Phenylmercury;hydrate

C6H7HgO

phenylmercury;hydrate

CAS100-57-2

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Identification

CAS Number
100-57-2
EC Number
202-866-7
UN Number
1894
Index Number
080-008-00-9
PubChem CID
7512

Physical-chemical properties

Molecular Formula
C6H7HgO
Molar Mass
295.71 g/mol
IUPAC Name
phenylmercury;hydrate

Chemical Identifiers

InChI
InChI=1S/C6H5.Hg.H2O/c1-2-4-6-5-3-1;;/h1-5H;;1H2
InChI Key
MSYUMXXVCSLXMR-UHFFFAOYSA-N

Overview

Phenylmercury hydrate (CAS 100-57-2) is an organomercury compound with antimicrobial and preservative properties used in specialized industrial applications. This organometallic substance, with the molecular formula C6H7HgO and a molar mass of 295.71 g/mol, represents a class of mercury-containing compounds that have historically played important roles in industrial chemistry. Phenylmercury hydrate is characterized by its phenyl group bonded to mercury, combined with water molecules in its crystalline structure, giving it distinct chemical and physical properties compared to other mercury compounds. The compound exhibits significant antimicrobial activity, which has made it valuable in specific preservation applications. However, like all mercury-containing substances, it requires careful handling and storage protocols due to its classification under ADR Class 6.1 for toxic materials. Its organometallic nature distinguishes it from purely organic compounds such as 4-nitroaniline or 4-nitrophenol, as the mercury atom provides unique reactivity patterns and biological activity. Industrial applications of phenylmercury hydrate include its use as a fungicide and bactericide in specialized formulations, particularly in agricultural chemistry and materials preservation. It has also found application in certain analytical chemistry procedures where its specific mercury-organic bonding characteristics are advantageous. The compound's effectiveness as a biocide stems from the mercury center's ability to interact with sulfur-containing biomolecules. Given the stringent regulations surrounding mercury compounds in many jurisdictions, the use of phenylmercury hydrate is increasingly restricted to specific licensed applications where alternative compounds cannot provide equivalent performance. OYSI maintains availability of phenylmercury hydrate for qualified industrial customers requiring this specialized organometallic compound for approved applications.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number1894
ADR Class6.1
Packing GroupII
Tunnel CodeD/E
Proper Shipping NamePhenylquecksilber(II)hydroxid
Marine PollutantNo

Frequently Asked Questions

What is phenylmercury hydrate?

Phenylmercury hydrate is an organomercury compound with the molecular formula C6H7HgO and CAS number 100-57-2. This chemical substance has a molecular weight of 295.71 g/mol and belongs to the class of phenylmercury derivatives. It contains mercury bonded to a phenyl group with associated water molecules in its crystal structure, making it a hydrated form of phenylmercury compounds used in various industrial applications.

What are the physicochemical properties of phenylmercury hydrate?

Phenylmercury hydrate is a solid organomercury compound at room temperature with the molecular formula C6H7HgO. As a mercury-containing organic compound, it typically appears as a crystalline solid. The presence of the hydrate form indicates water molecules are incorporated into its crystal structure. Being an organomercury compound, it exhibits limited water solubility but may dissolve in organic solvents.

What is phenylmercury hydrate used for?

Phenylmercury hydrate is primarily used as a fungicide and antimicrobial agent in industrial applications. Historically, it has been employed in agricultural formulations, wood preservation treatments, and as a biocide in various industrial processes. Due to its mercury content, its use has become increasingly restricted in many applications, with modern alternatives being preferred for environmental and safety reasons.

How to handle phenylmercury hydrate safely?

Phenylmercury hydrate requires careful handling due to its mercury content and potential toxicity. Always wear appropriate personal protective equipment including nitrile gloves, safety goggles, and respiratory protection when handling. Work in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin contact and ingestion. Use proper laboratory techniques and ensure all personnel are trained in mercury compound handling procedures.

How to store phenylmercury hydrate correctly?

Phenylmercury hydrate should be stored in tightly sealed containers in a cool, dry, and well-ventilated area away from incompatible materials. Keep containers away from heat sources, direct sunlight, and moisture. Store separately from food, beverages, and animal feed. Ensure storage areas have appropriate spill containment measures and are accessible only to authorized personnel trained in handling mercury-containing compounds.

What to do in case of contact with phenylmercury hydrate?

In case of skin contact with phenylmercury hydrate, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If eye contact occurs, flush eyes with clean water for 15 minutes while holding eyelids open. In case of inhalation, move to fresh air immediately. For ingestion, do not induce vomiting and seek immediate medical attention, informing healthcare providers about mercury exposure.

How to dispose of phenylmercury hydrate appropriately?

Phenylmercury hydrate must be disposed of as hazardous waste containing mercury through licensed waste management facilities. Never dispose of this substance in regular waste streams, sewers, or the environment. Contact specialized hazardous waste disposal companies that can handle mercury-containing compounds. Follow all local, national, and EU regulations regarding mercury waste disposal, including proper documentation and tracking requirements for hazardous waste transfers.

How to transport phenylmercury hydrate?

Phenylmercury hydrate is classified under ADR as Class 6.1 (toxic substances) with Packing Group II, indicating moderate toxicity requiring specific transport precautions. It must be packaged in UN-approved containers with appropriate labeling and documentation. Transport vehicles must carry proper emergency equipment and drivers need hazardous materials training. Comply with all ADR regulations for toxic substances during shipping and handling.

Is phenylmercury hydrate subject to particular regulations?

Phenylmercury hydrate is subject to strict regulations due to its mercury content under various European and international frameworks. It falls under REACH registration requirements and mercury-specific restrictions. Many jurisdictions have banned or severely limited its use in consumer products and certain industrial applications. Users must comply with occupational exposure limits, environmental discharge restrictions, and waste management regulations specific to mercury-containing substances.

Where to buy phenylmercury hydrate in Europe?

Phenylmercury hydrate is available through OYSI, a specialized European distributor of technical chemicals. As a professional chemical supplier, OYSI can provide this substance to qualified industrial customers with appropriate handling capabilities and regulatory compliance. Due to the restricted nature of mercury compounds, purchases typically require verification of legitimate industrial use and proper safety measures for handling and storage.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.