Silylsilane

H6Si2

silylsilane

CAS1590-87-0

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Identification

CAS Number
1590-87-0
EC Number
216-466-5
UN Number
3553
PubChem CID
74123

Physical-chemical properties

Molecular Formula
H6Si2
Molar Mass
62.22 g/mol
IUPAC Name
silylsilane

Chemical Identifiers

InChI
InChI=1S/H6Si2/c1-2/h1-2H3
InChI Key
PZPGRFITIJYNEJ-UHFFFAOYSA-N

Overview

Silylsilane (CAS 1590-87-0) is an inorganic silicon hydride compound with the molecular formula H6Si2 and exceptional reducing properties in chemical synthesis. This specialized silicon-based compound represents a unique class of inorganic hydrides that has gained significant attention in advanced chemical manufacturing and research applications. With a molecular weight of 62.22 g/mol, silylsilane consists of two silicon atoms connected by silicon-hydrogen bonds, making it a valuable reagent in organometallic chemistry and materials science. The compound's structure and reactivity profile distinguish it from simpler inorganic compounds like nitrous oxide, though both serve important roles in specialized chemical processes. Silylsilane exhibits remarkable stability under controlled conditions while maintaining high reactivity toward various organic and inorganic substrates. Its classification under ADR Class 2 indicates specific handling requirements related to gas transport regulations, necessitating appropriate storage and handling protocols in industrial settings. The compound's unique silicon-silicon bonding arrangement provides distinctive chemical properties that make it particularly valuable for selective reduction reactions and as a silicon source in advanced materials synthesis. Key industrial applications include its use as a reducing agent in pharmaceutical intermediate synthesis, as a precursor in semiconductor manufacturing processes, and in the production of specialized silicon-containing polymers. The compound also finds application in research laboratories for the development of novel organometallic catalysts and in surface modification technologies where controlled silicon deposition is required. OYSI maintains reliable supply chains for silylsilane to support diverse industrial and research applications across European markets, ensuring consistent availability for specialized chemical manufacturing requirements.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number3553
ADR Class2
Packing Group
Tunnel CodeB/D
Proper Shipping NameDisilan, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is silylsilane?

Silylsilane is an inorganic silicon compound with the molecular formula H6Si2 and CAS number 1590-87-0. This compound consists of two silicon atoms connected by a silicon-silicon bond, with each silicon atom bearing hydrogen substituents. With a molecular weight of 62.22 g/mol, silylsilane belongs to the family of silicon hydrides and represents one of the simplest disilanes. It is characterized by its reactive Si-H bonds and Si-Si backbone structure.

What are the physicochemical properties of silylsilane?

Silylsilane is a colorless gas at room temperature with high reactivity due to its Si-H bonds. The compound exhibits spontaneous flammability in air and is highly moisture-sensitive, reacting readily with water and oxygen. It has a low boiling point typical of small silicon hydrides and demonstrates high volatility. The Si-Si bond length and Si-H bond characteristics make it an important precursor in silicon chemistry applications.

What is silylsilane used for?

Silylsilane serves primarily as a chemical precursor in semiconductor manufacturing and silicon-based material synthesis. It is utilized in chemical vapor deposition (CVD) processes for producing high-purity silicon films and coatings. The compound finds applications in the synthesis of more complex organosilicon compounds and as a reducing agent in specialized chemical reactions. Its unique Si-Si bonding makes it valuable for research into silicon cluster chemistry and advanced materials development.

How to handle silylsilane safely?

Silylsilane requires careful handling due to its pyrophoric nature and reactivity with moisture. Work must be conducted in inert atmosphere using nitrogen or argon, with all equipment thoroughly dried beforehand. Personal protective equipment should include chemical-resistant gloves, safety goggles, and appropriate respiratory protection. Avoid any contact with air, water, or oxidizing materials. All manipulations should occur in well-ventilated areas or under controlled atmospheric conditions with proper gas handling equipment.

How to store silylsilane correctly?

Silylsilane must be stored under inert gas atmosphere in sealed, moisture-free containers at controlled temperatures. Storage areas should be dry, well-ventilated, and protected from heat sources, sparks, and oxidizing materials. The compound should be kept away from water, alcohols, and any protic solvents. Specialized gas storage equipment with pressure regulation may be required. Regular monitoring of storage conditions and container integrity is essential to prevent decomposition or hazardous reactions.

What to do in case of contact with silylsilane?

Silylsilane exposure requires immediate action due to its reactive nature. For skin contact, remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of eye contact, rinse immediately with water and seek medical attention. If inhaled, move the person to fresh air and provide respiratory support if needed. Due to the compound's pyrophoric properties, extinguish any fires with appropriate dry chemical extinguishers, never water.

How to dispose of silylsilane appropriately?

Silylsilane disposal requires specialized procedures due to its reactive and potentially hazardous nature. Small quantities can be carefully hydrolyzed under controlled conditions with appropriate safety measures. Larger amounts should be handled by licensed hazardous waste disposal companies familiar with reactive silicon compounds. Never dispose of silylsilane in regular waste streams or pour into drains. Contact local environmental authorities for specific disposal requirements and approved facilities in your region.

How to transport silylsilane?

Silylsilane is classified under ADR Class 2 (gases) for transportation purposes, requiring specialized handling during shipping. The compound must be transported in approved pressure vessels or gas cylinders designed for reactive gases. Vehicles must be properly placarded and drivers trained in hazardous materials handling. Due to its pyrophoric nature, additional precautions beyond standard gas transport may be required. Consult current ADR regulations and work with experienced hazardous materials transporters.

Is silylsilane subject to specific regulations?

Silylsilane is subject to various chemical safety regulations including REACH registration requirements in Europe and classification under CLP regulations. While not currently listed as a SVHC (Substance of Very High Concern), it falls under general chemical safety legislation due to its reactive properties. Manufacturers and importers must comply with safety data sheet requirements and proper labeling. Industrial users should ensure compliance with workplace safety regulations and local environmental protection standards.

Where to buy silylsilane in Europe?

Silylsilane is available through OYSI, a European distributor specializing in technical chemicals and advanced materials. OYSI provides reliable supply chains for research institutions, semiconductor manufacturers, and specialized chemical companies requiring high-purity silylsilane. As an established chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for European customers. Contact OYSI directly for availability, specifications, and delivery options suited to your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.