Sodium nitrite

NNaO2

sodium nitrite

CAS7632-00-0
GHS03 Gefahrensymbol: Brandfördernd – Flamme über Kreis
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
7632-00-0
EC Number
231-555-9
UN Number
1500
Index Number
007-010-00-4
PubChem CID
23668193

Physical-chemical properties

Molecular Formula
NNaO2
Molar Mass
69.00 g/mol
IUPAC Name
sodium nitrite

Chemical Identifiers

InChI
InChI=1S/HNO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1
InChI Key
LPXPTNMVRIOKMN-UHFFFAOYSA-M

Overview

Sodium nitrite (CAS 7632-00-0) is an inorganic sodium salt with oxidizing properties and high aquatic toxicity. This versatile chemical compound serves as a critical intermediate in numerous industrial processes across Europe. As a white to slightly yellowish crystalline powder, sodium nitrite demonstrates excellent solubility in water and exhibits strong oxidizing characteristics that make it valuable in various technical applications. The compound requires careful handling due to its classification as an oxidizing solid and acute toxin, demanding strict adherence to safety protocols during storage, transport, and use. From a safety perspective, sodium nitrite presents multiple hazard classifications that industrial users must consider. Its oxidizing properties can intensify fires and pose risks when in contact with combustible materials. The compound's acute toxicity profile necessitates appropriate personal protective equipment and well-ventilated working environments. Additionally, its high aquatic toxicity classification requires careful environmental management to prevent water contamination. Transportation falls under ADR class 5.1, reflecting its oxidizing nature and associated handling requirements. Industrial applications for sodium nitrite span several sectors, including metal treatment where it functions as a corrosion inhibitor and in chemical manufacturing as a diazotization agent for dye production. The food industry also utilizes this compound as a preservative, though under strict regulatory guidelines. Unlike potassium nitrite which serves similar functions, sodium nitrite often provides better solubility characteristics in specific formulations. OYSI maintains reliable supplies of technical-grade sodium nitrite to meet the demanding requirements of European industrial customers, ensuring consistent quality and regulatory compliance across all deliveries.

Safety & Classification

Danger
Classification:

Ox. Sol. 3; Acute Tox. 3 *; Aquatic Acute 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H272

May intensify fire; oxidiser.

H301

Toxic if swallowed.

H400

Very toxic to aquatic life.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Ingestion

Toxic

Measures if substance is accidentally swallowed

First Aid Actions

  • +P301IF SWALLOWED:
  • +P330Rinse mouth.
  • +P331Do NOT induce vomiting.
  • +P310Immediately call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1500
ADR Class5.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameNatriumnitrit, fest
Marine PollutantNo

Frequently Asked Questions

What is sodium nitrite?

Sodium nitrite is an inorganic compound with the chemical formula NNaO2 and molecular weight of 68.995 g/mol. It serves as both an oxidizing agent and preservative in various industrial applications. This white to slightly yellowish crystalline powder is highly soluble in water and classified as hazardous with oxidizing properties (Ox. Sol. 3), acute toxicity (Acute Tox. 3), and aquatic toxicity (Aquatic Acute 1), requiring careful handling protocols.

What are the physicochemical properties of sodium nitrite?

Sodium nitrite appears as white to pale yellow crystalline powder or granules that are highly soluble in water. It has a molecular formula of NNaO2 with a molecular weight of 68.995 g/mol. The compound is odorless and has a slightly salty taste. It exhibits strong oxidizing properties and is hygroscopic, meaning it readily absorbs moisture from air. These properties make it reactive with organic materials and reducing agents.

What is sodium nitrite used for?

Sodium nitrite serves multiple industrial purposes, primarily as a food preservative in meat products where it prevents bacterial growth and maintains color. It functions as a corrosion inhibitor in industrial cooling systems and concrete applications. The compound is also used in metal treatment processes, as an intermediate in dye manufacturing, and in pharmaceutical synthesis. Its oxidizing properties make it valuable in various chemical manufacturing processes.

How to handle sodium nitrite safely?

Sodium nitrite requires strict safety measures due to its toxicity and oxidizing properties. Wear appropriate PPE including chemical-resistant gloves, safety goggles, and protective clothing. Ensure adequate ventilation and avoid generating dust. Keep away from heat sources, combustible materials, and reducing agents. Wash hands thoroughly after handling and avoid eating, drinking, or smoking in work areas. Training on emergency procedures is essential for all handlers.

How to store sodium nitrite correctly?

Sodium nitrite must be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed and separate from combustible materials, reducing agents, acids, and food products. Storage areas should be equipped with appropriate fire suppression systems. Maintain temperature below 25°C and relative humidity below 60%. Regular inspection of containers for damage or contamination is recommended.

What to do in case of contact with sodium nitrite?

Sodium nitrite exposure requires immediate first aid measures. For skin contact, remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. If inhaled, move person to fresh air immediately. For eye contact, flush with clean water for 15 minutes while holding eyelids open. If ingested, do not induce vomiting - rinse mouth and seek immediate medical attention. Always consult emergency services for serious exposures.

How to dispose of sodium nitrite appropriately?

Sodium nitrite disposal must comply with local and EU waste regulations as hazardous waste. Contact licensed waste disposal companies for proper treatment and disposal. Small quantities can be neutralized by qualified personnel before disposal, but never mix with organic materials or reducing agents. Container disposal requires triple rinsing with appropriate solvents. Maintain detailed waste disposal records and ensure compliance with REACH and national environmental regulations.

How to transport sodium nitrite?

Sodium nitrite is classified under ADR as Class 5.1 (Oxidizing substances), Packing Group III. Transport requires appropriate UN-specification packaging and proper labeling with GHS pictograms (GHS03, GHS06, GHS09). Vehicles must carry appropriate emergency equipment and documentation. Drivers need ADR certification for dangerous goods transport. Segregation from combustible materials and other incompatible substances is mandatory during transport across European routes.

Is sodium nitrite subject to specific regulations?

Sodium nitrite is subject to comprehensive EU regulations including REACH registration and CLP classification requirements. It carries the signal word 'Danger' with specific hazard statements for oxidizing properties and acute toxicity. The substance is not listed as SVHC (Substance of Very High Concern). Additional food-grade regulations apply when used as preservative. Workplace exposure limits and environmental discharge restrictions may apply depending on usage and location.

Where to buy sodium nitrite in Europe?

Sodium nitrite is available through OYSI, a European distributor of technical chemicals serving industrial customers across Europe. OYSI provides quality sodium nitrite with proper documentation, safety data sheets, and regulatory compliance support. Professional customers can contact OYSI for technical grades suitable for various industrial applications. The company ensures proper packaging, labeling, and transport arrangements compliant with European dangerous goods regulations and customer specifications.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.