Sodium nitrite
NNaO2
sodium nitrite
Consulting for Sodium nitrite
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Identification
- CAS Number
- 7632-00-0
- EC Number
- 231-555-9
- UN Number
- 1500
- Index Number
- 007-010-00-4
- PubChem CID
- 23668193
Physical-chemical properties
- Molecular Formula
- NNaO2
- Molar Mass
- 69.00 g/mol
- IUPAC Name
- sodium nitrite
Chemical Identifiers
- InChI
- InChI=1S/HNO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1
- InChI Key
- LPXPTNMVRIOKMN-UHFFFAOYSA-M
Overview
Sodium nitrite (CAS 7632-00-0) is an inorganic sodium salt with strong oxidizing properties and significant industrial applications. This versatile chemical compound serves as a critical intermediate in numerous industrial processes and manufacturing applications across Europe. With the molecular formula NNaO2 and a molecular weight of 68.995 g/mol, sodium nitrite appears as a white to slightly yellowish crystalline powder that is highly soluble in water. The substance exhibits strong oxidizing characteristics, which makes it valuable in various chemical synthesis processes but also requires careful handling protocols. From a safety perspective, sodium nitrite carries significant hazard classifications including Oxidizing Solids Category 3, Acute Toxicity Category 3, and Aquatic Acute Category 1, accompanied by the danger signal word and multiple GHS pictograms (GHS03, GHS06, GHS09). Its ADR classification as Class 5.1 reflects its oxidizing nature, necessitating specialized transportation and storage requirements. These properties demand comprehensive safety measures during handling, storage, and transportation to ensure workplace safety and environmental protection. Industrial applications of sodium nitrite span multiple sectors, with primary uses in metal treatment processes where it serves as a corrosion inhibitor and in the production of diazo compounds for pharmaceutical and dye manufacturing. The chemical industry also utilizes sodium nitrite in the synthesis of various nitrogen-containing compounds, often in conjunction with related oxidizing agents like potassium nitrite for specific chemical transformations. The compound's oxidizing properties make it particularly valuable in analytical chemistry applications and certain specialized manufacturing processes requiring controlled oxidation reactions. OYSI maintains reliable supplies of technical-grade sodium nitrite to support diverse industrial requirements across European markets.
Safety & Classification
Ox. Sol. 3; Acute Tox. 3 *; Aquatic Acute 1
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Ingestion
Measures if substance is accidentally swallowed
First Aid Actions
- +P301IF SWALLOWED:
- +P330Rinse mouth.
- +P331Do NOT induce vomiting.
- +P310Immediately call a POISON CENTER/doctor.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 1500 |
| ADR Class | 5.1 |
| Packing Group | III |
| Tunnel Code | E |
| Proper Shipping Name | Natriumnitrit, fest |
| Marine Pollutant | No |
Frequently Asked Questions
What is sodium nitrite?
Sodium nitrite is an inorganic compound with the chemical formula NNaO2 and CAS number 7632-00-0. It has a molecular weight of 68.995 g/mol and appears as white to slightly yellowish crystalline powder. This chemical substance is classified as an oxidizing solid with acute toxicity properties and aquatic hazard potential. It is widely used in various industrial applications and requires careful handling due to its hazardous nature.
What are the physicochemical properties of sodium nitrite?
Sodium nitrite is a white to pale yellow crystalline solid that is highly soluble in water. It has no characteristic odor and readily dissolves in polar solvents. The compound is hygroscopic, meaning it absorbs moisture from the air. It has a relatively low molecular weight of 68.995 g/mol and decomposes at elevated temperatures, releasing toxic nitrogen oxides. Its high water solubility makes it easily dispersible in aqueous solutions.
What is sodium nitrite used for?
Sodium nitrite serves multiple industrial purposes, primarily as a food preservative in meat processing where it prevents bacterial growth and maintains color. It is used in metal treatment for corrosion inhibition, particularly in cooling systems and boilers. The compound also finds applications in pharmaceutical synthesis, dye manufacturing, and as an analytical reagent in laboratory settings. Additionally, it serves as an intermediate in various chemical synthesis processes.
How to handle sodium nitrite safely?
Sodium nitrite requires careful handling with appropriate personal protective equipment including chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas to avoid inhalation of dust particles. Avoid contact with skin, eyes, and clothing as it can cause irritation. Keep away from incompatible materials like acids and reducing agents. Always wash hands thoroughly after handling and never eat, drink, or smoke while working with this substance.
How to store sodium nitrite correctly?
Sodium nitrite should be stored in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers tightly closed to prevent moisture absorption and contamination. Store separately from acids, reducing agents, and combustible materials due to its oxidizing properties. Maintain storage temperature below 25°C and ensure adequate ventilation. Use original containers or chemically compatible alternatives, and implement proper labeling and inventory management systems.
What to do in case of contact with sodium nitrite?
In case of skin contact with sodium nitrite, immediately remove contaminated clothing and rinse affected area with plenty of water for at least 15 minutes. For eye contact, flush eyes with clean water for 15 minutes while holding eyelids open. If inhaled, move to fresh air immediately. In case of ingestion, do not induce vomiting and seek immediate medical attention. Always consult a physician if symptoms persist or if significant exposure occurs.
How to dispose of sodium nitrite appropriately?
Sodium nitrite disposal must comply with local and national environmental regulations as it poses aquatic hazards. Contact licensed waste disposal companies for proper handling and treatment. Small quantities may be neutralized under controlled conditions by qualified personnel, but never dispose of it down drains or in regular waste. Collect waste in appropriate containers, label clearly, and maintain disposal records. Consider recycling options through specialized chemical waste management services when available.
How to transport sodium nitrite?
Sodium nitrite is classified under ADR transport regulations as Class 5.1 (Oxidizing Substances), Packing Group III. It requires appropriate UN packaging and labeling with oxidizing and toxic hazard symbols. Vehicles must carry proper documentation including transport documents and emergency response information. Drivers need ADR training certification. Packages must be secured to prevent damage during transport and separated from incompatible materials according to segregation requirements.
Is sodium nitrite subject to particular regulations?
Sodium nitrite is subject to various European regulations including REACH registration requirements and CLP classification standards. It is classified as Ox. Sol. 3, Acute Tox. 3, and Aquatic Acute 1 under CLP regulation, requiring specific labeling with GHS03, GHS06, and GHS09 pictograms. Food industry applications are regulated under specific food additive legislation. It is not currently listed as a SVHC substance under REACH regulation.
Where to buy sodium nitrite in Europe?
Sodium nitrite is available through OYSI, a trusted European distributor of technical chemicals. OYSI provides high-quality sodium nitrite suitable for various industrial applications across Europe. As a specialized chemical distributor, OYSI ensures proper handling, documentation, and regulatory compliance for all shipments. Contact OYSI directly for specific grades, quantities, and delivery options tailored to your technical requirements and geographical location within the European market.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.