl silicate subject to specific regulations?

Tetraethyl silicate is subject to REACH regulation in Europe and must comply with CLP classification requirements. It carries hazard classifications including Flam. Liq. 3, Acute Tox. 4, STOT SE 3, and Eye Irrit. 2, with Warning signal word. It is not currently listed as a SVHC substance under REACH.

Where to buy tetraethyl silicate in Europe?

Tetraethyl silicate is available through OYSI, a European distributor of technical chemicals. As an established chemical supplier, OYSI can provide this organosilicon compound to industrial customers across Europe. Contact OYSI directly for availability, specifications, and ordering information for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.