Dipotassium;sulfonatooxy sulfate

K2O8S2

dipotassium;sulfonatooxy sulfate

CAS7727-21-1
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
Danger

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Identification

CAS Number
7727-21-1
EC Number
231-781-8
UN Number
1492
Index Number
016-061-00-1
PubChem CID
24412

Physical-chemical properties

Molecular Formula
K2O8S2
Molar Mass
270.33 g/mol
IUPAC Name
dipotassium;sulfonatooxy sulfate

Chemical Identifiers

InChI
InChI=1S/2K.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h;;(H,1,2,3)(H,4,5,6)/q2*+1;/p-2
InChI Key
USHAGKDGDHPEEY-UHFFFAOYSA-L

Overview

Dipotassium sulfonatooxy sulfate (CAS 7727-21-1) is an inorganic oxidizing compound with strong oxidative properties and notable chemical reactivity. This white crystalline solid, with molecular formula K2O8S2 and molecular weight 270.33 g/mol, belongs to the family of persulfate compounds widely utilized in industrial applications requiring controlled oxidation processes. As a Class 5.1 oxidizing substance under ADR classification, dipotassium sulfonatooxy sulfate presents significant safety considerations that must be carefully managed in industrial settings. The compound carries multiple hazard classifications including oxidizing solid category 3, acute toxicity 4, and respiratory sensitization category 1, requiring appropriate GHS03, GHS07, and GHS08 pictograms with the signal word "Danger." Its oxidizing nature makes it incompatible with reducing agents, organic materials, and combustible substances, necessitating proper segregation during storage and handling. The substance exhibits skin and eye irritation properties alongside respiratory and skin sensitization potential, making personal protective equipment essential during handling operations. Its classification as STOT SE 3 indicates specific target organ toxicity concerns that require adequate ventilation and exposure control measures in workplace environments. Industrial applications of dipotassium sulfonatooxy sulfate primarily focus on its oxidizing capabilities in chemical synthesis processes, polymer initiation systems, and specialized cleaning formulations. Like other oxidizing compounds such as potassium permanganate, it serves as an effective oxidizing agent in various chemical transformations. The compound also finds use in analytical chemistry applications and certain surface treatment processes where controlled oxidation is required. OYSI maintains reliable supply chains for dipotassium sulfonatooxy sulfate, ensuring consistent availability for European industrial customers requiring this specialized oxidizing compound.

Safety & Classification

Danger
Classification:

Ox. Sol. 3; Acute Tox. 4 *; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; Resp. Sens. 1; Skin Sens. 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H272

May intensify fire; oxidiser.

H302

Harmful if swallowed.

H335

May cause respiratory irritation.

H315

Causes skin irritation.

H319

Causes serious eye irritation.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

Eye Contact

Irritant

Measures if substance gets into the eyes

First Aid Actions

  • +P305IF IN EYES:
  • +P351Rinse cautiously with water for several minutes.
  • +P338Remove contact lenses, if present and easy to do. Continue rinsing.
  • +P313Get medical advice/attention.

Related hazard statements:

Ingestion

Harmful

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1492
ADR Class5.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameKaliumpersulfat
Marine PollutantNo

Frequently Asked Questions

What is dipotassium sulfonatooxy sulfate?

Dipotassium sulfonatooxy sulfate is an inorganic chemical compound with the molecular formula K2O8S2 and CAS number 7727-21-1. This white crystalline substance has a molecular weight of 270.33 g/mol and belongs to the persulfate family. It serves as a powerful oxidizing agent due to its chemical structure containing sulfonate and sulfate groups. The compound is classified as hazardous with multiple risk categories including oxidizing properties, acute toxicity, and potential for causing skin and respiratory sensitization.

What are the physicochemical properties of dipotassium sulfonatooxy sulfate?

Dipotassium sulfonatooxy sulfate appears as a white crystalline solid at room temperature with high water solubility. The compound is odorless and demonstrates strong oxidizing properties due to its persulfate structure. It has a molecular weight of 270.33 g/mol and maintains stability under normal storage conditions. The substance readily dissolves in water, forming clear solutions that retain the oxidizing characteristics. Its crystalline nature allows for easy handling in powder form, though proper safety measures must be observed due to its reactive properties.

What is dipotassium sulfonatooxy sulfate used for?

Dipotassium sulfonatooxy sulfate serves primarily as a strong oxidizing agent in various industrial applications. It is commonly used in polymer chemistry as a radical initiator for emulsion polymerization processes, particularly in the production of synthetic rubbers and plastics. The compound also finds application in analytical chemistry, metal cleaning processes, and as a bleaching agent in certain industrial formulations. Its oxidizing properties make it valuable in water treatment applications and chemical synthesis where controlled oxidation reactions are required.

How to handle dipotassium sulfonatooxy sulfate safely?

Dipotassium sulfonatooxy sulfate requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and respiratory protection. Work should be conducted in well-ventilated areas or under fume extraction due to respiratory sensitization risks (Resp. Sens. 1). Avoid direct skin contact as the substance can cause skin irritation and sensitization. Use non-sparking tools and avoid contact with combustible materials due to its oxidizing properties (Ox. Sol. 3). Emergency eyewash stations and safety showers should be readily accessible.

How to store dipotassium sulfonatooxy sulfate correctly?

Dipotassium sulfonatooxy sulfate must be stored in a cool, dry, well-ventilated area away from heat sources, sparks, and open flames. Keep containers tightly sealed and separate from combustible materials, reducing agents, and organic compounds due to its oxidizing properties (Class 5.1). Store in original containers made of compatible materials, avoiding metal containers that may react with the oxidizing agent. Maintain storage temperature below 30°C and protect from moisture to prevent decomposition. Ensure storage areas have appropriate fire suppression systems suitable for oxidizing agents.

What to do in case of contact with dipotassium sulfonatooxy sulfate?

Skin contact with dipotassium sulfonatooxy sulfate requires immediate removal of contaminated clothing and thorough rinsing with plenty of water for at least 15 minutes. For eye contact, flush immediately with clean water for 15-20 minutes and seek medical attention due to eye irritation potential. If inhaled, move the person to fresh air and monitor for respiratory distress given its respiratory sensitization properties. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a poison control center or physician for specific medical advice.

How to dispose of dipotassium sulfonatooxy sulfate appropriately?

Dipotassium sulfonatooxy sulfate disposal must comply with local, national, and EU waste regulations as hazardous chemical waste. The substance cannot be disposed of in regular waste streams due to its oxidizing properties and health hazards. Contact licensed hazardous waste disposal companies for proper collection and treatment. Small quantities may be neutralized through controlled chemical treatment by qualified professionals. Containers must be completely emptied and decontaminated before disposal. Always consult local environmental authorities for specific disposal requirements and approved disposal facilities in your region.

How to transport dipotassium sulfonatooxy sulfate?

Dipotassium sulfonatooxy sulfate is classified under ADR Class 5.1 (Oxidizing Substances), Packing Group III, requiring specific transport regulations compliance. Packages must bear appropriate hazard labels including oxidizing agent markings and proper shipping names. Use approved packaging materials resistant to oxidizing agents and ensure containers are properly sealed and labeled. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require ADR training certification for Class 5.1 substances. Avoid transport with incompatible materials, particularly combustible substances and reducing agents, and ensure adequate ventilation during transport.

Is dipotassium sulfonatooxy sulfate subject to specific regulations?

Dipotassium sulfonatooxy sulfate is subject to comprehensive EU chemical regulations including REACH registration requirements and CLP classification obligations. The substance is classified with multiple hazard categories requiring proper labeling with GHS pictograms (GHS03, GHS07, GHS08) and the signal word 'Danger'. It is not currently listed as an SVHC (Substance of Very High Concern). Workplace exposure limits may apply under occupational health regulations. Industrial users must comply with safety data sheet requirements and may need specific risk assessments for respiratory sensitization and oxidizing properties.

Where to buy dipotassium sulfonatooxy sulfate in Europe?

Dipotassium sulfonatooxy sulfate is available through OYSI, a specialized European distributor of technical chemicals serving industrial customers across Europe. OYSI provides this oxidizing agent with complete regulatory documentation including safety data sheets and certificates of analysis. As an established chemical distributor, OYSI ensures compliance with European chemical regulations and offers technical support for industrial applications. Contact OYSI directly for pricing, availability, and specific packaging options suitable for your industrial requirements. Professional chemical suppliers like OYSI maintain proper storage and handling protocols for hazardous oxidizing agents.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.