Potassium nitrite
KNO2
potassium nitrite
Consulting for Potassium nitrite
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Identification
- CAS Number
- 7758-09-0
- EC Number
- 231-832-4
- UN Number
- 1488
- Index Number
- 007-011-00-X
- PubChem CID
- 516910
Physical-chemical properties
- Molecular Formula
- KNO2
- Molar Mass
- 85.10 g/mol
- IUPAC Name
- potassium nitrite
Chemical Identifiers
- InChI
- InChI=1S/K.HNO2/c;2-1-3/h;(H,2,3)/q+1;/p-1
- InChI Key
- BXNHTSHTPBPRFX-UHFFFAOYSA-M
Overview
Potassium nitrite (CAS 7758-09-0) is an inorganic salt compound with strong oxidizing properties and significant industrial applications. This white crystalline substance serves as a crucial intermediate in various chemical processes and industrial applications. As a member of the nitrite family, potassium nitrite shares chemical characteristics with sodium nitrite, though it offers distinct advantages in specific applications due to the potassium ion's unique properties. The compound exhibits high solubility in water and demonstrates powerful oxidizing capabilities, making it valuable across multiple industrial sectors. From a safety perspective, potassium nitrite requires careful handling due to its classification as an oxidizing solid (Category 2) and acute toxicity (Category 3). The substance carries the danger signal word and displays GHS pictograms for oxidizing agents, acute toxicity, and environmental hazards. Its ADR classification as Class 5.1 reflects its oxidizing nature, requiring specific transport and storage protocols to prevent incompatible material reactions. Key industrial applications include its use as a corrosion inhibitor in metalworking fluids and industrial cooling systems, where it effectively protects metal surfaces from oxidation. The compound also serves as an intermediate in pharmaceutical synthesis and finds application in specialty chemical manufacturing processes. In some industrial processes, it functions as a more selective alternative to other oxidizing agents, providing controlled oxidation reactions. The environmental classification requires responsible handling to minimize aquatic impact, emphasizing the importance of proper waste management and containment procedures. OYSI provides high-quality potassium nitrite to support diverse industrial applications across European markets, ensuring reliable supply for technical and industrial customers.
Safety & Classification
Ox. Sol. 2; Acute Tox. 3 *; Aquatic Acute 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1488 |
| ADR Class | 5.1 |
| Packing Group | II |
| Tunnel Code | E |
| Proper Shipping Name | Kaliumnitrit |
| Marine Pollutant | No |
Frequently Asked Questions
What is potassium nitrite?
Potassium nitrite is an inorganic salt with the chemical formula KNO2 and CAS number 7758-09-0. It has a molecular weight of 85.104 g/mol and appears as white or slightly yellowish crystalline powder. This compound is classified as a strong oxidizing agent and is considered hazardous due to its acute toxicity and environmental impact on aquatic life. It readily dissolves in water and is commonly used in various industrial applications.
What are the physicochemical properties of potassium nitrite?
Potassium nitrite is a white to slightly yellowish crystalline solid that is highly soluble in water. It has a molecular weight of 85.104 g/mol and is odorless. The compound is hygroscopic, meaning it readily absorbs moisture from air. It decomposes when heated, releasing toxic nitrogen oxides. As an oxidizing salt, it can react vigorously with reducing agents and organic materials, making it potentially dangerous when improperly handled.
What is potassium nitrite used for?
Potassium nitrite is primarily used as a food preservative in meat processing, where it prevents bacterial growth and maintains color. It serves as a corrosion inhibitor in industrial cooling systems and concrete applications. The compound is also utilized in chemical synthesis as an oxidizing agent and in the production of dyes and pharmaceuticals. Additionally, it finds applications in heat transfer systems and as a reagent in analytical chemistry laboratories.
How to handle potassium nitrite safely?
Potassium nitrite requires careful handling due to its acute toxicity and oxidizing properties. Always wear appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas to avoid inhalation of dust. Avoid contact with skin, eyes, and clothing. Keep away from heat sources, combustible materials, and reducing agents. Use non-sparking tools and ensure proper grounding to prevent static electricity buildup during handling operations.
How to store potassium nitrite correctly?
Potassium nitrite must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and separate from combustible materials, reducing agents, and acids. Store in original containers made of compatible materials. Maintain storage temperature below 25°C and protect from moisture due to its hygroscopic nature. Ensure adequate segregation from incompatible substances and implement proper inventory rotation using first-in-first-out principles.
What to do in case of contact with potassium nitrite?
Potassium nitrite exposure requires immediate action due to its acute toxicity. For skin contact, remove contaminated clothing and wash affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15-20 minutes. If inhaled, move person to fresh air and seek medical attention. For ingestion, do not induce vomiting and seek immediate medical care. Always consult a physician and provide the safety data sheet.
How to dispose of potassium nitrite properly?
Potassium nitrite disposal must comply with local, national, and EU waste regulations as it's classified as hazardous waste. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never discharge into sewers, waterways, or soil due to its aquatic toxicity classification. Small quantities can be neutralized by qualified personnel following established protocols. Maintain proper documentation of disposal activities and ensure containers are properly labeled before collection by waste management services.
How to transport potassium nitrite?
Potassium nitrite is classified under ADR as Class 5.1 (Oxidizing substances) Packing Group II, requiring specific transport regulations. It must be packaged in UN-approved containers with proper labeling including GHS03, GHS06, and GHS09 pictograms. Transport vehicles must carry appropriate emergency equipment and documentation. Drivers require ADR training for dangerous goods transport. Segregation from incompatible materials during transport is mandatory, and emergency response procedures must be readily available.
Is potassium nitrite subject to specific regulations?
Potassium nitrite is subject to multiple European regulations including REACH registration requirements and CLP classification as Ox. Sol. 2, Acute Tox. 3, and Aquatic Acute 1. It requires safety data sheets and proper hazard communication. The substance is not currently listed as SVHC (Substance of Very High Concern). Food-grade applications are regulated under food additive legislation. Industrial users must comply with occupational exposure limits and implement appropriate risk management measures.
Where to buy potassium nitrite in Europe?
Potassium nitrite is available through OYSI, a trusted European distributor of technical chemicals. OYSI supplies high-quality potassium nitrite to industrial customers across Europe, ensuring full regulatory compliance and proper documentation. As a specialized chemical distributor, OYSI provides technical support, safety data sheets, and reliable supply chain management. Contact OYSI directly for availability, specifications, packaging options, and delivery throughout European markets for your industrial applications.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.