Nickel(2+) dibenzoate

C14H10NiO4

nickel(2+) dibenzoate

CAS553-71-9
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
553-71-9
EC Number
209-046-8
UN Number
3077
Index Number
028-024-00-7
PubChem CID
15269180

Physical-chemical properties

Molecular Formula
C14H10NiO4
Molar Mass
300.92 g/mol
IUPAC Name
nickel(2+) dibenzoate

Chemical Identifiers

InChI
InChI=1S/2C7H6O2.Ni/c2*8-7(9)6-4-2-1-3-5-6;/h2*1-5H,(H,8,9);/q;;+2/p-2
InChI Key
GAIQJSWQJOZOMI-UHFFFAOYSA-L

Overview

Nickel(2+) dibenzoate (CAS 553-71-9) is an organometallic nickel salt compound featuring two benzoate ligands coordinated to a divalent nickel center. This specialized nickel compound represents an important class of organometallic materials widely utilized in industrial applications requiring controlled nickel delivery and catalytic properties. The molecular structure consists of a central nickel(II) ion coordinated with two benzoate anions, forming a stable complex with the molecular formula C14H10NiO4 and a molecular weight of 300.92 g/mol. As part of the broader family of nickel coordination compounds, it shares structural similarities with other nickel salts such as bis(2-hydroxypropanoic acid);nickel, though each exhibits distinct reactivity profiles based on their specific ligand systems. The compound presents significant safety considerations due to its classification under multiple hazard categories. It carries a Class 1A carcinogen designation, indicating proven carcinogenic potential, alongside reproductive toxicity (Repr. 1B) and mutagenic properties (Muta. 2). Additional concerns include respiratory and skin sensitization potential, specific target organ toxicity following repeated exposure, and acute aquatic toxicity. These hazard classifications necessitate stringent handling protocols, appropriate personal protective equipment, and controlled storage conditions in accordance with ADR Class 9 dangerous goods regulations. Industrial applications typically leverage the compound's catalytic properties and controlled nickel release characteristics in specialized chemical processes, catalyst preparation, and materials synthesis applications. The benzoate ligands provide enhanced solubility in organic media compared to simple nickel salts, making it valuable in organic synthesis and polymerization reactions. OYSI maintains availability of nickel(2+) dibenzoate through our European distribution network, ensuring reliable supply for qualified industrial customers with appropriate handling capabilities.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chr...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H372

Causes damage to organs through prolonged or repeated exposure.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickel(II)-benzoat
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) dibenzoate?

Nickel(2+) dibenzoate is an organometallic compound with the molecular formula C14H10NiO4 and CAS number 553-71-9. This chemical consists of a nickel(II) ion coordinated with two benzoate ligands, forming a complex with a molecular weight of 300.92 g/mol. It belongs to the category of nickel salts and is classified as a hazardous substance due to its carcinogenic, mutagenic, and reproductive toxicity properties.

What are the physicochemical properties of nickel(2+) dibenzoate?

Nickel(2+) dibenzoate typically appears as a solid crystalline compound at room temperature. As a nickel complex, it generally exhibits characteristic coloration, often green or blue-green, typical of nickel(II) compounds. The compound has limited solubility in water but may dissolve in organic solvents. Its molecular structure features nickel coordinated with benzoate groups, contributing to its stability and specific chemical behavior in various applications.

What is nickel(2+) dibenzoate used for?

Nickel(2+) dibenzoate is primarily used as a catalyst in various chemical processes and organic synthesis reactions. It serves as a precursor for preparing other nickel compounds and catalysts in industrial applications. The compound may also be utilized in specialized chemical research, materials science, and as an intermediate in the production of nickel-based materials. Its applications are typically limited to professional and industrial settings due to its hazardous classification.

How to handle nickel(2+) dibenzoate safely?

Nickel(2+) dibenzoate requires strict safety measures due to its carcinogenic and sensitizing properties. Use appropriate personal protective equipment including respiratory protection, chemical-resistant gloves, and protective clothing. Work in well-ventilated areas or under fume hoods to prevent inhalation exposure. Avoid skin and eye contact, and implement proper hygiene practices. Training on hazardous substance handling is essential before use, and exposure monitoring may be required in workplace settings.

How to store nickel(2+) dibenzoate correctly?

Nickel(2+) dibenzoate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Keep away from sources of ignition, heat, and direct sunlight. Store separately from food, beverages, and animal feed. Ensure proper labeling according to CLP regulations and maintain an inventory of quantities. Access should be restricted to trained personnel only, and storage areas should have appropriate spill containment measures.

What to do in case of contact with nickel(2+) dibenzoate?

In case of skin contact with nickel(2+) dibenzoate, immediately remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. If inhaled, move the person to fresh air and seek medical attention if breathing difficulties occur. For eye contact, rinse immediately with plenty of water for at least 15 minutes. Seek immediate medical attention for all exposure routes due to the substance's carcinogenic and sensitizing properties.

How to dispose of nickel(2+) dibenzoate appropriately?

Nickel(2+) dibenzoate must be disposed of as hazardous waste through licensed waste management companies in accordance with local and European waste regulations. The substance cannot be disposed of in regular waste streams due to its classification and environmental hazards. Collect waste in appropriate containers, properly labeled, and ensure proper documentation for waste tracking. Consult local environmental authorities for specific disposal requirements and approved disposal facilities in your region.

How to transport nickel(2+) dibenzoate?

Nickel(2+) dibenzoate is classified under ADR Class 9 (Miscellaneous dangerous substances), Packing Group III for transportation purposes. It must be packaged in UN-approved containers with proper labeling including the appropriate hazard pictogrammes (GHS08, GHS09) and 'Danger' signal word. Transport documentation must include the proper shipping name, UN number, and hazard class. Only trained personnel should handle transportation, and emergency response information must be available during transport.

Is nickel(2+) dibenzoate subject to specific regulations?

Nickel(2+) dibenzoate is subject to comprehensive European chemical regulations including REACH registration requirements and CLP classification and labeling obligations. Due to its carcinogenic (Category 1A), mutagenic (Category 2), and reproductive toxicity (Category 1B) classifications, it may be subject to authorization procedures and workplace exposure limits. Companies using this substance must comply with occupational health regulations and may need to implement risk management measures and worker health surveillance programs.

Where to buy nickel(2+) dibenzoate in Europe?

Nickel(2+) dibenzoate is available through OYSI, a European distributor of specialty chemicals, serving customers across the European market. As a professional chemical distributor, OYSI provides this substance to qualified industrial and research customers with proper documentation and safety data sheets. Due to the hazardous nature of this compound, purchases are typically restricted to professional users with appropriate handling capabilities and regulatory compliance measures in place.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.