Nickel;sulfanylidenenickel

Ni3S2

nickel;sulfanylidenenickel

CAS12035-72-2
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS06 Gefahrensymbol: Giftig – Totenkopf mit Knochen
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
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Identification

CAS Number
12035-72-2
EC Number
234-829-6
UN Number
3288
Index Number
028-007-00-4
PubChem CID
25199732

Physical-chemical properties

Molecular Formula
Ni3S2
Molar Mass
240.22 g/mol
IUPAC Name
nickel;sulfanylidenenickel

Chemical Identifiers

InChI
InChI=1S/3Ni.2S
InChI Key
YGHCWPXPAHSSNA-UHFFFAOYSA-N

Overview

Nickel;sulfanylidenenickel (CAS 12035-72-2) is an inorganic nickel sulfide compound with high toxicity and significant industrial applications. This chemical compound, also known by its IUPAC designation nickel;sulfanylidenenickel, represents a binary metal sulfide with the molecular formula Ni3S2 and a molecular weight of 240.22 g/mol. The substance belongs to the family of transition metal sulfides and exhibits distinctive properties that make it valuable in various industrial processes, though its handling requires extreme caution due to its severe health hazards. The compound carries multiple serious safety classifications including Category 1A carcinogen, Category 2 mutagen, and Category 3 acute toxicity, reflecting its potential to cause cancer, genetic damage, and immediate health effects upon exposure. Its hazard profile also includes respiratory sensitization, skin sensitization, and specific target organ toxicity with repeated exposure. The environmental impact is equally concerning, with acute and chronic aquatic toxicity classifications requiring careful waste management and disposal protocols. These safety characteristics distinguish it from less hazardous organic compounds such as N-methylaniline, which, while toxic, does not carry the same carcinogenic classification. Primary industrial applications include catalyst preparation in hydrogenation processes, battery electrode manufacturing, and specialized metallurgical operations where its unique electronic properties prove essential. The compound also finds use in advanced materials research and certain electrochemical applications where nickel sulfide phases are required. OYSI maintains availability of nickel;sulfanylidenenickel with full regulatory documentation and safety data sheets, ensuring compliance with European chemical regulations for qualified industrial customers requiring this specialized compound.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Acute Tox. 3; STOT RE 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chronic 1

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H331

Toxic if inhaled.

H372

Causes damage to organs through prolonged or repeated exposure.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Toxic

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3288
ADR Class6.1
Packing GroupIII
Tunnel CodeE
Proper Shipping NameTrinickeldisulfid
Marine PollutantNo

Frequently Asked Questions

What is nickel;sulfanylidenenickel?

Nickel;sulfanylidenenickel is an inorganic compound with the chemical formula Ni3S2 and CAS number 12035-72-2. This nickel sulfide compound has a molecular weight of 240.22 g/mol and consists of three nickel atoms bonded to two sulfur atoms. It is classified as a hazardous substance with multiple danger classifications including carcinogenicity, mutagenicity, and acute toxicity, requiring careful handling in industrial applications.

What are the physicochemical properties of nickel;sulfanylidenenickel?

Nickel;sulfanylidenenickel (Ni3S2) is typically a solid crystalline compound at room temperature with a metallic luster. As a nickel sulfide, it generally appears as dark-colored crystals or powder, ranging from gray to black. The compound has limited solubility in water but may dissolve in certain acids. Its molecular structure consists of nickel atoms in various oxidation states coordinated with sulfide ions, giving it characteristic metallic and semiconducting properties.

What is nickel;sulfanylidenenickel used for?

Nickel;sulfanylidenenickel serves primarily as a precursor in metallurgical processes and catalyst preparation. It is used in the production of nickel metal through pyrometallurgical processes and as an intermediate in nickel refining operations. The compound also finds applications in research and development of advanced materials, battery technologies, and specialized catalysts for chemical processes. Its unique electronic properties make it valuable in semiconductor and electronic component manufacturing.

How to handle nickel;sulfanylidenenickel safely?

Safe handling of nickel;sulfanylidenenickel requires comprehensive personal protective equipment due to its carcinogenic and toxic properties. Use respiratory protection, chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume extraction systems. Avoid skin contact, inhalation, and ingestion. Implement strict hygiene measures including hand washing and contaminated clothing removal. Train personnel on hazard recognition and emergency procedures before handling this dangerous substance.

How to store nickel;sulfanylidenenickel correctly?

Proper storage of nickel;sulfanylidenenickel requires a cool, dry, well-ventilated area away from incompatible materials. Store in tightly sealed, labeled containers to prevent moisture absorption and contamination. Keep away from acids, oxidizing agents, and reactive metals. Implement restricted access with appropriate warning signs due to its carcinogenic classification. Maintain storage areas with appropriate spill containment measures and ensure compliance with local chemical storage regulations and fire safety requirements.

What to do in case of contact with nickel;sulfanylidenenickel?

Immediate first aid measures for nickel;sulfanylidenenickel contact include removing contaminated clothing and washing affected skin thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air immediately and seek medical attention. For eye contact, rinse continuously with clean water for 15 minutes. If ingested, do not induce vomiting and seek immediate medical care. Always inform medical personnel about the specific substance and its hazardous properties.

How to dispose of nickel;sulfanylidenenickel appropriately?

Disposal of nickel;sulfanylidenenickel must comply with hazardous waste regulations due to its toxic and carcinogenic properties. Contact licensed hazardous waste disposal companies for proper treatment and disposal. Never discharge into sewers, water bodies, or regular waste streams. Collect waste in appropriate containers, properly labeled with hazard information. Consider recovery or recycling options where available, as nickel compounds have value for metal recovery. Follow local and European waste management directives strictly.

How to transport nickel;sulfanylidenenickel?

Transportation of nickel;sulfanylidenenickel follows ADR classification as Class 6.1 (toxic substances), Packing Group III. Use appropriate packaging meeting UN specifications with proper hazard labels and documentation. Vehicles must comply with ADR requirements including equipment and driver certification. Ensure packages are secure, properly marked, and accompanied by transport documents indicating the hazardous nature. Follow routing restrictions and emergency response procedures for dangerous goods transportation throughout Europe.

Is nickel;sulfanylidenenickel subject to specific regulations?

Nickel;sulfanylidenenickel is subject to extensive European chemical regulations under REACH and CLP classifications. Its carcinogenic (Category 1A) and mutagenic properties require strict compliance with occupational safety directives and worker protection measures. The compound's environmental hazard classification demands adherence to emission controls and environmental protection standards. Industries using this substance must implement comprehensive risk management measures and may require specific authorizations or notifications depending on usage quantities and applications.

Where to buy nickel;sulfanylidenenickel in Europe?

Nickel;sulfanylidenenickel is available through specialized chemical distributors in Europe, including OYSI, which supplies technical-grade chemicals to industrial customers. Due to its hazardous classification, purchases typically require proper business credentials and compliance documentation. Suppliers must provide safety data sheets, certificates of analysis, and appropriate packaging for safe transport. Contact OYSI's technical team for availability, specifications, and regulatory compliance support for your specific application requirements.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.