Sodium Hydroxide

HNaO

sodium hydroxide

CAS1310-73-2
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
1310-73-2
EC Number
215-185-5
UN Number
1823
Index Number
011-001-00-0
PubChem CID
14798

Physical-chemical properties

Molecular Formula
HNaO
Molar Mass
40.00 g/mol
IUPAC Name
sodium hydroxide

Chemical Identifiers

InChI
InChI=1S/Na.H2O/h;1H2/q+1;/p-1
InChI Key
HEMHJVSKTPXQMS-UHFFFAOYSA-M

Overview

Sodium Hydroxide (CAS 1310-73-2) is a highly caustic inorganic base with strong alkaline properties and excellent solubility in water. Sodium hydroxide, commonly known as caustic soda or lye, represents one of the most important industrial chemicals in modern manufacturing processes. This white, crystalline solid demonstrates exceptional reactivity and serves as a fundamental building block across numerous industrial applications. With its molecular formula HNaO and molecular weight of 39.997 g/mol, sodium hydroxide exhibits powerful alkaline characteristics that make it indispensable for pH adjustment, chemical synthesis, and various purification processes. The substance presents significant safety considerations due to its highly corrosive nature, classified under Skin Corr. 1A with the GHS05 pictogram indicating corrosive properties. When handling sodium hydroxide, proper protective equipment is essential as it can cause severe burns upon contact with skin or eyes. Its ADR Class 8 classification reflects its corrosive transport requirements, necessitating specialized handling protocols throughout the supply chain. Industrial applications for sodium hydroxide span multiple sectors, including pulp and paper manufacturing where it facilitates lignin removal, chemical processing for soap and detergent production, and water treatment facilities for pH control. Unlike other strong chemicals such as sulfuric acid, sodium hydroxide provides alkaline rather than acidic properties, making it crucial for neutralization reactions and basic chemical processes. The compound's hygroscopic nature requires careful storage in dry conditions to prevent moisture absorption and maintain product integrity. Its exothermic dissolution in water demands controlled mixing procedures to ensure operator safety and process efficiency. OYSI supplies high-quality sodium hydroxide to meet diverse industrial requirements across European markets, supporting customers with reliable technical-grade chemical solutions.

Safety & Classification

Danger
Classification:

Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1823
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameNatriumhydroxid, fest
Marine PollutantNo

Frequently Asked Questions

What is Sodium Hydroxide?

Sodium Hydroxide is a highly corrosive inorganic compound with the chemical formula NaOH and CAS number 1310-73-2. This strong alkaline substance has a molecular weight of 39.997 g/mol and appears as white pellets, flakes, or powder. It is classified as Skin Corr. 1A under GHS regulations, indicating its severe corrosive properties to skin and eyes. Sodium hydroxide is one of the most important industrial chemicals, widely used in manufacturing processes across various industries.

What are the physicochemical properties of Sodium Hydroxide?

Sodium Hydroxide is a white, odorless solid at room temperature that readily absorbs moisture and carbon dioxide from air. It is highly soluble in water, generating significant heat during dissolution. The substance has a melting point of 318°C and is extremely hygroscopic, meaning it attracts water vapor from the atmosphere. When dissolved, it forms a highly alkaline solution with a pH greater than 13, making it one of the strongest bases commonly used in industry.

What is Sodium Hydroxide used for?

Sodium Hydroxide serves multiple industrial applications including pulp and paper manufacturing, soap and detergent production, and chemical synthesis. It is extensively used in water treatment for pH adjustment, in food processing for cleaning and sanitization, and in petroleum refining. The chemical industry utilizes it for producing various chemicals, while the textile industry employs it for fiber processing. It also plays a crucial role in aluminum production and metal cleaning applications.

How to handle Sodium Hydroxide safely?

Sodium Hydroxide requires careful handling due to its highly corrosive nature classified as Skin Corr. 1A. Essential personal protective equipment includes chemical-resistant gloves, safety goggles, face shields, and protective clothing. Work in well-ventilated areas to avoid inhalation of dust or vapors. Never add water directly to solid sodium hydroxide as it generates intense heat. Always add the solid slowly to water while stirring. Keep emergency eyewash stations and safety showers readily accessible during handling operations.

How to store Sodium Hydroxide correctly?

Sodium Hydroxide must be stored in a cool, dry place away from moisture, acids, and incompatible materials. Use tightly sealed, corrosion-resistant containers made of materials like polyethylene or stainless steel. Avoid storage in aluminum, zinc, or tin containers as they react with the substance. Keep away from organic materials, oxidizers, and acids to prevent dangerous reactions. Storage areas should be well-ventilated and equipped with appropriate spill containment measures and emergency response equipment.

What to do in case of contact with Sodium Hydroxide?

Sodium Hydroxide contact requires immediate emergency response due to its corrosive classification. For skin contact, immediately remove contaminated clothing and flush affected area with large amounts of water for at least 20 minutes. For eye contact, rinse continuously with water for at least 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. Never induce vomiting if ingested - rinse mouth and drink water. Seek immediate medical attention for all exposure incidents as burns may not be immediately apparent.

How to dispose of Sodium Hydroxide appropriately?

Sodium Hydroxide disposal must comply with local and national hazardous waste regulations. Small quantities can be carefully neutralized with dilute acid under controlled conditions by qualified personnel, then disposed of according to local wastewater regulations. Larger quantities require disposal through licensed hazardous waste contractors. Never dispose of in regular trash or pour down drains without proper neutralization and authorization. Contaminated packaging must also be treated as hazardous waste and disposed of accordingly through appropriate channels.

How to transport Sodium Hydroxide?

Sodium Hydroxide is classified as ADR Class 8 (corrosive substances) Packing Group II for transportation. It requires appropriate UN specification packaging marked with proper shipping names and hazard labels including the GHS05 corrosion pictogram. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require ADR training for dangerous goods transport. Packages must be properly secured to prevent damage during transit, and emergency response information must be readily available throughout the transportation process.

Is Sodium Hydroxide subject to specific regulations?

Sodium Hydroxide is subject to comprehensive chemical regulations including REACH registration requirements in Europe and CLP classification as a corrosive substance with the danger signal word. It falls under various occupational safety regulations requiring proper workplace controls and employee training. The substance is not currently listed as an SVHC (Substance of Very High Concern) but must comply with standard industrial chemical handling regulations, environmental discharge limits, and transportation safety requirements across different jurisdictions.

Where to buy Sodium Hydroxide in Europe?

Sodium Hydroxide is readily available through OYSI, a leading European distributor of industrial chemicals. OYSI provides reliable supply of quality sodium hydroxide with proper documentation, safety data sheets, and regulatory compliance support across European markets. As an established chemical distributor, OYSI ensures product traceability, appropriate packaging, and technical support for industrial customers. Contact OYSI directly for specific grades, quantities, packaging options, and delivery arrangements to meet your industrial sodium hydroxide requirements.

Digital Product Passport available

EU DPP

A Digital Product Passport (DPP) compliant with EU regulations is available for this substance. The passport contains complete information on composition, safety, and sustainability.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.