Sodium Hydroxide

HNaO

sodium hydroxide

CAS1310-73-2
GHS05 Gefahrensymbol: Ätzend – Ätzwirkung
Danger

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Identification

CAS Number
1310-73-2
EC Number
215-185-5
UN Number
1823
Index Number
011-001-00-0
PubChem CID
14798

Physical-chemical properties

Molecular Formula
HNaO
Molar Mass
40.00 g/mol
IUPAC Name
sodium hydroxide

Chemical Identifiers

InChI
InChI=1S/Na.H2O/h;1H2/q+1;/p-1
InChI Key
HEMHJVSKTPXQMS-UHFFFAOYSA-M

Overview

Sodium Hydroxide (CAS 1310-73-2) is a highly caustic inorganic compound with strong alkaline properties and exceptional solubility in water. This white, crystalline solid represents one of the most important industrial chemicals worldwide, serving as a fundamental building block in numerous manufacturing processes. Also known as caustic soda or lye, sodium hydroxide demonstrates remarkable reactivity with acids, forming sodium salts and water through neutralization reactions. The compound exhibits hygroscopic characteristics, readily absorbing moisture and carbon dioxide from ambient air, which necessitates careful storage in sealed containers. The safety profile of sodium hydroxide demands strict handling protocols due to its corrosive nature. Classified under GHS05 with a "Danger" signal word, this substance can cause severe chemical burns upon contact with skin or eyes. Its ADR Class 8 designation reflects its corrosive transport requirements, emphasizing the need for specialized packaging and documentation during shipping. Industrial applications span diverse sectors, with pulp and paper manufacturing representing a primary consumption area where sodium hydroxide facilitates lignin removal during wood processing. Chemical synthesis operations extensively utilize this compound for pH adjustment and as a reactant in producing various sodium-based chemicals. The textile industry employs sodium hydroxide in mercerization processes, enhancing cotton fiber strength and dye absorption properties. Unlike sulfuric acid, which serves as a strong acid counterpart in many neutralization processes, sodium hydroxide provides the alkaline component essential for maintaining proper chemical equilibrium in industrial applications. OYSI maintains reliable supply chains for technical-grade sodium hydroxide, ensuring consistent availability for European industrial customers requiring this essential chemical intermediate.

Safety & Classification

Danger
Classification:

Skin Corr. 1A

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H314

Causes severe skin burns and eye damage.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Skin Contact

Harmful

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Harmful

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1823
ADR Class8
Packing GroupII
Tunnel CodeE
Proper Shipping NameNatriumhydroxid, fest
Marine PollutantNo

Frequently Asked Questions

What is Sodium Hydroxide?

Sodium Hydroxide is a highly caustic metallic base with the chemical formula HNaO and CAS number 1310-73-2. It has a molecular weight of 39.997 g/mol and is classified as a corrosive substance (Skin Corr. 1A). This inorganic compound is one of the most widely used industrial chemicals, known for its strong alkaline properties and ability to neutralize acids completely.

What are the physicochemical properties of Sodium Hydroxide?

Sodium Hydroxide is a white, odorless solid at room temperature that appears as pellets, flakes, or powder. It is highly hygroscopic, readily absorbing moisture from air, and is extremely soluble in water, generating significant heat during dissolution. The substance is also soluble in alcohols and glycerol but insoluble in organic solvents like acetone and ether.

What is Sodium Hydroxide used for?

Sodium Hydroxide is primarily used in chemical manufacturing, pulp and paper production, soap and detergent manufacturing, and water treatment processes. It serves as a key ingredient in aluminum production, textile processing, food processing (as a cleaning agent), and petroleum refining. Additionally, it's essential for pH adjustment in various industrial processes and as a drain cleaner in maintenance applications.

How to handle Sodium Hydroxide safely?

Sodium Hydroxide requires extreme caution during handling due to its corrosive nature (Skin Corr. 1A classification). Essential PPE includes chemical-resistant gloves, safety goggles, face shields, and protective clothing. Work in well-ventilated areas, avoid contact with skin and eyes, and never add water directly to concentrated sodium hydroxide. Always have eyewash stations and safety showers readily accessible in work areas.

How to store Sodium Hydroxide correctly?

Sodium Hydroxide must be stored in a cool, dry place in tightly sealed containers to prevent moisture absorption. Use corrosion-resistant containers made of steel or appropriate plastics. Keep away from acids, metals like aluminum and zinc, and organic materials. Ensure adequate ventilation in storage areas and maintain temperatures below 40°C to prevent decomposition and container damage.

What to do in case of contact with Sodium Hydroxide?

Sodium Hydroxide contact requires immediate action due to its corrosive properties. For skin contact, immediately flush with copious amounts of water for at least 20 minutes while removing contaminated clothing. For eye contact, rinse continuously with clean water for 15-20 minutes. If inhaled, move to fresh air immediately. Seek medical attention promptly in all cases of exposure.

How to dispose of Sodium Hydroxide appropriately?

Sodium Hydroxide disposal must comply with local environmental regulations and waste management laws. Small quantities can be neutralized carefully with dilute acid under controlled conditions before disposal. Large quantities require professional hazardous waste disposal services. Never discharge untreated sodium hydroxide into sewers or waterways. Contact licensed waste management companies for proper disposal procedures and documentation.

How to transport Sodium Hydroxide?

Sodium Hydroxide is classified as ADR Class 8 (corrosive substances) with Packing Group II, indicating moderate danger level. Transportation requires appropriate corrosive material placarding, proper packaging in UN-approved containers, and compliance with dangerous goods regulations. Drivers must possess ADR certification, and vehicles need appropriate emergency equipment. Shipping documentation must include proper shipping names and hazard classifications.

Is Sodium Hydroxide subject to specific regulations?

Sodium Hydroxide is regulated under CLP Regulation with hazard pictogram GHS05 and signal word 'Danger'. It requires safety data sheets under REACH regulation but is not classified as an SVHC (Substance of Very High Concern). Industrial users must comply with workplace safety regulations, proper labeling requirements, and employee training protocols for corrosive substance handling.

Where to buy Sodium Hydroxide in Europe?

Sodium Hydroxide is available through OYSI, a specialized European chemical distributor offering professional-grade industrial chemicals. OYSI provides comprehensive technical support, proper documentation, and reliable supply chains across European markets. As a professional distributor, OYSI ensures compliance with all regulatory requirements and provides detailed safety data sheets and certificates of analysis for industrial customers.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.