Silylsilane
H6Si2
silylsilane
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Identification
- CAS Number
- 1590-87-0
- EC Number
- 216-466-5
- UN Number
- 3553
- PubChem CID
- 74123
Physical-chemical properties
- Molecular Formula
- H6Si2
- Molar Mass
- 62.22 g/mol
- IUPAC Name
- silylsilane
Chemical Identifiers
- InChI
- InChI=1S/H6Si2/c1-2/h1-2H3
- InChI Key
- PZPGRFITIJYNEJ-UHFFFAOYSA-N
Overview
Silylsilane (CAS 1590-87-0) is a disilicon hydride compound with the molecular formula H6Si2 and exceptional reactivity in silicon chemistry applications. This specialized silicon-hydrogen compound represents one of the simplest polysilanes, featuring a direct silicon-silicon bond with terminal hydrogen atoms. With a molecular weight of 62.22 g/mol, silylsilane exhibits unique chemical properties that make it valuable in advanced materials synthesis and semiconductor applications. The compound's structure consists of two silicon atoms connected by a covalent bond, each bearing three hydrogen atoms, creating a highly reactive precursor material. As a member of the polysilane family, silylsilane demonstrates significantly different reactivity patterns compared to simpler hydrides like bromane or other gaseous compounds. Its classification under ADR Class 2 reflects its gaseous nature and associated handling requirements. The compound's reactivity stems from the relatively weak Si-Si bond and the presence of multiple Si-H bonds, making it an excellent source of silicon in various chemical processes. Silylsilane finds primary applications in semiconductor manufacturing as a precursor for silicon thin film deposition, particularly in chemical vapor deposition (CVD) processes. The compound also serves as an important intermediate in organosilicon synthesis, enabling the production of more complex silicon-containing materials. Additionally, it functions as a reducing agent in specialized chemical reactions where controlled silicon incorporation is required. The controlled decomposition of silylsilane at elevated temperatures produces high-purity silicon films, making it valuable for photovoltaic cell production and electronic device fabrication. Its unique properties also make it suitable for research applications in materials science and nanotechnology. OYSI provides silylsilane to European industrial customers requiring high-purity silicon precursors for advanced manufacturing applications.
Safety & Classification
No Hazard Classification
This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.
Transport (ADR)
| UN Number | 3553 |
| ADR Class | 2 |
| Packing Group | |
| Tunnel Code | B/D |
| Proper Shipping Name | Disilan, unter Druck verflüssigt |
| Marine Pollutant | No |
Frequently Asked Questions
What is silylsilane?
Silylsilane is an inorganic silicon compound with the chemical formula H6Si2 and CAS number 1590-87-0. This disilane molecule consists of two silicon atoms connected by a silicon-silicon bond, with each silicon atom bonded to hydrogen atoms. With a molecular weight of 62.22 g/mol, silylsilane belongs to the family of silicon hydrides and serves as an important precursor in silicon chemistry and materials science applications.
What are the physicochemical properties of silylsilane?
Silylsilane is a colorless gas at room temperature with high reactivity due to its Si-H bonds. The compound is highly sensitive to air and moisture, readily decomposing in the presence of water or oxygen. It exhibits low boiling and melting points typical of small silicon hydrides. Silylsilane is insoluble in water due to its hydrolytic instability but may be soluble in inert organic solvents under controlled conditions.
What is silylsilane used for?
Silylsilane is primarily used as a precursor in chemical vapor deposition (CVD) processes for producing high-purity silicon films and coatings. It serves as a reducing agent in semiconductor manufacturing and as an intermediate in the synthesis of organosilicon compounds. The compound is also utilized in research applications for developing advanced silicon-based materials, thin films, and in the production of specialized silicon-containing polymers and ceramics.
How to handle silylsilane safely?
Silylsilane requires careful handling due to its reactive nature and potential for spontaneous ignition in air. Personal protective equipment should include safety goggles, chemical-resistant gloves, and protective clothing. Work should be conducted in well-ventilated areas or under inert atmosphere conditions. Avoid contact with water, oxygen, and ignition sources. Use appropriate gas handling equipment and ensure proper grounding to prevent static electricity buildup during transfer operations.
How to store silylsilane correctly?
Silylsilane must be stored in sealed containers under inert atmosphere conditions, typically nitrogen or argon, to prevent decomposition. Storage areas should be cool, dry, and well-ventilated, away from heat sources and incompatible materials such as oxidizers, water, and acids. Containers should be made of compatible materials and regularly inspected for leaks. Storage facilities must comply with local regulations for handling reactive gases and pyrophoric substances.
What to do in case of contact with silylsilane?
Immediate evacuation from the exposure area is essential in case of silylsilane contact. For skin contact, remove contaminated clothing and flush affected areas with plenty of water. In case of inhalation, move the person to fresh air and seek medical attention if breathing difficulties occur. Eye contact requires immediate flushing with water for at least 15 minutes. Always seek professional medical advice and inform healthcare providers about the specific chemical involved.
How to dispose of silylsilane properly?
Silylsilane disposal must comply with local and national hazardous waste regulations due to its reactive nature. The compound should never be disposed of in regular waste streams or sewers. Controlled decomposition under inert conditions by qualified waste management companies is typically required. Small quantities may be carefully neutralized through controlled hydrolysis, but this should only be performed by trained professionals with appropriate safety equipment and containment measures.
How to transport silylsilane?
Silylsilane is classified under ADR Class 2 as a compressed gas, requiring specialized transportation procedures. The compound must be transported in appropriate pressure vessels designed for reactive gases, with proper labeling and documentation. Vehicles must comply with dangerous goods transportation regulations, including proper ventilation and emergency equipment. Only certified carriers experienced in handling reactive chemicals should transport silylsilane, following all applicable international transportation codes.
Is silylsilane subject to specific regulations?
Silylsilane is regulated under various chemical safety frameworks including REACH registration requirements for commercial use in Europe. The compound is not currently classified as a Substance of Very High Concern (SVHC), but its reactive nature subjects it to standard industrial chemical handling regulations. Users must comply with CLP classification requirements and maintain appropriate safety data sheets. Local workplace safety regulations may impose additional requirements for handling reactive silicon compounds.
Where to buy silylsilane in Europe?
Silylsilane is available through OYSI, a specialized European distributor of technical chemicals serving industrial and research customers. As a professional chemical distributor, OYSI can provide silylsilane with appropriate documentation, safety data sheets, and technical support for industrial applications. Contact OYSI directly for availability, specifications, and delivery options tailored to your specific requirements. Professional handling and specialized packaging ensure safe delivery throughout Europe.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.