Pentafluoro-lambda5-chlorane

ClF5

pentafluoro-lambda5-chlorane

CAS13637-63-3

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Identification

CAS Number
13637-63-3
EC Number
237-123-6
UN Number
2548
PubChem CID
61654

Physical-chemical properties

Molecular Formula
ClF5
Molar Mass
130.44 g/mol
IUPAC Name
pentafluoro-lambda5-chlorane

Chemical Identifiers

InChI
InChI=1S/ClF5/c2-1(3,4,5)6
InChI Key
KNSWNNXPAWSACI-UHFFFAOYSA-N

Overview

Pentafluoro-lambda5-chlorane (CAS 13637-63-3) is an interhalogen compound with highly reactive fluorinating properties and strong oxidizing characteristics. This inorganic compound, with the molecular formula ClF5 and molecular weight of 130.44 g/mol, represents one of the most potent fluorinating agents available in industrial chemistry. Also known by its IUPAC name pentafluoro-lambda5-chlorane, this colorless gas exhibits exceptional reactivity due to its unique molecular structure containing five fluorine atoms bonded to a central chlorine atom in a square pyramidal geometry. The compound demonstrates extreme oxidizing power, capable of fluorinating most organic and many inorganic materials at room temperature. Its reactivity surpasses that of many other halogen compounds, including related interhalogens such as those containing iodane structures. Unlike simpler compounds like nitrous oxide, pentafluoro-lambda5-chlorane requires specialized handling protocols due to its aggressive chemical nature and potential for violent reactions with organic matter, water, and reducing agents. Safety considerations are paramount when working with this substance, as it can cause severe burns and releases toxic hydrogen fluoride upon contact with moisture. The compound is classified under ADR Class 2, reflecting its nature as a compressed gas requiring specialized transport conditions. Proper ventilation, fluorine-resistant materials, and emergency procedures are essential for safe handling. Primary industrial applications include semiconductor manufacturing for plasma etching processes, specialized fluorination reactions in pharmaceutical synthesis, and as a powerful cleaning agent for certain high-tech manufacturing equipment. The compound's ability to selectively introduce fluorine atoms makes it valuable in producing fluorinated pharmaceuticals and specialty chemicals. OYSI maintains reliable supply chains for pentafluoro-lambda5-chlorane, ensuring consistent availability for European industrial customers requiring this specialized fluorinating agent.

Safety & Classification

No Hazard Classification

This substance is not classified as hazardous according to CLP Regulation (EC) No 1272/2008.

Transport (ADR)

UN Number2548
ADR Class2
Packing Group
Tunnel CodeD
Proper Shipping NameChlorpentafluorid, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is pentafluoro-lambda5-chlorane?

Pentafluoro-lambda5-chlorane is a highly reactive interhalogen compound with the chemical formula ClF5 and CAS number 13637-63-3. This molecular compound consists of one chlorine atom bonded to five fluorine atoms, forming a volatile and extremely oxidizing substance. With a molecular weight of 130.44 g/mol, it belongs to the family of chlorine fluorides and exhibits exceptional chemical reactivity due to its high fluorine content.

What are the physicochemical properties of pentafluoro-lambda5-chlorane?

Pentafluoro-lambda5-chlorane is a colorless gas at room temperature with an extremely pungent and irritating odor. It demonstrates high volatility and exists predominantly in gaseous form under standard conditions. The compound is highly reactive with water and most organic materials, showing strong oxidizing properties. Its molecular structure features chlorine in a +5 oxidation state, making it thermodynamically unstable and prone to decomposition reactions.

What is pentafluoro-lambda5-chlorane used for?

Pentafluoro-lambda5-chlorane serves primarily as a powerful fluorinating agent in specialized chemical synthesis applications. It is utilized in research laboratories for the preparation of various fluorinated compounds and as an oxidizing agent in specific industrial processes. Due to its extreme reactivity and handling challenges, its applications are limited to highly controlled environments where specialized expertise and safety equipment are available for safe manipulation.

How to handle pentafluoro-lambda5-chlorane safely?

Safe handling of pentafluoro-lambda5-chlorane requires specialized personal protective equipment including chemical-resistant suits, self-contained breathing apparatus, and fluorine-compatible gloves. Work must be conducted in well-ventilated areas or fume hoods designed for highly reactive gases. Personnel should be thoroughly trained in emergency procedures, and all equipment must be compatible with fluorine compounds to prevent violent reactions or equipment failure during handling operations.

How to store pentafluoro-lambda5-chlorane correctly?

Pentafluoro-lambda5-chlorane must be stored in specialized containers made of materials compatible with fluorine compounds, such as certain fluoropolymers or passivated metals. Storage areas should be cool, dry, and well-ventilated, isolated from combustible materials, organic compounds, and moisture. The compound is incompatible with most common materials and requires segregation from reducing agents, metals, and any substances containing hydrogen to prevent violent reactions.

What to do in case of contact with pentafluoro-lambda5-chlorane?

Immediate evacuation from the exposure area is critical in case of contact with pentafluoro-lambda5-chlorane. For skin contact, remove contaminated clothing and flush affected areas with copious amounts of water for at least 15 minutes. In case of inhalation, move to fresh air immediately and seek medical attention. Eye contact requires immediate irrigation with water. Due to its extreme reactivity, professional emergency medical treatment should be sought immediately for any exposure incident.

How to dispose of pentafluoro-lambda5-chlorane appropriately?

Disposal of pentafluoro-lambda5-chlorane must comply with local hazardous waste regulations and requires specialized treatment by licensed waste management facilities. The compound cannot be disposed of through normal waste streams due to its extreme reactivity. Neutralization procedures typically involve controlled reaction with appropriate scrubbing systems designed for fluorine-containing compounds. Professional hazardous waste contractors experienced with reactive fluorine compounds should handle all disposal operations.

How to transport pentafluoro-lambda5-chlorane?

Pentafluoro-lambda5-chlorane is classified under ADR Class 2 for transport as a compressed or liquefied gas. Transportation requires specialized packaging designed for highly reactive fluorine compounds, with appropriate pressure ratings and material compatibility. Vehicles must be properly placarded, and drivers require specialized training for handling dangerous goods. All transport operations must comply with international dangerous goods regulations and local transportation authorities' requirements.

Is pentafluoro-lambda5-chlorane subject to specific regulations?

Pentafluoro-lambda5-chlorane is subject to various chemical safety regulations including REACH registration requirements in Europe. As a highly reactive chemical substance, it falls under strict handling and storage regulations in most jurisdictions. The compound is not classified as an SVHC (Substance of Very High Concern), but its extreme reactivity means it requires compliance with workplace safety regulations and specialized handling protocols in industrial and research applications.

Where to buy pentafluoro-lambda5-chlorane in Europe?

OYSI serves as a specialized European distributor for pentafluoro-lambda5-chlorane, providing this highly reactive compound to qualified industrial and research customers. Due to the extreme handling requirements and safety considerations, purchases typically require verification of appropriate facilities and trained personnel. OYSI can provide technical support and guidance on safe handling procedures along with proper packaging and transportation arrangements for this challenging chemical compound.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.