1,1,2,3,3,3-hexafluoroprop-1-ene

C3F6

CAS116-15-4
GHS04 Gefahrensymbol: Unter Druck stehende Gase – Gasflasche
GHS07 Gefahrensymbol: Gesundheitsschädlich/Reizend – Ausrufezeichen
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Identification

CAS Number
116-15-4
EC Number
204-127-4
UN Number
1858
Index Number
602-061-00-4
PubChem CID
8302

Physical-chemical properties

Molecular Formula
C3F6
Molar Mass
150.02 g/mol
IUPAC Name
1,1,2,3,3,3-hexafluoroprop-1-ene

Chemical Identifiers

InChI
InChI=1S/C3F6/c4-1(2(5)6)3(7,8)9
InChI Key
HCDGVLDPFQMKDK-UHFFFAOYSA-N

Overview

1,1,2,3,3,3-hexafluoroprop-1-ene (CAS 116-15-4) is a fluorinated olefin compound with exceptional chemical stability and low toxicity profile for industrial applications. This highly fluorinated propene derivative represents an important class of specialty chemicals used across various industrial sectors. With its molecular formula C3F6 and molecular weight of 150.02 g/mol, this compound exhibits unique properties that make it valuable for specialized applications requiring chemical inertness and thermal stability. The compound belongs to the family of fluorinated alkenes, sharing structural similarities with other halogenated hydrocarbons, though it demonstrates superior performance characteristics compared to traditional compounds like ethene in demanding industrial environments. From a safety perspective, 1,1,2,3,3,3-hexafluoroprop-1-ene is classified as a pressurized gas with GHS pictograms GHS04 and GHS07, carrying a "Warning" signal word. The substance presents moderate acute toxicity (Acute Tox. 4) and specific target organ toxicity for single exposure (STOT SE 3), requiring appropriate handling protocols and ventilation systems during industrial use. Its ADR classification as Class 2 material necessitates specialized transportation and storage procedures. Key industrial applications include use as a refrigerant in specialized cooling systems, as an intermediate in fluoropolymer synthesis, and as a specialty solvent in electronics manufacturing processes. The compound's chemical stability and non-flammable properties make it particularly suitable for applications where safety and performance are critical requirements. OYSI maintains reliable supply chains for 1,1,2,3,3,3-hexafluoroprop-1-ene, ensuring consistent availability for European industrial customers requiring this specialized fluorinated compound for their technical applications.

Safety & Classification

Warning
Classification:

Press. Gas; Acute Tox. 4 *; STOT SE 3

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H332

Harmful if inhaled.

H335

May cause respiratory irritation.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number1858
ADR Class2
Packing Group
Tunnel CodeC/E
Proper Shipping NameHexafluorpropylen, unter Druck verflüssigt
Marine PollutantNo

Frequently Asked Questions

What is 1,1,2,3,3,3-hexafluoroprop-1-ene?

1,1,2,3,3,3-hexafluoroprop-1-ene is a fluorinated organic compound with the molecular formula C3F6 and CAS number 116-15-4. This substance belongs to the family of hydrofluoroolefins (HFOs) and has a molecular weight of 150.02 g/mol. It is classified as a pressurized gas with acute toxicity and specific target organ toxicity properties, requiring careful handling in industrial applications.

What are the physicochemical properties of 1,1,2,3,3,3-hexafluoroprop-1-ene?

1,1,2,3,3,3-hexafluoroprop-1-ene is a colorless gas under normal conditions due to its classification as a pressurized gas. As a highly fluorinated compound, it exhibits low reactivity and chemical stability. The substance has limited solubility in water but shows better compatibility with organic solvents. Its fluorinated structure provides unique thermal and chemical resistance properties typical of perfluorinated compounds.

What is 1,1,2,3,3,3-hexafluoroprop-1-ene used for?

1,1,2,3,3,3-hexafluoroprop-1-ene is primarily used as a refrigerant and working fluid in cooling systems due to its excellent thermodynamic properties. It serves as an environmentally friendly alternative to traditional refrigerants with high global warming potential. The compound is also utilized in specialty chemical synthesis, foam blowing applications, and as a component in fire suppression systems where its inert properties are advantageous.

How to handle 1,1,2,3,3,3-hexafluoroprop-1-ene safely?

Safe handling of 1,1,2,3,3,3-hexafluoroprop-1-ene requires appropriate personal protective equipment including safety goggles, chemical-resistant gloves, and adequate respiratory protection. Work in well-ventilated areas or under fume hoods to prevent accumulation of vapors. Avoid direct contact with skin and eyes, and prevent inhalation. Use proper gas handling equipment designed for pressurized systems and ensure all personnel are trained in emergency procedures.

How to store 1,1,2,3,3,3-hexafluoroprop-1-ene correctly?

1,1,2,3,3,3-hexafluoroprop-1-ene must be stored in appropriate pressure vessels designed for compressed gases in a cool, dry, well-ventilated area away from heat sources and ignition points. Keep containers upright and secured to prevent tipping. Store away from incompatible materials and ensure storage areas are equipped with gas detection systems. Regular inspection of storage containers for leaks and proper labeling is essential for safe storage.

What to do in case of contact with 1,1,2,3,3,3-hexafluoroprop-1-ene?

In case of skin contact with 1,1,2,3,3,3-hexafluoroprop-1-ene, immediately remove contaminated clothing and flush the affected area with plenty of water. For eye contact, rinse thoroughly with clean water for at least 15 minutes and remove contact lenses if present. If inhaled, move the person to fresh air immediately and provide oxygen if breathing is difficult. Seek immediate medical attention for all exposure cases and contact poison control if necessary.

How to dispose of 1,1,2,3,3,3-hexafluoroprop-1-ene appropriately?

Disposal of 1,1,2,3,3,3-hexafluoroprop-1-ene must be conducted through licensed hazardous waste disposal facilities equipped to handle pressurized gases and fluorinated compounds. Never release the substance directly into the atmosphere or water systems. Empty containers should be properly depressurized and handled as hazardous waste. Consult local environmental regulations and waste management authorities to ensure compliance with specific disposal requirements for fluorinated gases.

How to transport 1,1,2,3,3,3-hexafluoroprop-1-ene?

Transportation of 1,1,2,3,3,3-hexafluoroprop-1-ene falls under ADR Class 2 (gases) regulations for dangerous goods transport. Proper packaging in UN-approved pressure vessels is mandatory, along with appropriate hazard labels and transport documentation. Vehicles must be equipped with proper ventilation and emergency equipment. Drivers require ADR certification for transporting dangerous goods, and specific routing restrictions may apply depending on local regulations.

Is 1,1,2,3,3,3-hexafluoroprop-1-ene subject to specific regulations?

1,1,2,3,3,3-hexafluoroprop-1-ene is subject to REACH regulation for chemical registration and evaluation within the European Union. The substance falls under CLP regulation for classification, labeling, and packaging requirements, displaying GHS04 and GHS07 pictograms with warning signal word. It is not currently listed as a Substance of Very High Concern (SVHC). Additional regulations may apply regarding fluorinated gas emissions and environmental protection depending on the specific application.

Where to buy 1,1,2,3,3,3-hexafluoroprop-1-ene in Europe?

1,1,2,3,3,3-hexafluoroprop-1-ene is available through OYSI, a specialized European distributor of industrial chemicals and gases. OYSI provides reliable supply chains across Europe with proper handling, storage, and transport capabilities for pressurized gas products. Their technical expertise ensures compliance with all relevant safety and regulatory requirements. Contact OYSI directly for availability, technical specifications, and delivery options tailored to your specific industrial requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.