Nickel(2+);bis(octadecanoate)
C36H70NiO4
nickel(2+);bis(octadecanoate)
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Identification
- CAS Number
- 2223-95-2
- EC Number
- 218-744-1
- UN Number
- 3077
- Index Number
- 028-026-00-8
- PubChem CID
- 160624
Physical-chemical properties
- Molecular Formula
- C36H70NiO4
- Molar Mass
- 625.60 g/mol
- IUPAC Name
- nickel(2+);bis(octadecanoate)
Chemical Identifiers
- InChI
- InChI=1S/2C18H36O2.Ni/c2*1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h2*2-17H2,1H3,(H,19,20);/q;;+2/p-2
- InChI Key
- JMWUYEFBFUCSAK-UHFFFAOYSA-L
Overview
Nickel(2+);bis(octadecanoate) (CAS 2223-95-2) is an organometallic salt compound with long-chain fatty acid ligands and significant industrial catalytic properties. This nickel-based organometallic compound represents a specialized chemical intermediate widely utilized in industrial applications requiring nickel catalysis and surface modification. The substance consists of a nickel(2+) cation coordinated with two octadecanoate anions, creating a complex with both metallic and organic characteristics. With its molecular formula C36H70NiO4 and molecular weight of 625.6 g/mol, this compound exhibits unique properties derived from the combination of nickel's catalytic activity and the long-chain aliphatic structure of octadecanoic acid. The compound's extensive hazard classification includes carcinogenic (Category 1A), mutagenic (Category 2), and reproductive toxicity (Category 1B) properties, along with respiratory and skin sensitization potential. These characteristics, shared with related nickel compounds such as diiodonickel, necessitate strict handling protocols and appropriate personal protective equipment. The GHS08 and GHS09 pictograms indicate both health hazards and environmental concerns, particularly regarding aquatic toxicity. Primary industrial applications include its use as a catalyst in polymerization reactions, as a metallic soap in lubricant formulations, and as a precursor in specialized coating applications. The compound's long-chain fatty acid structure provides enhanced solubility in organic systems compared to simpler nickel salts like nickel(2+) diformate, making it particularly valuable in applications requiring compatibility with organic matrices. OYSI maintains reliable supply chains for nickel(2+);bis(octadecanoate) to support various industrial requirements across European markets.
Safety & Classification
Carc. 1A; Muta. 2; Repr. 1B; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chr...
GHS Pictograms
HHazard Statements (H-Statements)
Describe the nature and severity of the hazard
Suspected of causing genetic defects.
Causes damage to organs through prolonged or repeated exposure.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).
First Aid Measures
Inhalation
Measures if vapours or dust are inhaled
First Aid Actions
- +P304IF INHALED:
- +P340Remove person to fresh air and keep comfortable for breathing.
- +P311Call a POISON CENTER/doctor.
Related hazard statements:
Skin Contact
Measures if substance contacts the skin
First Aid Actions
- +P302IF ON SKIN:
- +P352Wash with plenty of water.
- +P361Take off immediately all contaminated clothing.
- +P313Get medical advice/attention.
Related hazard statements:
General Measures
Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)
First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.
Transport (ADR)
| UN Number | 3077 |
| ADR Class | 9 |
| Packing Group | III |
| Tunnel Code | - |
| Proper Shipping Name | Nickel(II)-stearat |
| Marine Pollutant | No |
Frequently Asked Questions
What is nickel(2+);bis(octadecanoate)?
Nickel(2+);bis(octadecanoate) is an organometallic compound consisting of a nickel(II) ion coordinated with two octadecanoate (stearate) anions. With the molecular formula C36H70NiO4 and a molecular weight of 625.6 g/mol, this compound combines the catalytic properties of nickel with the long-chain fatty acid structure of stearic acid. It appears as a metal soap compound commonly used in industrial applications requiring both metallic and surfactant properties.
What are the physicochemical properties of nickel(2+);bis(octadecanoate)?
Nickel(2+);bis(octadecanoate) is typically a solid compound at room temperature, often appearing as a greenish or bluish powder due to the characteristic color of nickel(II) compounds. As a metal stearate, it exhibits low solubility in water but shows better solubility in organic solvents and oils. The compound has lubricating properties inherited from its stearate chains and demonstrates thermal stability typical of metal soaps, making it suitable for high-temperature applications.
What is nickel(2+);bis(octadecanoate) used for?
Nickel(2+);bis(octadecanoate) is primarily used as a catalyst in polymerization reactions, particularly in the production of plastics and synthetic rubbers. It serves as a metal soap in lubricant formulations, providing anti-wear and extreme pressure properties. The compound is also employed in paint and coating formulations as a drier and stabilizer, and in the production of specialized greases where its unique combination of metallic and surfactant properties is valued.
How to handle nickel(2+);bis(octadecanoate) safely?
Nickel(2+);bis(octadecanoate) requires careful handling due to its classification as Carc. 1A, Muta. 2, Repr. 1B, STOT RE 1, and respiratory/skin sensitizer. Essential PPE includes respiratory protection (P2 filter minimum), chemical-resistant gloves, safety goggles, and protective clothing. Work in well-ventilated areas or under fume extraction to prevent inhalation. Avoid skin contact and dust generation. Implement strict hygiene measures including hand washing and separate work clothing to prevent contamination.
How to store nickel(2+);bis(octadecanoate) correctly?
Nickel(2+);bis(octadecanoate) should be stored in tightly sealed, original containers in a cool, dry, well-ventilated area away from heat sources and direct sunlight. Keep containers upright and protected from moisture to prevent degradation. Store separately from incompatible materials including strong oxidizers and acids. Ensure storage areas are equipped with appropriate spill containment measures and restrict access to authorized personnel only due to the compound's hazardous classification.
What to do in case of contact with nickel(2+);bis(octadecanoate)?
Immediate action is crucial due to the compound's sensitizing and carcinogenic properties. For skin contact, remove contaminated clothing immediately and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air and seek medical attention immediately. For eye contact, rinse with clean water for at least 15 minutes and remove contact lenses if present. Seek immediate medical attention in all cases of exposure, providing the safety data sheet to medical personnel.
How to dispose of nickel(2+);bis(octadecanoate) appropriately?
Nickel(2+);bis(octadecanoate) must be disposed of as hazardous waste through licensed waste management companies due to its classification and heavy metal content. The compound cannot be disposed of in regular waste streams or sewage systems due to its aquatic toxicity (Aquatic Acute 1). Collection should be done in appropriate containers, clearly labeled, and handled according to local and European waste regulations including the Waste Framework Directive. Consult local authorities for specific disposal requirements.
How to transport nickel(2+);bis(octadecanoate)?
Nickel(2+);bis(octadecanoate) is classified as ADR Class 9 (Miscellaneous Dangerous Goods), Packing Group III for transportation purposes. This classification requires appropriate packaging, labeling with Class 9 hazard labels, and proper documentation including transport documents. Packages must be marked with the proper shipping name and UN number. Transport vehicles should be equipped with appropriate safety equipment, and drivers must be trained in ADR regulations for Class 9 substances.
Is nickel(2+);bis(octadecanoate) subject to specific regulations?
Nickel(2+);bis(octadecanoate) is subject to comprehensive European chemical regulations under REACH and CLP due to its hazardous classification including carcinogenicity, mutagenicity, and reproductive toxicity. As a nickel compound, it may face restrictions under various occupational health regulations and requires risk assessment under workplace safety directives. The compound's environmental hazard classification also subjects it to water protection regulations and emission control requirements across EU member states.
Where to buy nickel(2+);bis(octadecanoate) in Europe?
Nickel(2+);bis(octadecanoate) is available through OYSI, a specialized European distributor of technical chemicals with expertise in handling hazardous substances. OYSI provides comprehensive support including proper documentation, safety data sheets, and regulatory compliance assistance. As a professional chemical distributor, OYSI ensures appropriate packaging, labeling according to CLP requirements, and reliable supply chain management for industrial customers requiring this specialized organometallic compound across European markets.
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Data Sources
Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.