Nickel;sulfanylidenenickel

Ni3S2

nickel;sulfanylidenenickel

CAS12035-72-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

Consulting for Nickel;sulfanylidenenickel

Our experts support you with application, dosage, and compliance.

Request Consultation

Identification

CAS Number
12035-72-2
EC Number
234-829-6
UN Number
3288
Index Number
028-007-00-4
PubChem CID
25199732

Physical-chemical properties

Molecular Formula
Ni3S2
Molar Mass
240.22 g/mol
IUPAC Name
nickel;sulfanylidenenickel

Chemical Identifiers

InChI
InChI=1S/3Ni.2S
InChI Key
YGHCWPXPAHSSNA-UHFFFAOYSA-N

Overview

Nickel;sulfanylidenenickel (CAS 12035-72-2) is an inorganic nickel sulfide compound with significant industrial applications and notable health hazards requiring careful handling protocols. This chemical compound, also known by its IUPAC designation nickel;sulfanylidenenickel, represents a critical industrial material in various manufacturing processes. With the molecular formula Ni3S2 and a molecular weight of 240.22 g/mol, this nickel sulfide exhibits unique properties that make it valuable across multiple industrial sectors. The compound is assigned EC number 234-829-6 and falls under ADR transport class 6.1, reflecting its toxic nature and requiring specialized handling procedures. The substance presents significant safety considerations, classified under multiple hazard categories including carcinogenicity (Carc. 1A), mutagenicity (Muta. 2), and acute toxicity (Acute Tox. 3). Additional classifications encompass specific target organ toxicity with repeated exposure (STOT RE 1), skin sensitization potential (Skin Sens. 1), and severe aquatic toxicity both acute and chronic. These hazard classifications necessitate the "Danger" signal word and require appropriate GHS pictograms including GHS08, GHS06, and GHS09 for health hazards, acute toxicity, and environmental concerns respectively. Primary industrial applications include catalyst production, metallurgical processes, and specialized chemical synthesis operations. The compound finds particular utility in hydrogenation reactions and as a precursor in advanced materials manufacturing. Unlike related compounds such as N-methylaniline or phenylhydrazine, which serve primarily as organic intermediates, nickel;sulfanylidenenickel functions predominantly in inorganic industrial processes requiring nickel-based catalytic systems. OYSI maintains reliable supply chains for this specialized chemical compound, ensuring consistent availability for European industrial customers requiring high-quality nickel sulfide materials.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Acute Tox. 3; STOT RE 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H331

Toxic if inhaled.

H372

Causes damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3288
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameTrinickeldisulfid
Marine PollutantNo

Frequently Asked Questions

What is nickel;sulfanylidenenickel?

Nickel;sulfanylidenenickel (Ni3S2) is an inorganic compound consisting of three nickel atoms combined with two sulfur atoms, also known as nickel subsulfide. This crystalline solid has a molecular weight of 240.22 g/mol and is classified as a hazardous substance with multiple health and environmental risks. It is recognized as a Category 1A carcinogen and Category 2 mutagen, making it subject to strict safety regulations and handling procedures in industrial applications.

What are the physicochemical properties of nickel;sulfanylidenenickel?

Nickel;sulfanylidenenickel is a solid crystalline compound at room temperature, typically appearing as a dark metallic or black powder. The substance has limited solubility in water but may dissolve in certain acids. Its chemical formula Ni3S2 indicates a specific stoichiometric ratio of nickel to sulfur atoms. The compound exhibits metallic properties due to its nickel content and forms part of the nickel sulfide family of compounds with distinctive chemical reactivity.

What is nickel;sulfanylidenenickel used for?

Nickel;sulfanylidenenickel is primarily used in metallurgical processes and as an intermediate in nickel production and refining operations. The compound finds applications in specialized industrial processes where nickel sulfide chemistry is required. It may be used in research and development activities related to materials science and catalysis. Due to its hazardous classification, its use is restricted to professional industrial settings with appropriate safety measures and trained personnel.

How to handle nickel;sulfanylidenenickel safely?

Safe handling of nickel;sulfanylidenenickel requires comprehensive personal protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing to prevent skin contact and inhalation. Work should be conducted in well-ventilated areas or under fume extraction systems due to its carcinogenic and mutagenic properties. Personnel must be trained in hazardous material handling procedures, and exposure monitoring should be implemented. Emergency procedures and decontamination protocols must be established before handling this substance.

How to store nickel;sulfanylidenenickel correctly?

Proper storage of nickel;sulfanylidenenickel requires a cool, dry, well-ventilated area away from incompatible materials such as strong oxidizers and acids. Containers must be tightly sealed and properly labeled according to GHS requirements with appropriate hazard pictogrammes (GHS06, GHS08, GHS09). Storage areas should be restricted to authorized personnel only, with appropriate security measures. The substance should be kept away from heat sources and protected from moisture to prevent degradation or unwanted reactions.

What to do in case of contact with nickel;sulfanylidenenickel?

Immediate first aid for nickel;sulfanylidenenickel contact involves removing contaminated clothing and flushing affected skin areas with plenty of water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention due to its acute toxicity classification. Eye contact requires immediate irrigation with clean water for at least 15 minutes. Medical attention should be sought promptly in all exposure cases due to the substance's carcinogenic and sensitizing properties. Never induce vomiting if ingested.

How to dispose of nickel;sulfanylidenenickel appropriately?

Disposal of nickel;sulfanylidenenickel must comply with local and European waste regulations for hazardous materials, particularly those containing carcinogenic substances. The waste should be classified according to the European Waste Catalogue and disposed of through licensed hazardous waste contractors. Incineration or specialized treatment facilities capable of handling toxic metal compounds are typically required. Recovery or recycling of nickel content may be possible through specialized metal recovery processes, subject to regulatory approval and proper handling procedures.

How to transport nickel;sulfanylidenenickel?

Transportation of nickel;sulfanylidenenickel falls under ADR Class 6.1 (Toxic substances) Packing Group III, requiring appropriate dangerous goods documentation and packaging. Packages must bear proper UN identification numbers, hazard labels, and shipping names according to ADR regulations. Transport vehicles must be equipped with appropriate emergency equipment, and drivers must hold valid dangerous goods transport certificates. The substance requires segregation from incompatible materials during transport and must be secured to prevent damage or spillage.

Is nickel;sulfanylidenenickel subject to specific regulations?

Nickel;sulfanylidenenickel is subject to comprehensive European chemical regulations under REACH and CLP. As a Category 1A carcinogen and Category 2 mutagen, it requires authorization for certain uses and is subject to strict workplace exposure limits. The substance must be classified and labeled according to CLP regulation with appropriate hazard statements and precautionary measures. Users must implement risk management measures and may require safety data sheets for downstream communication. Export/import may require additional notifications.

Where to buy nickel;sulfanylidenenickel in Europe?

Nickel;sulfanylidenenickel is available through specialized chemical distributors in Europe, including OYSI, which supplies industrial chemicals to European markets. Due to its hazardous classification as a carcinogen and mutagen, purchase typically requires verification of legitimate industrial use and appropriate safety capabilities. Buyers must demonstrate proper handling facilities, trained personnel, and compliance with applicable regulations. Supply is generally limited to qualified industrial customers with established chemical handling infrastructure and regulatory compliance programs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.