Nickel(2+) dibenzoate

C14H10NiO4

nickel(2+) dibenzoate

CAS553-71-9
GHS08 Gefahrensymbol: Gesundheitsgefahr – Gesundheitsgefahr
GHS09 Gefahrensymbol: Umweltgefährlich – Umwelt
Danger

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Identification

CAS Number
553-71-9
EC Number
209-046-8
UN Number
3077
Index Number
028-024-00-7
PubChem CID
15269180

Physical-chemical properties

Molecular Formula
C14H10NiO4
Molar Mass
300.92 g/mol
IUPAC Name
nickel(2+) dibenzoate

Chemical Identifiers

InChI
InChI=1S/2C7H6O2.Ni/c2*8-7(9)6-4-2-1-3-5-6;/h2*1-5H,(H,8,9);/q;;+2/p-2
InChI Key
GAIQJSWQJOZOMI-UHFFFAOYSA-L

Overview

Nickel(2+) dibenzoate (CAS 553-71-9) is an organometallic nickel salt compound featuring two benzoate ligands coordinated to a divalent nickel center. This specialized nickel compound represents a significant organometallic salt widely utilized across various industrial applications where controlled nickel delivery is essential. With its molecular formula C14H10NiO4 and molecular weight of 300.92 g/mol, nickel(2+) dibenzoate demonstrates the characteristic properties of transition metal carboxylates, offering unique catalytic and chemical processing capabilities. The compound belongs to the broader family of nickel carboxylates, sharing structural similarities with related compounds such as nickel(2+);bis(octadecanoate), though differing in its aromatic benzoate ligands which confer distinct solubility and reactivity profiles. Its classification under multiple hazard categories including Carcinogenic 1A, Mutagenic 2, and Reproductive toxicity 1B requires stringent safety protocols during handling and storage. The presence of GHS08 and GHS09 pictograms indicates serious health hazards and environmental concerns, necessitating appropriate personal protective equipment and containment measures. Industrial applications of nickel(2+) dibenzoate primarily include catalytic processes in organic synthesis, where it serves as a nickel source for various coupling reactions and polymerization processes. The compound also finds application in specialized coating formulations and as a precursor for advanced materials synthesis. Additionally, it functions as an intermediate in the production of other nickel-containing compounds and catalysts. Safety considerations are paramount when working with this substance, given its classification under ADR Class 9 and its potential respiratory and skin sensitization effects. Proper ventilation, appropriate disposal methods, and adherence to occupational exposure limits are essential for safe handling. OYSI maintains reliable supplies of nickel(2+) dibenzoate to support diverse industrial applications across European markets.

Safety & Classification

Danger
Classification:

Carc. 1A; Muta. 2; Repr. 1B; STOT RE 1; Resp. Sens. 1; Skin Sens. 1; Aquatic Acute 1; Aquatic Chr...

HHazard Statements (H-Statements)

Describe the nature and severity of the hazard

H341

Suspected of causing genetic defects.

H372

Causes damage to organs through prolonged or repeated exposure.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H317

May cause an allergic skin reaction.

H400

Very toxic to aquatic life.

H410

Very toxic to aquatic life with long lasting effects.

Classification according to CLP Regulation (EC) No 1272/2008. The complete list of hazard and precautionary statements can be found in the Safety Data Sheet (SDS).

First Aid Measures

Inhalation

Harmful

Measures if vapours or dust are inhaled

First Aid Actions

  • +P304IF INHALED:
  • +P340Remove person to fresh air and keep comfortable for breathing.
  • +P311Call a POISON CENTER/doctor.

Related hazard statements:

Skin Contact

Irritant

Measures if substance contacts the skin

First Aid Actions

  • +P302IF ON SKIN:
  • +P352Wash with plenty of water.
  • +P361Take off immediately all contaminated clothing.
  • +P313Get medical advice/attention.

Related hazard statements:

General Measures

Emergency 112 | Poison Control: +49 30 19240 (DE), +33 1 45 42 59 59 (FR), +31 30 274 88 88 (NL)

First aid measures are based on CLP classification and associated P-statements. They do not replace the Safety Data Sheet (SDS). In case of emergency, always consult the full SDS and a physician.

Transport (ADR)

UN Number3077
ADR Class9
Packing GroupIII
Tunnel Code-
Proper Shipping NameNickel(II)-benzoat
Marine PollutantNo

Frequently Asked Questions

What is nickel(2+) dibenzoate?

Nickel(2+) dibenzoate is an organometallic compound with the chemical formula C14H10NiO4 and CAS number 553-71-9. It consists of a nickel(II) ion coordinated with two benzoate ligands, forming a complex with a molecular weight of 300.92 g/mol. This compound is classified as highly hazardous due to its carcinogenic, mutagenic, and reproductive toxicity properties, requiring strict handling protocols in industrial applications.

What are the physicochemical properties of nickel(2+) dibenzoate?

Nickel(2+) dibenzoate typically appears as a crystalline solid at room temperature. Like most nickel compounds, it likely exhibits a characteristic green or blue-green coloration. The compound has a molecular weight of 300.92 g/mol and contains nickel in the +2 oxidation state. Its solubility properties depend on the solvent system, with limited water solubility expected due to its organometallic nature and coordination structure.

What is nickel(2+) dibenzoate used for?

Nickel(2+) dibenzoate serves primarily as a catalyst precursor in organic synthesis and polymerization reactions. It finds applications in specialized chemical manufacturing processes where nickel coordination compounds are required. The compound may also be used in research settings for studying nickel chemistry and coordination complexes. Due to its hazardous classification, its use is restricted to professional industrial applications with appropriate safety measures and regulatory compliance.

How to handle nickel(2+) dibenzoate safely?

Nickel(2+) dibenzoate requires strict safety protocols due to its carcinogenic and sensitizing properties. Personnel must wear appropriate respiratory protection, chemical-resistant gloves, and protective clothing to prevent skin and inhalation exposure. Work should be conducted in well-ventilated areas or under fume hoods. Regular health monitoring is essential for workers handling this substance. Emergency procedures and decontamination protocols must be established before use.

How to store nickel(2+) dibenzoate correctly?

Nickel(2+) dibenzoate should be stored in tightly sealed containers in a cool, dry, well-ventilated area away from incompatible materials. Storage areas must be restricted to authorized personnel only due to the compound's hazardous classification. Containers should be properly labeled with hazard information and stored away from heat sources, oxidizing agents, and incompatible chemicals. Regular inspection of containers for integrity is recommended to prevent accidental releases.

What to do in case of contact with nickel(2+) dibenzoate?

Immediate action is required for any contact with nickel(2+) dibenzoate. For skin contact, remove contaminated clothing and wash the affected area thoroughly with soap and water for at least 15 minutes. In case of eye contact, flush immediately with clean water for 15 minutes. If inhaled, move the person to fresh air immediately. Seek medical attention promptly in all cases, informing healthcare providers about the specific substance and its hazardous properties.

How to dispose of nickel(2+) dibenzoate appropriately?

Nickel(2+) dibenzoate must be disposed of as hazardous waste through licensed waste management companies specializing in heavy metal and carcinogenic substances. The compound cannot be disposed of in regular waste streams due to its environmental toxicity and carcinogenic properties. All disposal activities must comply with local, national, and EU waste regulations. Proper documentation and waste tracking are required throughout the disposal process to ensure regulatory compliance.

How to transport nickel(2+) dibenzoate?

Nickel(2+) dibenzoate is classified as ADR Class 9 (Miscellaneous Dangerous Goods), Packing Group III for transport purposes. It requires appropriate hazardous materials packaging, labeling, and documentation during transport. Shipments must comply with ADR regulations for road transport within Europe. Proper shipping papers, emergency response information, and vehicle placarding are mandatory. Only certified carriers experienced in handling hazardous materials should transport this substance.

Is nickel(2+) dibenzoate subject to particular regulations?

Nickel(2+) dibenzoate is subject to extensive regulatory oversight under REACH and CLP regulations due to its classification as carcinogenic, mutagenic, and reprotoxic. The compound requires safety data sheets, exposure scenarios, and risk assessments for commercial use. Its classification as a respiratory and skin sensitizer triggers additional workplace safety requirements. Users must implement appropriate risk management measures and may need authorization depending on specific applications and exposure levels.

Where to buy nickel(2+) dibenzoate in Europe?

Nickel(2+) dibenzoate is available through specialized chemical distributors like OYSI, which serves the European market with technical-grade chemicals. Due to its hazardous classification, purchase is typically restricted to qualified industrial users with appropriate handling capabilities and regulatory compliance. Buyers must provide proper documentation and demonstrate adequate safety measures. Contact OYSI directly to discuss availability, specifications, and regulatory requirements for your specific application needs.

Data Sources

Classification per CLP Regulation (EC) No 1272/2008. Data from ECHA and PubChem.