Potassium nitrite

KNO2

potassium nitrite

CAS7758-09-0
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7758-09-0
EC Number
231-832-4
UN Number
1488
Index Number
007-011-00-X
PubChem CID
516910

Physical-chemical properties

Molecular Formula
KNO2
Molar Mass
85.10 g/mol
IUPAC Name
potassium nitrite

Chemical Identifiers

InChI
InChI=1S/K.HNO2/c;2-1-3/h;(H,2,3)/q+1;/p-1
InChI Key
BXNHTSHTPBPRFX-UHFFFAOYSA-M

Overview

Potassium nitrite (CAS 7758-09-0) is an inorganic nitrite salt with strong oxidizing properties and acute toxicity characteristics. This white to slightly yellowish crystalline compound serves as a versatile chemical intermediate in numerous industrial applications. With the molecular formula KNO2 and a molecular weight of 85.104 g/mol, potassium nitrite demonstrates significant solubility in water and exhibits hygroscopic behavior under ambient conditions. The substance belongs to the nitrite family of compounds, sharing chemical similarities with sodium nitrite, another widely used nitrite salt in industrial processes. From a safety perspective, potassium nitrite requires careful handling due to its classification as a Category 2 oxidizing solid and Category 3 acute toxicant. The compound displays the GHS danger pictograms for oxidizing substances (GHS03), acute toxicity (GHS06), and environmental hazards (GHS09). Its oxidizing nature means it can intensify fires and react vigorously with combustible materials, while its acute toxicity properties necessitate appropriate personal protective equipment during handling and storage. Industrial applications of potassium nitrite include its use as a corrosion inhibitor in metalworking fluids and cooling systems, where it effectively prevents rust formation on ferrous metals. The compound also serves as a chemical intermediate in organic synthesis processes and finds application in certain analytical chemistry procedures. Additionally, it functions as a nitrogen source in specialized fertilizer formulations for specific agricultural applications. OYSI maintains reliable supplies of technical-grade potassium nitrite to support European industrial customers across various sectors requiring this essential oxidizing agent.

Safety & Classification

Danger
Classification:

Ox. Sol. 2; Acute Tox. 3 *; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H272

May intensify fire; oxidiser.

H301

Toxic if swallowed.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1488
ADR Class5.1
Packing GroupII
Tunnel CodeE
Proper Shipping NameKaliumnitrit
Marine PollutantNo

Frequently Asked Questions

What is potassium nitrite?

Potassium nitrite is an inorganic salt with the chemical formula KNO2 and CAS number 7758-09-0. This compound has a molecular weight of 85.104 g/mol and appears as white or slightly yellowish crystalline powder. It serves as an important industrial chemical with oxidizing properties, classified as a hazardous substance requiring careful handling due to its acute toxicity and environmental impact on aquatic systems.

What are the physicochemical properties of potassium nitrite?

Potassium nitrite is a white to pale yellow crystalline solid that is highly soluble in water and slightly soluble in ethanol. The compound is hygroscopic, meaning it absorbs moisture from air, and decomposes at elevated temperatures above 440°C. It exhibits strong oxidizing properties and can react vigorously with reducing agents, organic materials, and combustible substances, making it chemically reactive under certain conditions.

What is potassium nitrite used for?

Potassium nitrite is primarily used as a food preservative in meat processing to prevent bacterial growth and maintain color. Industrial applications include its use as a corrosion inhibitor in metalworking fluids, an intermediate in dye and pharmaceutical manufacturing, and as an analytical reagent in laboratories. It also serves in heat treatment salt baths and as a component in some photographic processes.

How to handle potassium nitrite safely?

Potassium nitrite requires careful handling due to its acute toxicity and oxidizing properties. Personal protective equipment must include nitrile gloves, safety goggles, and dust masks to prevent inhalation or skin contact. Work in well-ventilated areas away from heat sources, combustible materials, and reducing agents. Avoid creating dust clouds and ensure emergency eyewash stations and safety showers are readily accessible.

How to store potassium nitrite correctly?

Potassium nitrite must be stored in tightly sealed containers in cool, dry, well-ventilated areas away from heat sources and direct sunlight. Keep separated from incompatible materials including acids, reducing agents, organic compounds, and combustible materials. Storage areas should be equipped with appropriate fire suppression systems and maintained at stable temperatures to prevent decomposition and moisture absorption.

What to do in case of contact with potassium nitrite?

In case of skin contact with potassium nitrite, immediately remove contaminated clothing and rinse affected areas with plenty of water for at least 15 minutes. For eye contact, flush immediately with water for 15-20 minutes. If inhaled, move to fresh air immediately. If ingested, rinse mouth and seek immediate medical attention. Never induce vomiting and always consult emergency medical services for any exposure.

How to dispose of potassium nitrite appropriately?

Potassium nitrite disposal must comply with local environmental regulations as hazardous waste due to its acute aquatic toxicity classification. The substance cannot be disposed of in regular waste streams or sewage systems. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Small quantities may require neutralization under professional supervision before disposal according to regional hazardous waste management protocols.

How to transport potassium nitrite?

Potassium nitrite is classified as ADR Class 5.1 (oxidizing substances) Packing Group II, requiring specialized dangerous goods transport procedures. Packages must bear appropriate hazard labels including GHS03, GHS06, and GHS09 pictograms with 'Danger' signal word. Transport vehicles need proper ventilation, emergency equipment, and trained drivers with ADR certification. Documentation must include safety data sheets and transport emergency cards.

Is potassium nitrite subject to particular regulations?

Potassium nitrite is regulated under multiple European frameworks including REACH registration requirements and CLP classification as Oxidizing Solid Category 2, Acute Toxicity Category 3, and Aquatic Acute Category 1. It requires safety data sheets for professional users and is subject to food additive regulations when used in food processing. The substance is not currently listed as SVHC under REACH.

Where to buy potassium nitrite in Europe?

Potassium nitrite is available through OYSI, a specialized European distributor of technical chemicals serving industrial and professional customers. OYSI provides reliable supply chains across Europe with proper documentation, safety data sheets, and regulatory compliance support. Professional buyers can contact OYSI directly for quotations, technical specifications, and delivery arrangements to meet their specific industrial requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.